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Mechanistic Design of Membrane Adsorbent Based on Inverse Vulcanized Polysulfide for Hg2+ Sequestration

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  • URLhttps://db.koreascholar.com/Article/Detail/345514
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한국막학회 (The Membrane Society Of Korea)
초록

Sulfur copolymer (poly(S-r-CEA)) was synthesized via facile inverse vulcanization of elemental sulfur with 2-carboxyethyl acrylate (CEA). Polysulfide (PS) oligomer was soluble to common solvents including DMF, producing homogenous dope solution with PAN as filler. PS-PAN was electrospun resulting to nanofiber membrane effective for Hg2+ sequestration with recorded maximum capacity of 612 mg g-1 based on Langmuir model isotherm. Kinetics, selectivity and reusability were also evaluated. This work presents new and cheap yet effective material for heavy metal sequestration from contaminated water. This work was supported by Basic Science Research Program through the National Research Foundation of Korea (NRF) funded by the Ministry of Science, ICT and Future Planning (2015R1A2A1A15055407) and by the Ministry of Education (No. 2009-0093816).

저자
  • 로렌스 림주코(명지대학교 에너지융합공학과, 에너지환경융합기술연구소) | Lawrence A. Limjuco
  • 그레이스 니솔라(명지대학교 에너지융합공학과, 에너지환경융합기술연구소) | Grace M. Nisola
  • 하나 게브리찌아버(명지대학교 에너지융합공학과, 에너지환경융합기술연구소) | Hana Gebreegziabher
  • 아닐린 벤도이(명지대학교 에너지융합공학과, 에너지환경융합기술연구소) | Anelyn P. Bendoy
  • 이성풍(명지대학교 에너지융합공학과, 에너지환경융합기술연구소) | Seong-Poong Lee
  • 정욱진(명지대학교 에너지융합공학과, 에너지환경융합기술연구소) | Wook Jin Chung 교신저자