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산화그래핀을 적용한 고반응성 Al/CuO 나노복합재 제조 및 분석 KCI 등재

Fabrication and Characterization of Highly Reactive Al/CuO Nano-composite using Graphene Oxide

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한국분말야금학회지 (Journal of Korean Powder Metallurgy Institute)
한국분말재료학회(구 한국분말야금학회) (Korean Powder Metallurgy Institute)
초록

The aluminum (Al)/copper oxide (CuO) complex is known as the most promising material for thermite reactions, releasing a high heat and pressure through ignition or thermal heating. To improve the reaction rate and wettability for handling safety, nanosized primary particles are applied on Al/CuO composite for energetic materials in explosives or propellants. Herein, graphene oxide (GO) is adopted for the Al/CuO composites as the functional supporting materials, preventing a phase-separation between solvent and composites, leading to a significantly enhanced reactivity. The characterizations of Al/CuO decorated on GO(Al/CuO/GO) are performed through scanning electron microscopy, transmission electron microscopy, and energy dispersive X-ray spectroscopy mapping analysis. Moreover, the functional bridging between Al/CuO and GO is suggested by identifying the chemical bonding with GO in X-ray photoelectron spectroscopy analysis. The reactivity of Al/CuO/GO composites is evaluated by comparing the maximum pressure and rate of the pressure increase of Al/CuO and Al/CuO/GO. The composites with a specific concentration of GO (10 wt%) demonstrate a well-dispersed mixture in hexane solution without phase separation.

목차
Abstract
 1. 서 론
 2. 실험방법
  2.1 산화 그래핀 제조
  2.2 Al/CuO/GO 나노복합재 제조
 3. 결과 및 고찰
  3.1 Al/GO 나노복합재 분석
  3.2 Al/CuO/GO 나노복합재 분석
  3.3 Al/CuO/GO 나노복합재 반응성
 4. 결 론
 References
저자
  • 임예슬(국방과학연구소 제 4기술연구본부) | YeSeul Lim (Agency for Defence Development, The 4th R&D Institute) Corresponding Author