This research performed physico-chemical analysis of MSW(municipal solid waste) for design and operation ofgasification generation system. The MSW sample was analyzed by proximate, ultimate, heat value method and sampledeach residential type classified apartment, house, urban and rural in by seasonal generation According to statistics of 2010MSW generation in Korea, On average, Namwon generated about 101.4 ton of trash and recycled almost 57.5 ton ofthis material per day, equivalent to a 56.7 percent recycling rate. It was recycled 0.73 kilograms out of individual wastegeneration of 1.29 kilograms per person per day. In 2011, On average, Namwon generated about 46.7 ton without recycledmaterial per day, and individual generation was 0.60 kilograms. It was virtually identical with statistics data in 2010. Inthe physico-chemical analysis results, it was composed of 84.1 percent of combustible and 15.9 percent of Non-combustible. On average, heat value was 2,529kcal per kilogram in condition of LHV and wet. The MSW sample wasincluded 32.0 percent of moisture, 21.9 percent of ash, 26.8 percent of carbon, 14.4 percent of oxygen, 3.7 percent ofhydrogen and 1.3 percent of others. Estimate of technical potential energy of MSW was 1,278 toe per year, equivalentto a 33.3 percent of total potential energy.