3D printing technology is a processing technology in which 3D structures are formed by fabricating multiple 2D layers of materials based on 3D designed digital data and stacking them layer by layer. Although layers are stacked using inkjet printing to release various materials, it is still rare for research to successfully form a product as an additive manufacture of multi-materials. In this study, dispersion conditions are optimized by adding a dispersant to an acrylic monomer suitable for inkjet printing using Co3O4 and Al2O3. 3D structures having continuous composition composed of a different ceramic material are manufactured by printing using two UV curable ceramic inks whose optimization is advanced. After the heat treatment, the produced structure is checked for the formation and color of the desired crystals by comparing the crystalline analysis according to the characteristics of each part of the structure with ceramic pigments made by solid phase synthesis method.