논문 상세보기

전처리를 이용한 탄소 나노 섬유의 균일한 SnO2 코팅막 형성 KCI 등재

Formation of Uniform SnO2 Coating Layer on Carbon Nanofiber by Pretreatment in Atomic Layer Deposition

  • 언어KOR
  • URLhttps://db.koreascholar.com/Article/Detail/343759
구독 기관 인증 시 무료 이용이 가능합니다. 4,000원
한국분말야금학회지 (Journal of Korean Powder Metallurgy Institute)
한국분말재료학회(구 한국분말야금학회) (Korean Powder Metallurgy Institute)
초록

Carbon nanofibers (CNF) are widely used as active agents for electrodes in Li-ion secondary battery cells, supercapacitors, and fuel cells. Nanoscale coatings on CNF electrodes can increase the output and lifespan of battery devices. Atomic layer deposition (ALD) can control the coating thickness at the nanoscale regardless of the shape, suitable for coating CNFs. However, because the CNF surface comprises stable C–C bonds, initiating homogeneous nuclear formation is difficult because of the lack of initial nucleation sites. This study introduces uniform nucleation site formation on CNF surfaces to promote a uniform SnO2 layer. We pretreat the CNF surface by introducing H2O or Al2O3 (trimethylaluminum + H2O) before the SnO2 ALD process to form active sites on the CNF surface. Transmission electron microscopy and energy-dispersive spectroscopy both identify the SnO2 layer morphology on the CNF. The Al2O3-pretreated sample shows a uniform SnO2 layer, while island-type SnOx layers grow sparsely on the H2Opretreated or untreated CNF.

목차
Abstract
 1. 서 론
 2. 실험 방법
 3. 결과 및 고찰
 4. 결 론
 감사의 글
 References
저자
  • 김동하(서울과학기술대학교 신소재공학과) | Dong Ha Kim
  • 류도형(서울과학기술대학교 신소재공학과) | Doh-Hyung Riu
  • 최병준(서울과학기술대학교 신소재공학과) | Byung Joon Choi Corresponding Author