PURPOSES : Nitrogen oxides (NOx) are the main precursors to generate fine particulate matter, which significantly contribute to air pollution. NOx gases are transmitted into the atmosphere in large quantities, especially in areas with a high volume of traffic. Titanium dioxide (TiO2), which is a photocatalytic reaction material, is very efficient for removing NOx. The application of TiO2 to concrete road structures is a good alternative to remove NOx. Generally, TiO2 concrete is produced by mixing concrete with TiO2 . However, a significant amount of TiO2 in concrete cannot be exposed to air pollutants or UV. Therefore, an alternative method of penetrating TiO2 into horizontal concrete structures using a surface penetration agent was proposed in a previous study. This method may not only be economical but also applicable to various types of horizontal concrete structures. However, the TiO2 penetration method may not be applied to vertical structures because it has a mechanism for the penetration of TiO2-containing penetration agents via gravity and capillary forces. Therefore, this study aimed to evaluate the applicability of the pressurized TiO2 fixation method for existing vertical road structures. METHODS : For the application of vertical concrete structures — such as retaining walls, side ditches, and barriers — the applicability of a static and dynamic pressurized TiO2 fixation method was evaluated according to the experimental conditions, considering the amount of pressure and time. The penetration depth and distribution of TiO2 particles in the concrete specimen were measured using SEM/EDAX. In addition, the NOx removal efficiencies of TiO2 concrete were evaluated using the NOx analysis system. RESULTS : As a result of measuring the penetration depth and distribution of TiO2 in the concrete, it was found that the surface-predicted mass ratio increased with increasing pressure and time. In the case of the static pressurized fixation method, it was confirmed that a pressure time of at least 10 s at a pressure of 0.2 MPa and 5 s at a pressure higher than 0.3 MPa were required to achieve a NOx removal efficiency higher than 40 %. Conversely, for the dynamic pressurized fixation method applying a hitting energy of 16.95 J, NOx removal efficiencies higher than 50 % were secured in a pressure time of more than 3 s. CONCLUSIONS : The results of this study showed that the static and dynamic pressurized TiO2 fixation method was advantageous in penetrating and distributing TiO2 particles into the concrete surface to effectively remove NOx. It was confirmed that the proposed method to remove NOx was sufficiently applicable to existing vertical concrete road structures.

PURPOSES : NOx is a particle matter precursor that is harmful to humans. Various methods of removing NOx from the air have been developed. TiO2 and activated carbon are particularly useful materials for removing NOx, and the method is known as particulate matter precursor reduction. The removal of NOx using TiO2 requires sunlight for the photocatalytic reaction, whereas activated carbon absorbs NOx particles into its pores after contact with the atmosphere. The purpose of this study is to evaluate the NOx removal efficiency of TiO2 and activated carbon applied to concrete surfaces using the penetration method. METHODS : Surface penetration agents, such as silane-siloxane and silicate, were used. Photocatalyst TiO2 and adsorbent activated carbons were selected as the materials for NOx removal. TiO2 used in this study was formed by crystal structures of anatase and rutile, and plant-type and coal-type materials were used for the activated carbon. Each surface penetration agent was mixed with each particulate matter sealer at a concentration ratio of 8:2, and the mixtures were sprayed onto the surface. The NOx removal efficiency was evaluated using NOx removal efficiency equipment fabricated in compliance with the ISO 22197-1 standard. RESULTS : Anatase TiO2 showed a maximum NOx removal efficiency of 48% when 500 g/m² was applied. However, 500 g/m² of rutile TiO2 showed a NOx removal efficiency of up to 10%. When 700 g/m² of coal-based activated carbon and plant-based activated carbon was used, NOx removal efficiencies of up to 11% and 14%, respectively, were obtained. CONCLUSIONS : Rutile TiO2, a coal-based activated carbon, and plant-based activated carbon have lower NOx removal efficiencies than anatase TiO2. A lower amount of anatase TiO2 (500 g/m²), compared to the other spraying volumes, yielded the most significant NOx removal efficiency under optimal conditions. Therefore, it is recommended that 500 g/m² of anatase TiO2 should be sprayed onto concrete structures to improve the economic and long-term performance of these structures.

PURPOSES : Concrete pavement is excellent in structural performance and durability. However, its functionality – such as noise and skid resistance – is a shortcoming. Functionality such as noise reduction and skid resistance of concrete pavement is affected by the texture surface, and the texture surface is classified according to the length of the wavelength. In recent years, Fine-size exposed aggregate concrete pavement has been applied, which has excellent structural performance and durability, and secures functionalities such as noise reduction and long-term skid resistance by randomly forming texture surface. Fine-size exposed aggregate concrete pavements are constructed by removing the surface cement binder to randomly expose coarse aggregate and their functionality is mainly governed by the surface texture. However, deteriorated concrete by tire-pavement friction and deicing agent may cause abrasion and aggregate loss on the surface texture; thus reducing their functional performances. Abrasion is created by the thin cutoff of aggregate texture under repeated tire-pavement friction. In addition, aggregate loss is defined by the detachment of aggregates from cement binder. This study aims to evaluate the abrasion and aggregate loss of Fine-size exposed aggregate concrete pavement surface texture under tire-pavement friction and scaling tests. METHODS : In the study, abrasion and aggregate loss of tining and exposed aggregate concrete surface treatments were evaluated. Deterioration of each surface treatment was replicated by scaling test under ASTM C 672 test method. Afterward, abrasion test was conducted by ASTM C779 to simulate the tire-pavement friction under traffic. Consequently, abrasion and aggregate loss were measured. RESULTS : Abrasion depth of non-scaling tining, 10-mm EACP, and 8-mm EACP was 1.76, 1.12, and 1.01mm, respectively. Compared to scaling surface treatments, the difference of abrasion depth in tining texture was the largest with value of 0.4mm. For both textures of finesize exposed aggregate concrete, abrasion depth difference was about 0.1mm. Moreover, The 10-mm EACP exhibited a 2.6% of aggregate loss rate caused by tire-pavement friction before conducting concrete deterioration test. After 40-cycle scaling test, aggregate loss increased up to 12.2%. For 8-mm EACP, aggregate loss rate was 1.7% on non-scaling concrete. Further, this rate was magnified up to 7.3% for the 40-cycle scaling concrete. CONCLUSIONS : Under non-scaling or scaling tests, fine-size exposed aggregate concrete pavement showed better abrasion resistance than tining texture since tining was formed by aggregates and cement binder. Additionally, rate of aggregate loss was significant when EACP experienced the deicing agent under numerous cycles of freeze-thaw action.

PURPOSES : Pavement growth (PG) of concrete pavement has been recognized as a major concern to highway and airport engineers as well as to road users for many years. PG is caused by the pressure generation in the concrete pavement as a result of a rise of the concrete temperature and moisture. PG could result in concrete pavement blowup and damage the adjacent or the nearby structures such as bridge structures. The amount of the PG is affected by the complicated interactions of numerous factors such as climatic condition, amounts of incompressible particles (IP) infiltration into the joints, pavement structure, and materials. Trigger temperature for pavement growth (TTPG) is defined as the concrete temperature when all transverse cracks or joints within the expansion joints completely close and generating a pressure in the pavement section. It is one of the most critical parameters to evaluate the potential of PG occurring in the pavement. Unfortunately, there are no available methods or guidelines for estimating TTPG. Therefore, this study aims to provide a methodology to predict TTPG of a concrete pavement section. METHODS : In this study, a method to evaluate the TTPG and its influencing factors using the field measured data of concrete pavement expansions is proposed. The data of the concrete pavement expansions obtained from the long-term monitoring of three concrete pavement sections, which are I-70, I-70N, and Md.458, in Maryland of United Stated, were used. The AASHTO equation to estimate the joint movement in concrete pavement was used and modified for the back-calculation of the TTPG value. A series of the analytical and numerical solutions presented in the literatures were utilized to predict the friction coefficient between the concrete slab-base and to estimate the maximum concrete temperature of these three pavement sections. RESULTS : The estimated maximum concrete temperature of these three pavement sections yearly exhibited relatively constant values, which range from 40 to 45 °C. The results of the back-calculation revealed that the TTPG of the I-70 and Md.58 sections decreased with time. However, the TTPG of the I-70N section tended to be relatively constant from the first year of the pavement age. CONCLUSIONS : The estimation of the TTPG for the three concrete pavement sections showed that the values of the TTPG gradually decreased although the yearly maximum concrete pavement temperature did not change significantly.

PURPOSES: Nitrogen oxide (NOx) is a particulate matter precursor, which is a harmful gas contributing to air pollution and causes acid rain. The approaching methods for NOx removal from the air are the focus of numerous researchers worldwide. Titanium dioxide (TiO2) and activated carbon are particularly useful materials for NOx removal. The mechanism of NOx elimination by using TiO2 requires sunlight for a photocatalytic reaction, while activated carbon absorbs the NOx particle into the pore itself after contact with the atmosphere. The mixing method of these two materials with concrete, coating, and penetration methods on the surface is an alternative method for NOx removal. However, this mixing method is not as efficient as the coating and penetration methods because the TiO2 and the activated carbon inside the concrete cannot come in contact with sunlight and air, respectively. Hence, the coating and penetration methods may be effective solutions for directly exposing these materials to the environment. However, the coating method requires surface pretreatment, such as milling, prior to securing contact, and this may not satisfy economic considerations. Therefore, this study aims to apply TiO2 and activated carbon on the concrete surface by using the penetration method. METHODS : Surface penetrants, namely silane siloxane and silicate, were used in this study. Photocatalyst TiO2 and adsorbent activated carbons were selected. TiO2 was formed by the crystal structures of anatase and rutile, while the activated carbons were plant- and coal-type materials. Each penetrant was mixed with each particulate matter reductant. The mixtures were sprayed on the concrete surface using concentration ratios of 8:2 and 9:1. A scanning electron microscopy with energy dispersive X-ray equipment was employed to measure the penetration depth of each specimen. The optimum concentration ratio was selected based on the penetration depth. RESULTS: TiO2 and activated carbon were penetrated within 1 mm from the concrete surface. This TiO2 distribution was acceptable because TiO2 and activated carbon locate to where they can directly come in contact with sunlight and air pollutant, respectively. Infiltration to the concrete surface was easily achieved because the concrete voids were bigger than the nanosized TiO2 and microsized activated carbon. The amount of penetration for each particulate matter reductant was measured from the concrete surface to a certain depth. CONCLUSIONS : The mass ratio on the surface can be predicted from the mass ratio of the particulate matter reductant measurement distributed through the penetration depth. The optimum mass ratio was also presented. Moreover, the mixtures of TiO2 with silane siloxane and activated carbon with silicate were recommended with an 8:2 concentration ratio.

PURPOSES : This study investigates the abrasion characteristics of coarse aggregate using the Los Angeles (L.A.) abrasion test and the accelerated polishing machine (APM) test. The coarse aggregates are randomly exposed on the surface of asphalt concrete pavements and on exposed aggregate concrete pavements. The exposed aggregates play a very important role in providing skid resistance. Therefore, the adequate abrasion resistance of coarse aggregate must be ensured to maintain the skid resistance during service life. In Korea, the LA abrasion test is conducted according to the KS F 2508 standard for the evaluation of the abrasion resistance of coarse aggregate. However, the road surface abrasion is caused by the friction between the tire and the road surface structure; hence, whether the LA abrasion test, which evaluates the abrasion caused by the impact of coarse aggregates and steel balls, can evaluate the road surface abrasion is questionable. A comparison and an analysis between the APM and LA abrasion tests were conducted herein to evaluate the road abrasion. An analysis was also performed to analyze whether the abrasion characteristics appeared depending on the type of coarse aggregate. METHODS: The results of the APM and LA abrasion tests for various aggregate types were obtained through a series of experiments and literature reviews. The correlation between the LA abrasion loss and the PV data was derived. In addition, the influence of the aggregate type on the abrasion resistance was investigated. RESULTS : An abrasion resistance database was established, and the relationship between the rock types and the abrasion resistance was statistically determined. The results showed that the PV was increased to 0.54 along with a 1% increasing rate of the LA abrasion loss with a 0.67 coefficient of determination. The abrasion resistance was also influenced by the aggregate type, which was found to be statistically significant. CONCLUSIONS: A good relationship between the PV and the LA abrasion loss was obtained, allowing the use of the LA abrasion test (KS F 2508) alone, to reasonably evaluate the abrasion resistance of the exposed aggregate texture. The aggregate types were also found to have an impact on the abrasion resistance.

PURPOSES : In Korea, asphalt overlay has been used as a typical alternative rehabilitation method for deteriorated pavements. However, asphalt overlay has problems due to poor bonding of the asphalt overlay and the old concrete. Recently, concrete overlays, which have advantages such as long-term durability and high structural capacity to carry heavy traffic, have been considered for rehabilitation construction. However, concrete overlays have limitations such as difficulty in opening to traffic and pavement noise. Recently, an appropriate fine-size exposed aggregate concrete pavement technique was reported to solve these problems. Therefore, this study aims to suggest an optimum mixture design of fine-size exposed aggregate concrete overlay (EACO) that can ensure low noise and early strength. METHODS : The optimum mixture design of fine-size EACO is determined to ensure adequate structural performance for early traffic opening and good functional performances such as low noise. Therefore, the optimum mixture proportion is determined based on the optimum design of aggregate content to produce a low-noise pavement texture by controlling the exposed aggregate number (EAN) and mean texture depth (MTD). RESULTS : The water-cement ratio and unit cement ratio were used to determine the mixture designs to achieve workability and adequate strength for early traffic opening. The texture was determined by selecting the maximum size of coarse aggregate smaller than 10 mm with an S/a ratio of less than 30% for low noise. With these mixture proportions, the EAN and MTD were 50±5 / 25cm2 and 1.0±0.2 mm. Respectively, which meet the criteria for EACO. CONCLUSIONS: In this study, an optimum mixture design of EACO for early traffic opening and low noise is suggested by using earlyhigh strength cement, and the pavement texture is implemented considering EAN and MTD. In addition, a pavement surface texture criterion is suggested for the quality control of EACO.

PURPOSES : Exposed aggregate concrete pavements have been adopted in several countries because of their advantages of pavement texture characteristics, which can produce low tire-pavement noise and higher load-carrying capacities. The magnitude of tire-pavement noise greatly depends on the wavelength of pavement texture. The wavelength of exposed aggregate concrete pavement can be controlled with maximum sizing and by controlling the amount of coarse aggregates in the concrete mixture. In this study, the maximum size and the amount of coarse aggregate in the exposed aggregate concrete pavement are investigated to produce equal levels of wavelength in the asphalt pavement. METHODS: A simple method to measure the average wavelength of pavement texture is introduced. Subsequently, the average wavelength of typical asphalt pavement is investigated. A set of mixture designs of exposed aggregate concrete with three maximum-sized coarse aggregates, and three amounts of coarse aggregate are used. The average wavelengths are measured to find the mixture design needed to produce equal levels of wavelength as typical asphalt pavement. RESULTS : With a cement content of 420 kg/m3 and fine aggregate modulus of 30%, the number of exposed aggregates was 48, and the shortest texture depth provided a wavelength of 4.2 mm. According to the number of exposed aggregates, the exposed aggregate concrete pavement could be rendered low-noise, because its wavelength was similar to that of asphalt pavement ranging from 3.9 to 4.4 mm. CONCLUSIONS : Selection of appropriate maximum sizes and the amount of coarse aggregates for exposed aggregate concrete pavement can produce a wavelength texture closely resembling that of asphalt pavement. Therefore, the noise level of exposed aggregate concrete pavement can be reduced with an appropriate maximum size and the amount of coarse aggregates are employed.

PURPOSES : In Korea, concrete pavements with transverse tining, which have excellent skid resistance, have been mainly constructed to secure road bearing capacity and safety. However, transverse tining has higher noise level of approximately 4-5 dB(A) compared with asphalt pavement. As a method to determine low-noise characteristics of concrete pavements, the fine-size exposed aggregate concrete pavement (EACP) has been studied in Korea and abroad. The surface of EACPs consists of exposed coarse aggregates and 2-3 mm removal surface mortar. EACPs have the advantages of maintaining low-noise and adequate skid-resistance levels during the performance period. Although EACPs have been widely studied to reduce noise, quantitative noise analysis with various paving methods has not been performed owing to differences in mixture proportioning, construction conditions, environmental conditions, and measurement methods. Therefore, the purpose of this study is to investigate the low-noise characteristics of fine-size EACPs by comparing noise with various paving methods, including concrete and asphalt pavements. METHODS: In this study, noise data were collected to quantitatively analyze the low-noise characteristics of EACPs compared with various paving methods such as transverse tining, longitudinal tining, SMA, and HMA. RESULTS: The evaluation of the low-noise characteristics of EACPs compared with transverse tining showed that the relative noise of 13 mm EACP with transverse tining was reduced by approximately 2% at 60 km/h, 4% at 80 km/h, and 5% at 100 km/h. The relative noise of 10 mm EACP with transverse tining was reduced to 3%, 7%, and 8% at 50 km/h, 80 km/h, and 100 km/h, respectively. In addition, it was confirmed that the noise of 10 mm EACP was similar to that of asphalt pavement. CONCLUSIONS : It was confirmed that EACP using 10 mm coarse aggregates generates lower noise than that using 13 mm coarse aggregates. Therefore, the use of coarse aggregates smaller than 10 mm needs to be considered to improve the low-noise effect of EACP.

PURPOSES: A composite pavement utilizes both an asphalt surface and a concrete base. Typically, a concrete base layer provides structural capacity, while an asphalt surface layer provides smoothness and riding quality. This pavement type can be used in conjunction with rollercompacted concrete (RCC) pavement as a base layer due to its fast construction, economic efficiency, and structural performance. However, the service life and functionality of composite pavement may be reduced due to interfacial bond failure. Therefore, adequate interfacial bonding between the asphalt surface and the concrete base is essential to achieving monolithic behavior. The purpose of this study is to investigate the bond characteristics at the interface between asphalt (HMA; hot-mixed asphalt) and the RCC baseMETHODS: This study was performed to determine the optimal type and application rate of tack coat material for RCC-base composite pavement. In addition, the core size effect, temperature condition, and bonding failure shape were analyzed to investigate the bonding characteristics at the interface between the RCC base and HMA surface. To evaluate the bond strength, a pull-off test was performed using different diameters of specimens such as 50 mm and 100 mm. Tack coat materials such as RSC-4 and BD-Coat were applied in amounts of 0.3, 0.5, 0.7, 0.9, and 1.1ℓ/m2 to determine the optimal application rate. In order to evaluate the bond strength characteristics with temperature changes, a pull-off test was carried out at -15, 0, 20, and 40 °C. In addition, the bond failure shapes were analyzed using an image analysis program after the pull-off tests were completed.RESULTS: The test results indicated that the optimal application rate of RSC-4 and BD-Coat were 0.8ℓ/m2, 0.9 ℓ/m2, respectively. The core size effect was determined to be negligible because the bond strengths were similar in specimens with diameters of 50 mm and 100 mm. The bond strengths of RSC-4 and BD-Coat were found to decrease significantly when the temperature increased. As a result of the bonding failure shape in low-temperature conditions such as -15, 0, and 20 °C, it was found that most of the debonding occurred at the interface between the tack coat and RCC surface. On the other hand, the interface between the HMA and tack coat was weaker than that between the tack coat and RCC at a high temperature of 40 °C.CONCLUSIONS: This study suggested an optimal application rate of tack coat materials to apply to RCC-base composite pavement. The bond strengths at high temperatures were significantly lower than the required bond (tensile) strength of 0.4 MPa. It was known that the temperature was a critical factor affecting the bond strength at the interface of the RCC-base composite pavement.

아스팔트 표층과 콘크리트 기층으로 구성된 복합포장은 강성기층의 높은 지지력과 아스팔트 표층의 소음저감, 평탄성, 미끄럼저항성 등을 확보할 수 있는 장점을 가진 포장이다. 롤러다짐콘크리트(RCC)는 빠른 시공속도와 경제성을 가져 복합포장의 기층으로 활용된다. 그러나 이러한 복합포장의 공용수명 및 성능은 포장 계면의 부착파괴로 인해 저하된다. 그러므로 아스팔트 표층과 콘크리트 기층사이의 적절한 부착은 복합포장의 단일거동(monolithic behavior)을 통한 포장성능 및 공용수명 확보를 위해 필수적이다. 복합포장에 적용되는 아스팔트와 택코트 재료는 역청혼합물을 포함하고 있는 재료로 시간-온도에 의존적인 점탄성 특성을 나타내며 콘크리트는 환경적 조건(온도 등)에 따라 컬링 및 수축·팽창 등이 발생하는 재료적 특성을 가진 재료이다. 복합포장의 역학적 거동은 이러한 각 재료 및 포장계면의 특성에 기반 한다. 그러므로 부착 성능을 평가함에 있어 국내의 계절별 기후에 따른 복합포장 내 온도특성을 반영하여 부착성능이 평가되어야 하며 겨울철 반복적 동결-융해가 발생하는 국내의 기후특성상 이를 고려한 부착내구성 평가 등이 수행되어야 한다. 그러나 국내의 경우 20 ℃의 표준온도만을 적용한 부착성능 평가를 통해 품질관리가 수행되고 있으며 이와 관련된 연구가 미흡한 실정이다. 또한, 복합포장의 경제적 강성기층으로 본 연구에 적용된 롤러다짐콘크리트(RCC)는 적은 단위수량 및 단위시멘트량을 사용하여 시멘트 페이트의 양이 일반콘크리트 포장에 비해 적으며 포설 후 롤러전압다짐이 적용되기 때문에 불규칙한 거친 표면을 형성한다. 그러므로 이러한 특성을 고려한 적정 택코트 재료 및 살포량 선정이 요구된다. 따라서, 본 연구에서는 롤러다짐콘크리트-기층 복합포장에 대한 부착특성을 분석하고자 하였다. RSC-4와 BD-Coat 두 종류의 택코트 재료가 실험되었으며 각 재료의 최적살포량을 선정하고자 0.3, 0.5, 0.7, 0.9, 1.1 ℓ/m2의 살포량이 적용되었다. 추가적으로 100 mm, 50 mm에 대한 core size effect가 고려되었다. 온도 조건에 따른 인장부착특성은 -15, 0, 20 40 ℃의 각 온도 조건에서 실험되었으며 반복적 동결-융해가 발생하는 국내의 기후 특성을 고려하고자 0, 50, 100 Cycle에 대한 부착내구성 실험이 수행되었다. 실험의 각 부착파괴단면은 이미지분석프로그램을 통해 검토 되었으며 검토 내용을 바탕으로 부착특성과 부착파괴단면과의 상관관계가 분석되었다.