본 연구에서는 세계적으로 문제가 되고 있는 하천 및 수계내의 중금속 오염 방지와 대책을 강구하기 위해 고로슬래그가 중금속흡착에 유리한 물리, 화학적 특성을 지녔다고 판단하여 흡착제로서의 중금속흡착능이 충분한지에 대해 검토하였다. 흔히 중금속흡착제로 알려진 활성탄의 경우 제거효율은 좋지만, 경제적인 부담감을 안고 있으며, 현재 최근 활발한 산업 활동으로 인하여 나오는 건설폐기물이나 산업부산물의 문제를 해결하기 위해 이를 이용한 중금속 제거 기술이 보고되고 있다. 특히, 고로슬래그의 경우 선철 1t당 0.5~1t정도의 양이 배출되며, 이에 고로슬래그의 흡착제로서의 사용 검토가 된다면 제철부산물의 처리와 하천 및 수계내의 수질개선에도 도움이 된다고 판단했다. 고로슬래그는 체가름시험을 통하여 1.2~2.5mm의 치수를 사용하였으며, 중금속은 Cd, Cu, Pb, Zn으로 선정하여 등온흡착실험을 진행하였다. 중금속의 초기농도는 1ppm, 2ppm, 5ppm로 설정하고 120분간 128rpm으로 교반하여 진행하였으며, 일정 시간간격을 두어 샘플을 채취하여 시간 당 중금속의 부하량을 산정하였다. 그 결과 Cd의 경우 120분간 선형의 그래프를 나타내며 제거 되었으며, Cu, Pb, Zn은 20~30분까지 급격하게 중금속의 농도가 감소하다가 120분까지 서서히 감소되었다. 초기농도에 관계없이 120분동안 중금속 제거량은 총 1ppm 정도였으며, 결과적으로 고로슬래그의 중금속 흡착제로서의 흡착능이 뛰어나다고 판단된다. 이를 통해 하천 및 수계내의 수질개선을 위한 비점오염저감시설이나 장치의 흡착제나 또는 여과저류지등의 여재로 이용할 수 있을 것으로 기대된다.

This study examined dynamic and characteristics and chloride penetration of concrete mixed with large amount of FA and BFS, which are considered for positive application to construction fields with purpose of long-tern durability of concrete structures. As a result of strength test on FA and BFS, FA concrete showed higher increase of strength compared to OPC, when FA4000 and FA5000 were mixed 30%, respectively. For BFS concrete, those mixed with 30% and 50% of BFS8000, respectively, showed higher or equivalent strength compare to OPC. As a result of test of chloride penetration on FA and BFS, diffusion coefficients of concrete mixed with 30% FA4000 and FA5000, respectively, showed to restrain average 6.5% of diffusion coefficient compared to OPC. And in case of BFS concrete, those mixed with BFS6000 and BFS8000, restrained diffusion of chloride ions 253% and 336%, respectively, compared to OPC. Therefore, Mixing 50% of BFS was most efficient in order to maximize restraint of chloride penetration according to metathesis of large amount. For relation between compression strength and diffusion coefficient of FA and BFS concrete, as strength increased, diffusion coefficient decreased. In this study, when mixing FA and BFS to concrete for long-run durability and restraint against chloride penetration, for FA, mixing it to concrete with less or equivalent 30% of replacement rate was most efficient. And for BFS, as fineness was higher and mixing it to concrete with less or equivalent 50% of replacement rate, there were results of higher strength compared to OPC and more efficient restraint of chloride ions.

본 연구에서는 표준실험체 (BSS), 순환굵은골재와 고로슬래그 미분말의 치환과 하이브리드섬유를 보강한 실험체 (BSPRR1, BSPRR2시리즈), 순환굵은골재와 고로슬래그 미분말의 치환과 PVA섬유를 보강한 실험체 (BSPG시리즈)로 총 13개의 실험체를 실물크기의 1/2로 축소 제작하여 실험을 수행하였다. 실험을 통하여 얻어진 결과를 비교⋅분석하여 하중-변위, 파괴형태, 최대내력 등을 규명함으로써 구조성능의 개선정도를 평가하였다. 실험결과 순환굵은골재와 고로슬래그 미분말을 치환한 콘크리트에 하이브리드섬유를 보강한 실험체 (BSPRR1, BSPRR2시리즈)의 경우 표준실험체 (BSS)에 비하여 압축강도는 최대 13%, 최대내력은 4~21%, 연성능력은 각각 4~28% 증가하는 결과를 나타내었다. 그리고 또한, 충분한 연성적인 거동과 안정적인 휨인장 파괴를 나타내었다.

Carbon dioxide generated from construction materials and construction material industry among the fields ofconstruction is approximately 67million tons. It is about 30% of the carbon dioxide generated in the fields of construction.In order to reduce carbon dioxide in the fields of construction, it is necessary to control the use of fossil fuel consumedand decrease carbon emission by reducing the secondary and tertiary curing generating carbon dioxide in constructionmaterial industry. Therefore, this study produced an extrusion panel by using cement as the base materials and substitutingbinding materials up to 40% to analyze strength characteristics. According to the results of strength characteristics bythe replacement binder (Low energy curing Admixture) showed an apparent active strength improvement. In particular,specimens substituting binder as 45% indicated the greatest strength improvement. When binding materials was used withsubstitution, it showed strength characteristics similar or higher than specimens made from tertiary autoclave curing assecondary steam curing.

Reaction degree of ground granulated blast furnace slag(GGBFS) in cement paste was measured by water-binder ratio and GGBFS replacement ratio, curing temperature with ages using selective dissolution. In result of experimental, when water-binder ratio and curing temperature were high and replace ratio of GGBFS was low, reaction degree was estimated high.

This study evaluated compressive strength on the slurry for HPFRCC using blast- furnace slag with various blain as a basic study for developing alternative technology of the existing HPFRCC.

The objective of this paper is to investigate the effect of spreading time of waste cooking oil (WCO) on durability of high volume blast furnace slag concrete. Carbonation and resistance to chloride attack were measured according to spreading time of WCO. WCO was spreaded on the surface of the concrete with different curing condition after demolding. Blast furnace slag with 60% was incorporated into concrete with 45% of W/B. Test results indicated that carbonation and penetration resistance of chloride attack had favorable results with the condition of 28days water curing and spreading WCO.

This study investigated the effect of cement type and ground granulated blast furnace slag (GGBS) on the mechanical properties and workability of grout for offshore PSC structures. As the replacement ratio of GGBS increased, the flowability of the grout increased and both intial and final setting times of grout was delayed regardless of cement type. However, the effects of GGBS on the bleeding of grout were different according to the type of cement: as the ratio of GGBS increased, less bleeding was observed for the grout with typeⅠ cement whereas higher bleeding was generated for the grout with type Ⅲ cement. However, there was no significant difference in their compressive strength at 28 day according the different replacement ratio of GGBS from 0 to 40%.

In this study, high performance fiber composites has developed using GGBS and Flyash with PVA fiber. Thus, four mixtures was determined accoding to the ratio of binder. A series of experiments, including slump flow, compressive strength, uniaxial tensile strength tests were carried out to characterize the mechanical properties of the fiber composites. The result of tests, slump flow showed an average 428mm and tensile strain 2% of behavior strain hardening of due to the occurrence multiple micro crack.

In this study, from the material properties of the aggregates into the actual applications were evaluated for utilizingthe air-cooled blast furnace slag as the coarse aggregates (SG) in PHC piles. The physical and chemical characters ofthe SG were satisfied the standards presented in KS F 2544 for concrete blast furnace slag aggregates. And it was satisfiedthe environmental-factor-evaluation, including the soluble, heavy metal elution and total mercury content, and etc. In casethe non-washed type SG is used, the S/A ratio adjustment according to micro-powder of the aggregate surface and chemicaladmixture adjustment are needed in order to satisfy the aimed material properties. As the replacement ratio of SGincreased, the manifestation rate of compressive strength of the PHC piles was decreased. Particularly, in case non-washingtype SG, the manifestation rate more decreased. Therefore, the elimination of the pop-out materials and cleaning processare necessary for the production process for using the SG as coarse aggregates of PHC Piles

Geopolymer foam block was prepared and its characteristics discussed to evaluate the possibility of replacing blastfurnace slag (below BFS) with melting slag in this study. 10~20wt% of BFS was replaced with melting slag. And also10wt% of mine tailing was replaced with fly ash discharged from municipal solid waste incinerator (below MSWI). Thecompressive strength of foam block prepared was similar to that of foam block prepared without replacing BFS. Andalso it was increased by replacing 10wt% of mine tailing with MSWI fly ash. Considering these results, melting slagmay be used instead of BFS without damaging the quality of foam block.

To evaluate the durability characteristics of low permeable concrete using ground granulated blast-furnace slag with fineness 4,650 cm2/g, carbonation depth was measured. From the test results, persisting period of that was calculated. And it was found that carbonation depth of concrete was proceed 29.5 mm for 100 years.

Mortar laboratory tests were conducted for analyzing fundamental properties of tunnel shotcrete materials used the furnace blast slag power and the surry-type accelerating admixture. This study tested and compared the shotcrete materials used various accelerating admixtures.

이 연구에서는 고로슬래그 미분말을 사용한 프리캐스트 보의 전단성능에 대하여 평가하였다. 실험체는 고로슬래그 미분말 치환율에 따라 총 4체의 실험체를 제작하였다. 모든 실험체는 전단경간비 2.5, 보의 폭 200mm, 유효깊이 300mm이며, 3점 가력을 받는 단순보로 계획하였다. 또한 이 연구에서는 실험체의 전단강도를 예측하기 위하여 기존 전단강도 예측식을 이용하여 실험결과와 비교하였으며, 총 89개의 기존 전단 실험결과를 이용하여 실험결과와 비교 분석하였다. 실험결과, 고로슬래그 미분말을 치환한 실험체는 포틀랜드 시멘트만을 사용한 실험체와 비교분석한 결과 유사한 전단성능을 나타내었다.

In this study, manufactured of cement mortar using high early strength cement(10 ~ 50 wt%) and blast furnace slag powder(50 ~ 90 wt%), according to compressive strength and flexural strength of hardened cement mortar. XRD and SEM were evaluated utilizing the initial cement hydration properties.

Comparing with using ordinary Portland cement, using blast furnace slag as binder in concrete shows low resistance for carbonation phenomenon. In this research, we focus on carbonation of high volume blast furnace-blended concrete, analysis the reason and find a more efficient method which comparing with using ordinary Portland cement, using FC shows better effort on concrete carbonate resistant.

Recently, the amount of the mineral admixture including fly ash and ground granulated blast-furnace slag was increased for the purpose of CO2 gas emission reduction in the concrete industry. However, in the case of korea, estimation model of strength development in concrete structural design code was prescribed a constant value according to cement type and curing method about the portland cement. therefore, the properties of strength development according to time of concrete using fly ash and ground granulated blast-furnace slag does not reflected estimation model of strength development. Accordingly, this paper was evaluated strength according to time on the concrete strength range using fly ash and ground granulated blast-furnace Slag and the strength development constant Bsc of concrete according to the kind of the mineral admixture and mixing ratio was proposed

본 연구에서는 각종 산업부산물 및 도시형 리싸이클링 재료 등의 재생자원을 안전하게 유효 이용할 수 있는 방안으로 BFS 및 SS를 활용한 저강도 콘크리트의 기초적 물성을 파악하기 위하여 플로우 및 블리딩, 일축압축강도, 환경오염평가를 중심으로 실험을 실시하였다. BFS 및 SS를 활용한 저강도 콘크리트의 경우 최소단위수량의 확보를 통한 유동성 개선 및 블리딩율 억제 또한, 현장 적용성을 고려한 일축압축강도의 확보에 있어 사용 잔골재의 차이에 상관없이 BFS 6000 이상을 30% 범위에서 혼입하는 것이 가장 유효한 것으로 나타났다. 특히, SS의 유효 활용 측면에서 BFS 8000을 30% 범위에서 혼합하여 사용하면 유동성 개선 및 블리딩율 억제, 일축압축강도의 확보는 물론 현장 적용에 있어 가장 최적의 배합조건으로 나타났다. 한편, SS를 활용한 시멘트 개량토를 대상으로 유해물질 함유량 및 용출시험을 실시한 결과 모두 환경 기준치 이하를 만족하는 것으로 나타나 주변 환경에 미치는 영향은 없는 것으로 확인되었다.

When manufacturing secondary concrete products, steam and autoclave curing are practiced for the purpose of securing product performance at early phase. CO2 is generated by combustion of fossil fuel at the time of curing. This study is part of a research conducted to minimize curing process which generates CO2. Combination materials types, substitution ratio, strength property per different types of curing are compared and evaluated. Result of the experiment indicates that combination material with 40%　blast furnace slag　substitution and W/B which has gone through 30,40% steam curing are the most outstanding experiment bodies.

These researchers are studying on the hydration model suggestion of cement incorporating blast furnace slag in durability prediction of concrete using hydration model. So in this study it measured hydration heat according to replace ratio, water cement ratio using conduction calorimeter to acquire experiment data for experimental verification and verify hydration heat property when blast furnace slag is incorporated.