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Waste Resin Treatment Generated From HWR Using Microwave Method

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한국방사성폐기물학회 학술논문요약집 (Abstracts of Proceedings of the Korean Radioactive Wasts Society)
한국방사성폐기물학회 (Korean Radioactive Waste Society)
초록

Inorganic and organic ion exchange materials were generally applied to liquid processes in nuclear reactor. In the case of heavy-water reactor (HWR), zeolite, active carbon, anion resin, and cation resin were used to treat liquid processes such as reactor primary coolant cleanup and liquid radioactive waste management system. Then, used ion exchangers were stored at storage tanks. Various kinds of nuclides were adsorbed in ion exchange materials. Especially, C-14, long half-life nuclide, was highly concentrated in anion resin, and waste resin was treated as intermediated level radioactive waste (ILW). Thermal and non-thermal methods such as pyrolysis, incineration, catalytic extraction, acid digestion, and wet oxidation have been studied for treating spent resin. However, destructive methods are not suitable due to massive off gas waste containing radioactive species. To solve this problem, various kinds of processes were developed such as acid stripping, PLO process, activity stripping, thermal treatment, and etc. In this study, microwave method is suggested to treat HWR waste resin. C-14 nuclide was selectively removed from waste resin without decomposition of main structure in waste resin. Radioactive waste resin generated from Wolsung HWR unit 1 and unit 2 was treated using microwave method and 95% of C-14 was successfully removed from the radioactive waste resin.

저자
  • Ki Rak Lee(Korea Atomic Energy Research Institute, 111, Daedeok-daero 989beon-gil, Yuseong-gu, Daejeon) Corresponding author
  • Hwan-Seo Park(Korea Atomic Energy Research Institute, 111, Daedeok-daero 989beon-gil, Yuseong-gu, Daejeon)
  • Geun-il Park(Korea Atomic Energy Research Institute, 111, Daedeok-daero 989beon-gil, Yuseong-gu, Daejeon)
  • Ga Yeong Kim(Korea Atomic Energy Research Institute, 111, Daedeok-daero 989beon-gil, Yuseong-gu, Daejeon)
  • Hyeon-Oh Park(Sunkwang T&S, 65, Techno 3-ro, Yuseong-gu, Daejeon)
  • Gi-Hyeon Kwon(Sunkwang T&S, 65, Techno 3-ro, Yuseong-gu, Daejeon)