A solution combustion process for the synthesis of hollandite (BaAl2Ti6O16) powders is described. SYNROC (synthetic rock) consists of four main titanate phases: perovskite, zirconolite, hollandite and rutile. Hollandite is one of the crystalline host matrices used for the disposal of high-level radioactive wastes because it immobilizes Sr and Lns elements by forming solid solutions. The solution combustion synthesis, which is a self-sustaining oxi-reduction reaction between a nitrate and organic fuel, generates an exothermic reaction and that heat converts the precursors into their corresponding oxide products in air. The process has high energy efficiency, fast heating rates, short reaction times, and high compositional homogeneity. To confirm the combustion synthesis reaction, FT-IR analysis was conducted using glycine with a carboxyl group and an amine as fuel to observe its bonding with metal element in the nitrate. TG-DTA, X-ray diffraction analysis, SEM and EDS were performed to confirm the formed phases and morphology. Powders with an uncontrolled shape were obtained through a general oxide-route process, confirming hollandite powders with micro-sized soft agglomerates consisting of nano-sized primary particles can be prepared using these methods.

In this study, we evaluated the effects of acid leaching on the properties of Cr powder synthesized using self-propagating high-temperature synthesis (SHS). Cr powder was synthesized from a mixture of Cr2O3 and magnesium (Mg) powders using the SHS Process, and the byproducts after the reaction were removed using acid leaching. The properties of the recovered Cr powder were analyzed via X-ray diffraction (XRD), scanning electron microscopy (SEM), energy-dispersive X-ray spectroscopy (EDS), particle size analysis (PSA), and oxygen content analysis. The results show that perfect selective leaching of Cr is challenging because of various factors such as incomplete reaction, reaction kinetics, the presence of impurities, and incompatibility between the acid and metal mixture. Therefore, this study provides essential information on the properties under acidic conditions during the production of high-quality Cr powder using a self-propagating high-temperature synthesis method.

Diesel engine has the advantages of strong power, low fuel consumption and good durability, so it has been widely used in transportation, automobile, ship and other fields. However, the nitrogen oxides(NOx) and particulate matter(PM) emitted by diesel engines have become one of the main causes of air pollution. Especially during idling, the engine temperature is low, and there are more residual exhaust gases in the combustion chamber, resulting in the formation of more harmful emissions. In this study, performance of a single cylinder, four-stroke, direct injection (DI) diesel engine fueled with diesel–biodiesel mixtures has been experimentally investigated. The findings show that a remarkable improvement in PM–NOx trade-off can be achieved by burning diesel-bioethanol blend fuels.

Diesel engine has the advantages of strong power, low fuel consumption and good durability, so it has been widely used in transportation, automobile, ship and other fields. However, the nitrogen oxides(NOx) and particulate matter(PM) emitted by diesel engines have become one of the main causes of air pollution. Especially during idling, the engine temperature is low, and there are more residual exhaust gases in the combustion chamber, resulting in the formation of more harmful emissions. In this study, performance of a single cylinder, four-stroke, direct injection (DI) diesel engine fueled with diesel–biodiesel mixtures has been experimentally investigated.

본 연구에서는 중국 북동지역에서 발생하는 산불에 의한 생체연소 배출물이 장거리 수송으로 한국의 미세먼지 질량농도에 미치는 영향을 WRF-Chem 모델을 활용하여 분석하였다. 2020년 4월 4-7일에 한국은 중국 북동지역의 생체 연소 배출물과 더불어 중국 동부지역의 인위적 배출과 중국 북부와 몽골에서 발생한 황사의 영향을 함께 받고 있었다. 인위적 배출과 황사가 혼재된 대기오염 상황에서 zero-out 방법을 활용하여 생체연소 배출물을 분류하고 미세먼지 장거 리 수송 기여도를 분석하였다. 또한, 광역적인 생체연소 배출물의 분포에 따라 한반도 주변의 육지와 해양에 대한 복사 에너지 수지를 분석하였다. 2020년 4월 5-6일에는 한국의 하루평균 미세먼지 질량농도에 대한 생체연소 배출물의 장거리 수송 기여도가 60%로 산출되었다. 더불어 한반도 주변에 광역적으로 분포하는 생체연소 배출물의 영향으로 육지와 해양의 순 복사 플럭스는 음의 값을 나타내었다. 그러나 2020년 4월 7-8일에는 중국 동부지역에서 발생한 인위적 오염 물질이 생체연소 배출물에 더해지면서 한국의 미세먼지 질량농도는 4월 5-6일보다 증가하였으나 생체연소 배출물의 기 여도는 45% 이하로 감소하였다. 또한, 생체연소 배출물의 영향이 줄어들면서 순 복사 플럭스는 양의 값을 나타내었다.

Tungsten carbide is widely used in carbide tools. However, its production process generates a significant number of end-of-life products and by-products. Therefore, it is necessary to develop efficient recycling methods and investigate the remanufacturing of tungsten carbide using recycled materials. Herein, we have recovered 99.9% of the tungsten in cemented carbide hard scrap as tungsten oxide via an alkali leaching process. Subsequently, using the recovered tungsten oxide as a starting material, tungsten carbide has been produced by employing a self-propagating high-temperature synthesis (SHS) method. SHS is advantageous as it reduces the reaction time and is energy-efficient. Tungsten carbide with a carbon content of 6.18 wt % and a particle size of 116 nm has been successfully synthesized by optimizing the SHS process parameters, pulverization, and mixing. In this study, a series of processes for the highefficiency recycling and quality improvement of tungsten-based materials have been developed.

In this study, the effects of fuel injection pressure changed from 45 to 65 MPa on combustion and emission characteristics were investigated in a common rail direct injection (CRDI) diesel engine fueled with diesel and palm oil biodiesel blends. The engine speed and engine load were controlled at constant 1700rpm and 100Nm, respectively. The tested fuel were PBD20 (20 vol.% palm oil biodiesel blended with 80 vol.% diesel fuel). The main and pilot injection timing was fixed at 3.5°CA BTDC and 27°CA BTDC (before top dead center), respectively. The experimental results show that the combustion pressure and heat release rate increased. In addition, the indicated mean effective pressure (IMEP) and maximum combustion pressure increased with an increase of the fuel injection pressure. Hydrocarbon (HC), smoke opacity and carbon monoxide (CO) decreased, but oxides of nitrogen (NOx) emissions increased as fuel injection pressure increased.

In this study, the combustion characteristics of low calorific gas (LCG) fuels are investigated by numerical simulation. PREMIXED code is used to predict the flame structure and NO emission with two mechanisms, which are GRI 3.0 and USC II chemical reaction mechanisms for CH4 and LCG 8000 and LCG 6000, respectively. Also, elementary reactions related with production and destruction for OH radical are studied because OH radical is dominant for burning velocity and NO emission. As results, the production and the destruction of OH radical for CH4 and LCG 8000 using GRI 3.0 are dominated by reactions of No. 4, No. 2 and No. 3 and by No. 5, No. 3 and No. 7, respectively. For LCG 6000 using USC II, reactions of No. 3, No. 4 and No. 11 and of No. 7, No. 8 and No. 12 dominates to the production and the destruction, respectively. In addition, NO emissions for LCG gas fuel are generated by thermal NO because the flame temperatures are over 1800 K.

In the past, the U.S. NRC(Nuclear Regulatory Commission) strictly required testing of the EDG for NPP through Reg.Guide 1.108 Rev 1. However, these test requirements acted as a deterioration and wear factor for diesel engines, and are now applying Reg.Guide 1.9 Rev 3, which relaxed regulatory requirements and improved performance monitoring. After applying the new regulatory guidelines in this study, the EDG analyzed the performance of the combustion chamber. As a result, there were no signs of deterioration or decreased performance of the current EDG. This is due to slow start, short operation time, the use of high quality fuel oil and proper maintenance. On the other hand, if the performance is proven, it is judged that proper period extension of cylinder maintenance is possible.