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Molten Salt Immersion Technique With MgCl2 Based Molten Salts for the Sr Nuclide Separation

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한국방사성폐기물학회 학술논문요약집 (Abstracts of Proceedings of the Korean Radioactive Wasts Society)
한국방사성폐기물학회 (Korean Radioactive Waste Society)
초록

Molten salt immersion technique has been tested with several Sr oxides, SrZrO3, SrMoO4 and U2SrOy, and MgCl2 based molten salts for the Sr nuclide separation. Reaction time, temperature, and salt composition were varied to effectively separate Sr in chloride forms. ICP-OES, XRD, and SEM analysis were conducted for the conversion efficiency and structure and morphology analysis. It is confirmed that all experiments of SrZrO3 with MgCl2 at 800°C for reaction time 5, 10, 20 hours showed higher conversion efficiency than 99% and in LiCl-KCl-MgCl2 and NaCl-MgCl2 molten salts at 500°C or 600°C, conversion efficiency higher than 97% was obtained. SrMoO4 in MgCl2 immersion experiments for 10 hours showed higher conversion efficiency than 99% when the molar ratio of salt/oxide powder is 7. U2SrOy was also tested with MgCl2 molten salt at 800°C and higher efficiency than 99% and mainly MgUO4 were produced as a reaction product.

저자
  • Sang-Kwon Lee(Korea Atomic Energy Research Institute, 111, Daedeok-daero 989beon-gil, Yuseong-gu, Daejeon) Corresponding author
  • Seoung-Woo Paek(Korea Atomic Energy Research Institute, 111, Daedeok-daero 989beon-gil, Yuseong-gu, Daejeon)
  • Ju Ho Lee(Korea Atomic Energy Research Institute, 111, Daedeok-daero 989beon-gil, Yuseong-gu, Daejeon)
  • Young Hwan Kim(Korea Atomic Energy Research Institute, 111, Daedeok-daero 989beon-gil, Yuseong-gu, Daejeon)
  • Chang Hwa Lee(Korea Atomic Energy Research Institute, 111, Daedeok-daero 989beon-gil, Yuseong-gu, Daejeon)