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패각 분말기반 과산화칼슘 제조와 산소 유리 특성 KCI 등재

Preparation of Calcium Peroxide Originated from Oyster Shell Powder and Oxygen Releasing Ability

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한국환경과학회지 (Journal of Environmental Science International)
한국환경과학회 (The Korean Environmental Sciences Society)
초록

Bioremediation in situ is heavily dependent on the oxygenic environment which would privide the dwelling microorganism with sufficient oxygen. The situation could be easily resolved with supply of an Oxygen Releasing Compound (ORC). In this paper we prepared that sort of material out of oyster shell powder (mostly calcium carbonate) that prevails every shore areas of the country. We used two different oxidizing methods in the first step of the whole manufacturing process–conventional heating in a furnace and an ultrasound generator to obtain calcium oxide. Then that calcium oxide was further oxidized into calcium peroxide which may release oxygen under a moisturized condition. The oxygen releasing experiments were run to test the performance of our products, and to determine the gas kinetics during the experiments. Interestingly, calcium peroxide derived from ultrasound treatment was much more energy-effective as ORC than that from furnace heating although the heat derived process was better than that of ultrasound in terms of oxygen content and its releasing rate. We also found that most of the data collected from the gas releasing experiments fairly supported an ordinary 1st order kinetics to oxygen concentration, which shaped a sharp discharge of oxygen at the very early moment of each test.

목차
Abstract
 1. 서 론
 2. 재료 및 방법
  2.1. 굴 패각 분말 준비
  2.2. CaO2 제조 방법
 3. 결과 및 고찰
  3.1. 열 분해법에 기초한 CaO2의 산소 발생 거동
  3.2. 초음파 분해를 기초로 한 CaO2의 산소발생 거동
  3.3. 산소 발생의 동력학
 4. 결 론
 REFERENCES
저자
  • 유길선(순천향대학교 에너지환경공학과) | Gilsun Yoo (Department of Energy and Environmental Engineering, Soonchunhyang University)
  • 안지은(순천향대학교 에너지환경공학과) | Jieun An (Department of Energy and Environmental Engineering, Soonchunhyang University)
  • 조대철(순천향대학교 에너지환경공학과) | Daechul Cho (Department of Energy and Environmental Engineering, Soonchunhyang University) Corresponding author
  • 권성현(경상대학교 해양환경공학과(공학연구원)) | Sung Hyun Kwon (Department of Marine Environmental Engineering/Engineering Research Institute(ERI), Gyeongsang National University)