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D2EHPA를 Polysulfone으로 고정화하여 제조한 고체상 추출제에 의한 Cu(II)와 Pb(II)의 제거 KCI 등재

Removal of Cu(II) and Pb(II) by Solid-Phase Extractant Prepared by Immobilizing D2EHPA with Polysulfone

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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

Abstract PS-D2EHPA beads were prepared by immobilizing di-2-ethylhexyl-phosphoric acid (D2EHPA) with polysulfone (PSf). The removal experiments of Cu(II) and Pb(II) by the prepared PS-D2EHPA beads were conducted batchwise. The removal efficiency of Cu(II) and Pb(II) by PS-D2EHPA beads was increased with increasing pH of solution. The removal rate of Cu(II) and Pb(II) was well described by the pseudo-second-order kinetic model. The maximum removal capacity of Cu(II) and Pb(II) obtained from Langmuir isotherm were 2.58 mg/g and 12.63 mg/g, respectively. External mass transfer coefficients for the removal of Cu(II) and Pb(II) by PS-D2EHPA beads were obtained 0.61×10-2∼ 5.87×10-2 /min and 1.55×10-2∼8.53×10-2 /min, respectively and diffusion coefficients were obtained 1.32×10-4∼ 3.98×10-4 cm2/min and 1.80×10-4∼2.28×10-4 cm2/min, respectively.

목차
Abstract
 1. 서 론
 2. 실험재료 및 방법
  2.1. 실험 재료
  2.2. 실험 방법
 3. 결과 및 고찰
  3.1. 제조한 PS-D2EHPA 비드의 구조
  3.2. pH의 영향
  3.3. 시간에 따른 영향
  3.4. 등온식
 4. 결론
 참고문헌
저자
  • 감상규(제주대학교 환경공학과) | Sang-Kyu Kam (Department of Environmental Engineering, Jeju National University)
  • 전진우(부경대학교 화학공학과) | Jin-Woo Jeon (Department of Chemical Engineering, Pukyong National University)
  • 이민규(부경대학교 화학공학과) | Min-Gyu Lee (Department of Chemical Engineering, Pukyong National University) Corresponding author