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Polysulfone에 추출제 Di-(2-ethylhexyl)phosphoric acid (D2EHPA)와 tri-butyl-phosphate(TBP)를 고정화한 고체상 추출제의 제조와 Cu(II)의 제거 특성 KCI 등재

Preparation of Solid-Phase Extractant by Immobilizing Di-(2-ethylhexyl)phosphoric Acid (D2EHPA) and Tri-butyl-phosphate (TBP) in Polysulfone and Removal Characteristics of Cu(II)

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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

The solid-phase extractant PS-D2EHPA/TBP was prepared by immobilizing two extractants D2EHPA and TBP in polysulfone (PS). The prepared PS-D2EHPA/TBP was characterized by using fourier transform infrared spectrometer (FTIR) and scanning electron microscopy (SEM). The removal of Cu(II) from aqueous solution was investigated in batch system. The experiment data were obeyed the pseudo-second-order kinetic model. Equilibrium data were well fitted by Langmuir model and the removal capacity of Cu(II) by solid extractant PS-D2EHPA/TBP obtained from Langmuir model was 3.11 mg/g at 288 K. The removal capacity of Cu(II) was increased according to increasing pH from 2 to 6, but the removal capacity was decreased below pH 3 remarkably.

목차
Abstract
 1. 서 론
 2. 재료 및 방법
  2.1. 재료
  2.2. 고체상 추출제의 제조
  2.3. 실험 방법
 3. 결과 및 고찰
  3.1. 고체상 추출제의 특성 분석
  3.2. 시간에 따른 제거량 변화
  3.3. 제거 속도
  3.4. 등온식
  3.5. pH의 영향
 4. 결론
 REFERENCES
저자
  • 감상규(제주대학교 환경공학과) | Sang-Kyu Kam (Department of Environmental Engineering, Jeju National University)
  • 전진우(부경대학교 화학공학과) | Jin-Woo Jeon (Department of Chemical Engineering, Pukyong National University)
  • 이민규(부경대학교 화학공학과) | Min-Gyu Lee (Department of Chemical Engineering, Pukyong National University) Corresponding author