본 연구는 기존 (불)투과형 사방댐의 부식 및 시공성 등의 문제를 보완하고자 GFRP와 CFRP를 사용하여 내부식성 투과형 사방댐을 설계한 선행연구의 후속 연구로써 FRP로 제작된 격자형 사방 구조물(Grid)을 설계하여 탈부착이 가능한 투과 형 사방댐을 개발하기 위한 기초 연구이다. 이를 위해 탄소산업진흥원(K-Carbon)의 상용 Grid 제원을 인용하였으며, Grid를 구성 하는 띠(Strip)는 41×21개로 총 4000×2000×1.5 mm의 크기로 설계하였다. Grid의 개발을 위한 기초 연구라는 특성상 Grid의 지지 부(Slot)와 충진재는 파괴되지 않는다고 가정하였으며, FRP의 파괴 이론인 Hashin Damage Criteria에 따라 Grid의 설계하중 작용 시의 안전성을 상용 유한요소해석 프로그램인 ABAQUS로 평가하였다. 그 결과, 0.01~0.03sec 내에서 GFRP와 CFRP Grid가 파괴 되었으며, 이는 Grid의 성능이 충분하지 못함을 의미한다. 이에 따라 Grid의 성능 향상을 위해서 GFRP 및 CFRP(면재)와 Balsa Wood(심재)로 구성된 Sandwich Grid를 개발하였으며, 동일 조건에서 해석을 수행한 결과, Grid 대비 Sandwich Grid가 약 126~140 배 뛰어난 성능을 보였다. 결론적으로 Sandwich Grid를 이용한 탈착형 사방댐은 내구성 및 경제성 측면에서 이점이 분명하다 판 단되지만, 이는 일부 가정 사항과 수치 해석을 기반으로 하는 결과이므로 향후 추가 연구가 수행되어야 할 필요가 있다.

Carbon nanofibers (CNFs) are promising materials for the construction of energy devices, particularly organic solar cells. In the electrospinning process, polyacrylonitrile (PAN) has been utilized to generate nanofibers, which is the simplest and most popular method of creating carbon nanofibers (CNFs) followed by carbonization. The CNFs are coated on stainless steel (SS) plates and involve an electropolymerization process. The prepared Cu, CNF, CNF–Cu, PANI, PANI–Cu, CNF–PANI, and CNF–PANI–Cu electrode materials’ electrical conductivity was evaluated using cyclic voltammetry (CV) technique in 1 M H2SO4 electrolyte solution. Compared to others, the CNF–PANI–Cu electrode has higher conductivity that range is 3.0 mA. Moreover, the PANI, CNF–PANI, and CNF–PANI–Cu are coated on FTO plates and characterized for their optical properties (absorbance, transmittance, and emission) and electrical properties (CV and Impedance) for organic solar cell application. The functional groups, and morphology-average roughness of the electrode materials found by FT–IR, XRD, XPS, SEM, and TGA exhibit a strong correlation with each other. Finally, the electrode materials that have been characterized serve to support and act as the nature of the hole transport for organic solar cells.

In this research, reduced graphene oxide/polypyrrole (rGO/PPy) particles were synthesized and used to measure the amount of dopamine (DA) electrochemically. The obtained rGO/PPy particle was characterized by Fourier Transform Infrared Spectrophotometer (FTIR), UV–Visible Spectrophotometer (UV–Vis), and X-Ray Diffraction Diffractometry (XRD). To investigate the DA sensor performance, cyclic voltammetry (CV) and differential pulse voltammetry (DPV) were used to acquire electrochemical measurements of the sensor. Current values of 1.65 and 5.9 mA were observed in the CV at 0.2 mM and 1.2 mM concentrations of target molecule, respectively. Under optimized conditions, the linear calibration plots were found to exhibit significant sensitivity in the linear range of 0.2 and 1.2 mM, with a corresponding detection limit of 0.061 μM for DA. The results obtained were similar to the sensor results of DA made using precious metals. This work was a demonstration of the feasibility of high-sensitivity electrochemical analysis with conductive carbon materials without the use of precious metals. It was also observed that the cost-effective rGO/PPy exhibited a very high potential for DA detection.

Energy storage for sustainable development and progress of power production industries is vitally important. The energy storage devices are under extensive research from last three decades to ensure the hand-on-hand coordination with power supply phenomenon and to reduce the energy loses in lines. The cost-effective materials are still highly demanding as an electrode material for energy storage devices. Biomass-derived carbon materials are best candidates due to their low cost, relatively high abundance, pollution-free nature. Here, we are reporting a facile two-step green approach to convert Himalayan horse chestnuts (HHCNs) into activated carbon materials. In first step, grinding and pyrolysis of the HHCNs were carried out, and then activation was performed using KOH to enhance the pore density and surface area. HHCNs-derived carbon was utilized as an electrode in electrical double-layer capacitors (EDLCs) with 1 M H2SO4 as an electrolyte. The macroporous structure along with hierarchical porous network acts as an efficient source of transportation of charges across the electrode and separator. Cyclic voltammetry test was taken from 10 to 100 mV/s current and within a range of 0–1 V applied potential; approximately rectangular CV shown mirror response towards current and shown typical EDLCs properties. The proximate analysis confirms the presence of heteroatoms like sulfur, oxygen, and nitrogen which act as carbon dopants. The wettability of HHCNs-derived carbon enhanced due to the various types of oxygen functionalities inherited from the lignin skeletal part. The nitrogen content is primarily responsible for the pseudo-capacitive behavior of HHCNs-codoped carbon. HHCNs-derived activated carbon materials has emerged as a promising electrode material for energy storage applications.

The lithium ion battery has applied to various fields of energy storage systems such as electric vehicle and potable electronic devices in terms of high energy density and long-life cycle. Despite of various research on the electrode and electrolyte materials, there is a lack of research for investigating of the binding materials to replace polymer based binder. In this study, we have investigated petroleum pitch/polymer composite with various ratios between petroleum pitch and polymer in order to optimize the electrochemical and physical performance of the lithium-ion battery based on petroleum pitch/polymer composite binder. The electrochemical and physical performances of the petroleum pitch/polymer composite binder based lithium-ion battery were evaluated by using a charge/discharge test, cyclic voltammetry (CV), electrochemical impedance spectroscopy (EIS) and universal testing machine (UTM). As a result, the petroleum pitch(MP-50)/polymer(PVDF) composite (5:5 wt % ratio) binder based lithium-ion battery showed 1.29 gf mm-1 of adhesion strength with 144 mAh g-1 of specific dis-charge capacity and 93.1 % of initial coulombic efficiency(ICE) value.

Abstract Purpose : This study analyzed physical properties using 1,6-Hexanediol diacrylate (HDDA) as an additive to improve functionality of hydrogel lens such as durability. It was checked whether HDDA can be applied as a crosslinking agent in place of ethylene glycol dimethacrylate (EGDMA). Methods : Polymerization used thermal polymerization and photopolymerization methods, and HDDA was added to each polymerization method at a ratio of 1∼20%. Optical and physical characteristics of the manufactured lens were evaluated by measuring spectral transmittance, refractive index, water content, tensile strength, contact angle, and AFM. Results : Regardless of the polymerization method, the tensile strength ranged from 0.232~0.408 kgf/mm2 in thermal polymerization and from 0.146~0.429 kgf/mm2 depending on the addition ratio of HDDA. In addition, as a result of using HDDA instead of EGDMA, it was confirmed that the physical characteristics of the lens were similar to that of EGDMA, and in the case of tensile strength, HDDA was much improved. Conclusion : HDDA has been shown to be effective in improving the functionality of hydrogel lens and to improve stability and durability. In addition, it is believed that it can be used in various ways as an ophthalmic material as well as a photopolymerization crosslinking agent. Key words : Crosslinking agent, Tensile strength, 1,6-Hexanediol diacrylate, Hydrogel lens

This study investigates the enhancement of surface precision and dimensional accuracy in STS 316L oval pipes through the application of magnetic abrasive finishing. The experiment involves the modification magnetic pole shapes(A, B, C, D) and a comprehensive analysis of their impact on surface quality. Key parameters include magnetic abrasive KX#320, iron powder, aluminum oxide, light oil, a test specimen rotating at 600rpm, and periodic injection of polishing liquid, a permanent magnet Nd-Fe-B, and magnetic pole steel 1018, reciprocating distance 20mm, and a feed rate 1mm/sec over a 32minutes duration with measurements every 4minutes. The results demonstrate significant variations in surface quality based on magnetic pole shape, with specific configurations demonstrating superior precision and smoothness from the initial surface 0.32μm to 0.06μm.

PURPOSES : The wedge-type anchorage system requires a complex analysis of not only the tensile stress of the CFRP plate, but also the compressive stress and shear stress generated by the wedge action. The purpose of this study is to find a composite material failure theory that is suitable for analyzing the behavior of wedge-type anchorage system among various failure theories. METHODS : In this study, numerical analysis of various composite material failure theories was performed to analyze the anchorage strength and failure mode of the wedge-type anchorage system according to each failure theory, and compared with actual test results to determine the composite material failure theory most suitable for analyzing the behavior of a wedge-type anchorage system. RESULTS : Since the Maximum Stress failure theory shows similar results to the actual test in terms of failure mode and anchorage strength, there is no significant problem in applying it to the wedge-type anchorage system. However, it is judged to be difficult to apply under property conditions where interactions between stresses are highlighted. The Tsai-Hill and Tsai-Wu failure theories are considered unsuitable for application to wedge-type anchorage systems because the wedge angle conditions at which the most advantageous anchorage strength occurs are significantly different from other theories and the fracture type cannot be predicted. The Hashin-Rotem failure theory is considered to be the most appropriate to apply as a failure theory for the wedge-shaped anchorage system because the anchorage strength was slightly lower than the actual test results, but there was no significant difference, and the failure mode was consistent with the test results. The Hashin failure theory is judged to be unsuitable for application as a failure theory for the wedge-type anchorage system because the anchorage strength and failure mode were interpreted differently from the actual test results. CONCLUSIONS : The Hashin-Rotem failure theory was presented as the composite material failure theory most suitable for analyzing the behavior of wedge-type anchorage system.

The membrane structure should maintain the membrane materials in tension for structural stability guaranty. The anchoring part in the membrane structure is an important part. It has the function to introduce tension into membrane materials and function to transmit stress which membrane materials receives to boundary structure such as steel frames. In this paper, it grasps anchoring system of the anchoring part in the membrane structure concerning the fracturing characteristic condition of membrane structure, and the influence which is caused to yield it designates the stress state when breaking the membrane structure which includes the anchoring part and that stress transition mechanism is elucidated as purpose. This paper follows to previous paper, does 1 axial tensile test concerning the bolting part specimen, grasp of fracturing progress of the bolting part and the edge rope and hardness of the rubber, does the appraisal in addition with the difference of bolt tightening torque. As a result, the influence which the bolt anchoring exerts on the fracturing characteristics of the membrane material in the membrane structure anchoring part is examined.

Protein is an essential nutrient for humans to sustain life, but it is predicted that it will be challenging to secure protein through the traditional livestock industry in the future. Microalgae has high future value as an alternative protein food source due to resource utilization and sustainability advantages. In order to increase productivity, the culture conditions of microalgae, Chlorella vulgaris, Dunaliella salina, and Scenedesmus obliquus were examined in this study. The optimal culture conditions of C. vulgaris were mixotrophic culture, 25oC culture temperature, 7.0 initial pH, 10% initial inoculation, stirring culture, 3000 Lux light intensity, and 24L:0D light/dark cycle period with red LED. For D. salina, the optimal culture conditions were mixotrophic culture, 20oC culture temperature, 8.0 initial pH, 10% initial inoculation, stirring culture, 6000 Lux light intensity, and 12L:12D light/dark cycle period with white LED. For S. obliquus, the optimal culture conditions were mixotrophic culture, 30oC culture temperature, 8.0 initial pH, 10% initial inoculation, stirring culture, 4500 Lux light intensity, and 14L:10D light/dark cycle period with fluorescent light. These findings can be used as important information for increasing the production of microalgae as an alternative protein material resource in the future.

Detectors utilized for nuclear material safeguards have been using scintillation detectors which are inexpensive and highly portable, and electrically cooled germanium detectors which are expensive but have excellent energy resolution. However, recently IAEA, the only international inspectorate of nuclear material safeguards for the globe, have replaced the existing scintillation detector and electrically cooled germanium detector with a CdZnTe detector owing to the improved performance of room-temperature semiconductors significantly. In this paper, we will examine the spectrum features of the CdZnTe detector such as spectrum shape, energy resolution, and efficiency in the energy region of interest, which are the important characteristics for measuring Uranium enrichment. For this purpose, it would be conducted to compare its spectrum features using CdZnTe, NaI, HPGe detectors. The main energies of interest include 185.7 keV and 1,001 keV, which are the decay energies of uranium 235 and uranium 238. The results of this study will provide a better understanding of the spectral features of various detectors used in uranium enrichment analysis, and are expected to be used as basic data for future related software development.

Activated carbon (AC) is used for filtering organic and radioactive particles, in liquid and ventilation systems, respectively. Spent ACs (SACs) are stored till decaying to clearance level before disposal, but some SACs are found to contain C-14, a radioactive isotopes 5,730 years halflife, at a concentration greater than clearance level concentration, 1 Bq/g. However, without waste acceptance criteria (WAC) regarding SACs, SACs are not delivered for disposal at current situation. Therefore, this paper aims to perform a preliminary disposal safety examination to provide fundamental data to establish WAC regarding SACs SACs are inorganic ash composed mostly of carbon (~88%) with few other elements (S, H, O, etc.). Some of these SACs produced from NPPs are found to contain C-14 at concentration up to very-low level waste (VLLW) criteria, and few up to low-level waste (LLW) criteria. As SACs are in form of bead or pellets, dispersion may become a concern, thus requiring conditioning to be indispersible, and considering VLL soils can be disposed by packaging into soft-bags, VLL SACs can also be disposed in the same way, provided SACs are dried to meet free water requirement. But, further analysis is required to evaluate radioactive inventory before disposal. Disposability of SACs is examined based on domestic WAC’s requirement on physical and chemical characteristics. Firstly, particulate regulation would be satisfied, as commonly used ACs in filters are in size greater than 0.3 mm, which is greater than regulated particle size of 0.2 mm and below. Secondly, chelating content regulation would be satisfied, as SACs do not contain chelating chemicals. Also, cellulose, which is known to produce chelating agent (ISA), would be degraded and removed as ACs are produced by pyrolysis at 1,000°C, while thermal degradation of cellulose occurs around 350~600°C. Thirdly, ignitability regulation would be satisfied because as per 40 CFR 261.21, ignitable material is defined with ignition point below 60°C, but SACs has ignition point above 350°C. Lastly, gas generation regulation would be satisfied, as SACs being inorganic, they would be targeted for biological degradation, which is one of the main mechanism of gas generation. Therefore, SACs would be suitable to be disposed at domestic repositories, provided they are securely packaged. Further analysis would be required before disposal to determine detailed radioactive inventories and chemical contents, which also would be used to produce fundamental data to establish WAC.