Multi-walled carbon nanotube reinforced epoxy composites were fabricated using shear mixing and sonication. The mechanical, viscoelastic, thermal, and electrical properties of the fabricated specimens were measured and evaluated. From the images and the results of the measurements of tensile strengths, the specimens having 0.6 wt% nanotube content showed better dispersion and higher strength than those of the other specimens. The Young's moduli of the specimens increased as the nanotube filler content was increased in the matrix. As the concentrations of nanotubes filler were increased in the composite specimens, their storage and loss moduli also tended to increase. The specimen having a nanotube filler content of 0.6 wt% showed higher thermal conductivity than that of the other specimens. On the other hand, in the measurement of thermal expansion, specimens having 0.4 and 0.6 wt% filler contents showed a lower value than that of the other specimens. The electrical conductivities also increased with increasing content of nanotube filler. Based on the measured and evaluated properties of the composites, it is believed that the simple and efficient fabrication process used in this study was sufficient to obtain improved properties in the specimens.

In this paper, the response of graphite/epoxy laminated composite beams subjected to impact loads without damage, is studied by the use of the developed finite element program. The modified Hertzian contact law considered elasto-plastic process is used to calculate the dynamic responses between the impactor and laminated target. Numerical results are presented to demonstrate the effects on the histories of contact force, deflection, damage energy, strain and stress through the thickness due to stacking sequence. In view of the kinetic energy response, [0/30/0/-30]2S laminate is faster than that of other two laminates due to its flexural stiffness. In special, the distribution of stress through the thickness shows nearly linear despite its discontinuity of stacking sequences for dynamic analysis unlike static analysis in a laminated composites.

The conductive polymer composites have attracted considerable attention in the field of industry due to their electrical properties. To understand electrical properties of the composites, their volume specific resistance was measured. Electrical conductivity results showed percolation phenomena. Percolation theories are frequently applied to describe the insulator-to-conductor transitions in the composites composed of conductive filler and insulating matrix. It was found that the percolation threshold strongly depends on the aspect ratio of filler particles. The critical concentration of percolation formed is defined as the percolation threshold. The purpose of this study was to examine electrical properties of the epoxy resins filled with nickel. The sample was prepared using vehicle such as epoxy resin replenished with nickel powder, and the evaluation on their practical use was performed in order to apply them to electric and electronic industry as well as general field. The volume specific resistance of epoxy resin composites was 4.666~13.074 when using nickel powder. Weight loss of the conductive composites took place at 350℃~470℃.

In this study, the effect of stacking sequence on the flexural and fracture properties of carbon/basalt/epoxy hybrid composites was investigated. Two types of carbon/basalt/epoxy hybrid composites with a sandwich form were fabricated: basalt skin-carbon core (BSCC) composites and carbon skin-basalt core (CSBC) composites. Fracture tests were conducted and the fracture surfaces of the carbon/basalt/epoxy hybrid composites were then examined using scanning electron microscopy (SEM). The results showed that the flexural strength and flexural modulus of the CSBC specimen respectively were ~32% and ~245% greater than those of the BSCC specimen. However, the interlaminar fracture toughness of the CSBC specimen was ~10% smaller than that of the BSCC specimen. SEM results on the fracture surface showed that matrix cracking is a dominant fracture mechanism for the CSBC specimen while interfacial debonding between fibers and epoxy resin is a dominant fracture process for the BSCC specimen.

This study was conducted to evaluate the health risk of workers exposed to phenyl glycidyl ether to prevent themfrom developing occupational diseases. The workplaces that coat floor with epoxy were selected and the sampleswere collected and analyzed with NIOSH 1619 Method. Unit risk was calculated according to the animalcarcinogenicity study. Excess cancer risk was also calculated by multiplying unit risk by exposure concentration.Monte Carlo simulation was performed to calculate the median, cumulative 90%, and cumulative 95% value.Phenyl glycidyl ether is a skin, eye irritator and can result in allergic reaction, nausea, intoxication. Unit risk wascalculated as 0.04 (mg/m³)-¹ based on the tumor incidence in rats. Geometric mean and geometric standarddeviation was also calculated as 0.112 ppm and 0.223, respectively by the workplace environment measurements.The median, cumulative 90%, and cumulative 95% value of excess cancer risk were calculated as 0.0244, 0.1328,0.1596, respectively. Not only cumulative 90% and cumulative 95% value but also the median of excess cancerrisk is much higher than 1×10-⁴ by the risk characterization, so there is a possibility of carcinogenesis to workers.Therefore, supervisors or managers of each workplace have to keep doing the risk management of their workplacesfor workers to reduce exposure to phenyl glycidyl ether.

The natures of fatigue crack growth under Mode Ⅱ loading are studied. End notched flexure beam specimens were used. The effects of adherend thickness, rubber modification and adhesive thickness on fatigue crack growth were examined. The experimental results show that some of these parameters apparently do affect fatigue crack growth. Resistance to ModeⅡ fatigue crack growth are increased by rubber modification. The effects of adhesive thickness and rubber content on fatigue crack growth were explained by von Mises's equivalent stress using BEM analysis. For unmodified epoxy adhesives, the fatigue crack growth properties under Mode Ⅱ loadings were significantly different in all regions. For rubber-modified epoxy adhesives, they were also different in the first and second regions, but in the third region, they were similar

In this work, nanocomposites of epoxy resin and chemically reduced graphene oxide (RGO) were prepared by thermal curing process. X-ray diffractions confirmed the microstructural properties of RGO. Differential scanning calorimetry was used to evaluate the curing behaviors of RGO/epoxy nanocomposites with different RGO loading amounts. We investigated the effect of RGO loading amounts on the mechanical properties of the epoxy nanocomposites. It was found that the presence of RGO improved both flexural strength and modulus of the epoxy nanocomposites till the RGO loading reached 0.4 wt%, and then decreased. The optimum loading achieved about 24.5 and 25.7% improvements, respectively, compared to the neat-epoxy composites. The observed mechanical reinforcement might be an enhancement of mechanical interlocking between the epoxy matrix and RGO due to the unique planar structures.

Multi-walled carbon nanotube (MWCNT)/epoxy composites are prepared by a vacuum assisted resin transfer molding (VARTM) method. The mechanical properties, fracture surface morphologies, and thermal stabilities of these nanocomposites are evaluated for epoxy resins with various amounts of MWCNTs. Composites consisting of different amounts of MWCNTs displayed an increase of the work of adhesion between the MWCNTs and the matrix, which improved both the tensile and impact strengths of the composites. The tensile and impact strengths of the MWCNT/epoxy composite improved by 59 and 562% with 0.3 phr of MWCNTs, respectively, compared to the epoxy composite without MWCNTs. Thermal stability of the 0.3 phr MWCNT/epoxy composite increased compared to other epoxy composites with MWCNTs. The enhancement of the mechanical and thermal properties of the MWCNT/epoxy nanocomposites is attributed to improved dispersibility and strong interfacial interaction between the MWCNTs and the epoxy in the composites prepared by VARTM.

A supercritical carbon dioxide (SCC) process of dispersion of multi-walled carbon nano-tubes (MWCNTs) into epoxy resin has been developed to achieve MWCNT/epoxy com-posites (CECs) with improved mechanical, thermal, and electrical properties. The synthesis of CECs has been executed at a MWCNT (phr) concentration ranging from 0.1 to 0.3 into epoxy resin (0.1 mol) at 1800 psi, 90°C, and 1500 rpm over 1 h followed by curing of the MWCNT/epoxy formulations with triethylene tetramine (15 phr). The effect of SCC treat-ment on the qualitative dispersion of MWCNTs at various concentrations into the epoxy has been investigated through spectra analyses and microscopy. The developed SCC assisted process provides a good dispersion of MWCNTs into the epoxy up to a MWCNT concentra-tion of 0.2. The effects of SCC assisted dispersion at various concentrations of MWCNTs on modificationof mechanical, thermal, dynamic mechanical thermal, and tribological proper-ties and the electrical conductivity of CECs have been investigated.

Magnetostrictive actuator is fabricated with epoxy bonding method instead of sputtering method in this study. Fabrication process and experimental measurement method for magneto-mechanical characteristics is proposed. For the design of highly flexible magnetostrictive actuator, TbDyFe epoxy bonding with SU-8 substrate is adopted. The fabrication process for SU-8 substrate and the epoxy bonding is suggested and magnetostrictive behavior is investigated. Variable magnetic field is applied to measure the various magnetostrictive characteristics and magnetostriction is measured with different waves and different magnitude of magnetic field.

It has been demonstrated in a previous study that carbon nanotube (CNT)/epoxy/basalt composites produce better flexural properties than epoxy/basalt composites. In this study, mode I fracture tests were conducted using CNT/epoxy/basalt composites with and without seawater absorption in order to investigate the effect of the seawater absorption on the mode I fracture toughness (GIC) of the CNT/epoxy/basalt composites. The results demonstrated that the compliance of the seawater-absorbed specimen was larger than that of the dry specimen at the same crack length, while the opposite result was obtained for the fracture load. The GIC value of the seawater-absorbed CNT/epoxy/basalt composites was approximately 20% lower than that of the dry CNT/epoxy/basalt composites.

The conductive polymer composites recently became increasingly to many fields of industry due to their electrical properties. To understand these properties of composites, electrical properties were measured and were studied relatively. Electrical conductivity measurements showed percolation phenomena. Percolation theories are frequently applied to describe the insulator-to-conductor transitions in composites made of a conductive filler and an insulating matrix. It has been showed both experimentally and theoretically that the percolation threshold strongly depends on the aspect ratio of filler particles. The critical concentration of percolation formed is defined as the percolation threshold. This paper was to study epoxy resin filled with copper. The experiment was made with vehicle such as epoxy resin replenished with copper powder and the study about their practical use was performed in order to apply to electric and electronic industry as well as general field. The volume specific resistance of epoxy resin composites was 3.065~13.325 in using copper powder. The weight loss of conductive composites happened from 350℃~470℃.

Carbon nanotubes (CNTs) are increasingly attracting scientific and industrial interest because of their outstanding characteristics, such as a high Young's modulus and tensile strength, low density, and excellent electrical and thermal properties. The incorporation of CNTs into polymer matrices greatly improves the electrical, thermal, and mechanical properties of the materials. Surface modification of CNTs can improve their processibility and dispersion within the composites. This paper aims to review the surface modification of CNTs, processing technologies, and mechanical and electrical properties of CNT-based epoxy composites.

In this paper, the features of fatigue crack growth under ModeⅠ loading are studied. Double cantilever beam specimens were used. The effects of adherend thickness, rubber modification and adhesive thickness on fatigue crack growth were examined. The experimental results show that some of these parameters do apparently affect fatigue crack growth. Resistance to ModeⅠ fatigue crack growth are increased by rubber modification. The effects of adhesive thickness and rubber content on fatigue crack growth were explained by von Mises's equivalent stress using BEM analysis.

This paper is to study the energy absorption characteristics of CF/Epoxy(Carbon Fiber/Epoxy Resin) laminated shell with the various curvatures subjected to transverse impact loadings under the low impact velocity in consideration of design of structural members for use of transportation machine, which are consisted of the characteristics of high stiffness, strength and lightweight. The curvature radius are associated with the energy absorption characteristics of CF/Epoxy laminated shell which is brittleness material. In all tests, maximum load of CF/Epoxy laminated plate is higher than that of laminated shell with curvature, but maximum deflection is lower. And then absorbed energy of laminated shell with curvature is higher than laminated plate(curvature radius is unlimited). As curvature radius is increased, the absorbed energy is increased in laminated shell with curvature.

This study investigates the flexural properties of multi-walled carbon nanotube (MWCNT) reinforced basalt/epoxy composites under conditions with and without moisture absorption. The basalt/CNT/epoxy composites were fabricated using 1 wt% silanized MWCNTs and kept in seawater for over 4 months. The flexural properties of the moisture absorbed specimens were evaluated and compared with those of dry specimens. The flexural properties of basalt/CNT/epoxy composites were found to decrease with moisture absorption. The flexural strength and modulus of moisture absorbed specimens were 22% and 16% lower, respectively, than those of the dry specimen. Scanning electron microscope examination of the fracture surfaces revealed that the decreases of flexural properties in the moisture absorbed specimen were due to the weakening of interfacial bonding from swelling of the epoxy matrix.

Various adhesive materials are used in flip chip packaging for electrical interconnection and structural reinforcement. In cases of COF(chip on film) packages, low temperature bonding adhesive is currently needed for the utilization of low thermal resistance substrate films, such as PEN(polyethylene naphthalate) and PET(polyethylene terephthalate). In this study, the effects of anhydride and dihydrazide hardeners on the low-temperature snap cure behavior of epoxy based non-conductive pastes(NCPs) were investigated to reduce flip chip bonding temperature. Dynamic DSC(differential scanning calorimetry) and isothermal DEA(dielectric analysis) results showed that the curing rate of MHHPA(hexahydro-4-methylphthalic anhydride) at 160˚C was faster than that of ADH(adipic dihydrazide) when considering the onset and peak curing temperatures. In a die shear test performed after flip chip bonding, however, ADH-containing formulations indicated faster trends in reaching saturated bond strength values due to the post curing effect. More enhanced HAST(highly accelerated stress test) reliability could be achieved in an assembly having a higher initial bond strength and, thus, MHHPA is considered to be a more effective hardener than ADH for low temperature snap cure NCPs.