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폴리피롤 첨가에 의한 supercapacitor용 저 임피던스 전극 Electrode of Low Impedance by Polypyrrole Addition for Supercapacitor

김경민, 장인영, 강안수
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대한안전경영과학회 학술대회
2003년도 대한안전경영과학회 추계학술대회 (2003.11)
pp.343-350
대한안전경영과학회 (Korea Safety Management & Science)
초록

The best Ppy weight ratio was 7 wt% and the optimal electrode composition ratio was 78 : 17 : 5 wt.% of (MSP-20 : BP-20 =1 : 1), (Super P : Ppy =10 : 7) and P(VdF-co-HFP). Implantation of Ppy as the conducting agents have led to superior electrochemical characteristics because of the low of internal resistance and faradaic capacitance. The result of unit cell with Ppy 7 wt% were as follows: 28.02 Fig of specific capacitance, 1.34 Ω of DC-ESR and 0.36 Ω of AC-ESR. Unit cell showed a good stability up to 200 charge-discharge cycles, retaining 82% of their original capacity at 200 cycles. From the analysis of impedance, the electrodes with Ppy 7 wt% showed low ESR, low charge transfer resistance and quick reaction rate. It was inferred that quick charge-discharge was possible. As compared with the specific capacitance (rectangular shape) of CV, it was also concluded that the specific capacitance originated from thecompound phenomena of the faradaic capacitance by oxidation and reduction of Ppy and the non-faradaic capacitance by adsorption-desorption of activated carbon.

키워드
목차
Abstract
 1. 서론
 2. 이론적 배경
  2.1. 전기이중층 이론
 3. 실험 방법
  3.1. 폴리피롤의 제조
  3.2. 전극 및 단위셀 제조
 4. 결과 및 토론
 5. 결론
 6. 참고문헌
저자
  • 김경민
  • 장인영
  • 강안수