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WO3-TiH2 혼합분말의 동결건조 및 수소환원에 의한 W-Ti 다공체 제조 KCI 등재

Fabrication of Porous W-Ti by Freeze-Drying and Hydrogen Reduction of WO3-TiH2 Powder Mixtures

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한국분말야금학회지 (Journal of Korean Powder Metallurgy Institute)
한국분말재료학회(구 한국분말야금학회) (Korean Powder Metallurgy Institute)
초록

Porous W-10 wt% Ti alloys are prepared by freeze-drying a WO3-TiH2/camphene slurry, using a sintering process. X-ray diffraction analysis of the heat-treated powder in an argon atmosphere shows the WO3 peak of the starting powder and reaction-phase peaks such as WO2.9, WO2, and TiO2 peaks. In contrast, a powder mixture heated in a hydrogen atmosphere is composed of the W and TiW phases. The formation of reaction phases that are dependent on the atmosphere is explained by a thermodynamic consideration of the reduction behavior of WO3 and the dehydrogenation reaction of TiH2. To fabricate a porous W-Ti alloy, the camphene slurry is frozen at -30℃, and pores are generated in the frozen specimens by the sublimation of camphene while drying in air. The green body is hydrogen-reduced and sintered at 1000℃ for 1 h. The sintered sample prepared by freeze-drying the camphene slurry shows large and aligned parallel pores in the camphene growth direction, and small pores in the internal walls of the large pores. The strut between large pores consists of very fine particles with partial necking between them.

목차
1. 서 론
 2. 실험 방법
 3. 실험결과 및 고찰
 4. 결 론
 감사의 글
 References
저자
  • 강현지(서울과학기술대학교 신소재공학과) | Hyunji Kang
  • 박성현(서울과학기술대학교 신소재공학과) | Sung Hyun Park
  • 오승탁(서울과학기술대학교 신소재공학과) | Sung-Tag Oh Corresponding Author