In order to respond to environmental pollution, developed countries, including Korea, have begun to conduct research to utilize hydrogen energy. For mass transfer of hydrogen energy, storage as liquid hydrogen is advantageous, and in this case, the volume can be reduced to 1/800. As such, the transportation technology of liquefied hydrogen for ships is expected to be needed in the near future, but there is no commercialized method yet. This study is a study on the technology to test the performance of the components constituting the membrane type storage container in a cryogenic environment as a preparation for the above. It is a study to find a way to respond by analyzing in advance the problems that may occur during the shear test of adhesives. Through this study, the limitations of ISO4587 were analyzed, and in order to cope with this, the specimen was supplemented so that fracture occurred in the adhesive, not the adhesive gripper, by using stainless steel, a low-temperature steel, to reinforce the thickness. Based on this, shear evaluation was performed under conditions lowered to minus 243℃, and it was confirmed that the breaking strength was higher at cryogenic temperatures.

Conversion to modern hydrogen energy is required, and research on liquefied hydrogen cargo containment systems is needed for large-capacity transport and storage. In this study, changes in the mechanical properties of the adhesive required for storage and transport in liquid hydrogen were confirmed. The lap shear test was performed by realizing cryogenic conditions in a small chamber using liquid nitrogen and liquid helium. There was an increase of 11.0% in the -180℃ condition compared to room temperature, and an increase of 1.8% in the -230℃ condition compared to the -180℃ condition was confirmed. In the case of shear strain, it is known that it decreases as the temperature goes down. As a result of the experiment, it was confirmed that the value at room temperature and the value at -180℃ reduced the shear strain by 5.0%, and -230˚ compared to the -180℃ condition. An increase of 1.5% was confirmed in the C condition. In the case of the specimen tested at -230℃, the deformation in the gripper part was larger than in other tests, and it is judged that the maximum shear strength and shear strain were affected. In addition, in this study, there is a limitation in the experiment at -230°C rather than 253°C, which is the boiling point of hydrogen

In modern times, where problems due to environmental pollution are continuously occurring, hydrogen is in the spotlight as the energy of the future. Hydrogen is an eco-friendly energy resource that does not even generate CO2, and is actively supporting research to utilize hydrogen energy at the national level. This study is a study on the cryogenic mechanical properties of the elements constituting the cargo hold during the transportation of liquid hydrogen. Among the various components, the evaluation of mechanical properties of the cryogenic adhesive under liquid helium conditions was confirmed. The related contents are summarized as follows. As a result of performing SSRT by curing the adhesive, it was confirmed that tensile strength and maximum strain were increased at cryogenic temperature (-230°C) compared to room temperature (25°C). It was confirmed that the adhesive-hardened specimen showed a brittle fracture mode at both room temperature and cryogenic temperature during tensile. Improvements in this study, such as pores occurring during adhesive curing, the use of standard specimens, and experiments at -253°C, the boiling point of hydrogen, exist, and are planned to be carried out in subsequent studies.

This paper aims at investigating the adhesive property at damage analysis according to the shape of the DCB test specimen made of Titanium, Dualumin as the high strength nonferrous metals. In this analysis, all three specimens had the lower holes bound by the cylinder support and the top holes were elongated with the rate of 6mm/min. The study results show that the longer the load block of DCB specimens, the more reliable and durable they are. It is utilized as the basic data at investigating the damage properties of adhesives in DCB specimens made of high strength nonferrous metals.

In this study, the experiments and analyses were carried out in order to investigate the fracture characteristics on the adhesive at the specimen bonded with aluminum and aluminum-foam. The same conditions were given for the experiments and analyses. The results are investigated by the graph of reaction force according to displacement. It was found that the experimental and the analytical data were very similar to each other. On the basis of the data, the reliability of the analysis data could be confirmed. The notches were produced at the distances of 40, 110, 150, and 190 mm from the front of the test specimen, and the maximum reaction force was compared accordingly. It was found that the highest reaction force was generated at the front end of the adhesive and the lowest reaction force was found at the middle of the adhesive interface. Finally, when the equivalent stress in the test specimen was examined, it was found that the highest stress was obtained at the distance of 110 mm. It can be deduced. As the notch formation point are similar to the point when stress is dispersed as the adhesive is peeled off, it is possible to infer the high stress compared to other test specimens.

홍합 족사 단백질은 수분이 있는 표면에서도 강한 접착력을 가진다. 홍합 연구에 대표가 되는 marine blue mussel을 통해 9가지 단백질의 구조와 기능이 보고되었으며, 이 단백질들은 홍합 족사를 구성하는 실(threads)과 플래크(plaques)를 형성한다. 알려진 바에 의하면, 히드록시기 2개가 포함된 카테콜 기 능기를 가진 DOPA 물질이 계면접착(adhesion)과 내부결합(cohesion) 과정에서 중요한 역할을 하는 것으로 알려져 있다. 본 논문에서는, 최근 10년간 활발히 연구된 계면접착과 내부응력 메카니즘에 대해 소개하고 평가하였다. 또한, 접착력을 갖는 기능기를 활용한 발전된 접착소재의 개발, 바이오접착제와 의료용 소재로 응용가능성에 대해 살펴보았다. 홍합 단백질이 다시 관심의 대상이 되면서, 바이오소재로 사용될 가능성이 커지고 있음이 주목된다.

본 연구에서는 수용성 접착제 가장 큰 단점인 내수성을 향상시킬 수 있는 수용성 첨가제를 개발하였다. 수 용성 첨가제는 diisocyanate 그룹을 가지는 분자들을 아황산수소나트륨과 반응시켜 얻을 수 있었다. FT-IR 측정 결 과 isocyanate 그룹이 완전히 사라진 것을 볼 수 있었고, DSC의 측정결과는 150℃ 이상의 온도에서 아황산수소나트 륨이 제거되어 isocyanate를 재형성하는 것을 확인할 수 있었다. 개발된 수용성 첨가제를 본사 제품인 DM-95 접착제 에 0.5 wt% 첨가하였을 때 높은 접착성능 및 향상된 내수성을 확보할 수 있었다. 그뿐만 아니라 기존의 복잡한 접착 공정을 요구하는 2 액형 시스템에서 탈피하여 생산 공정이 간단한 1 액형 시스템을 구축할 수 있으므로 산업 전반에 서 유용하게 사용될 것으로 사료된다.

이 연구에서는 계면활성제에 작용기를 첨가하여 유화제 뿐만 아니라 합성에서의 모노머로 작 용할 수 있는 반응성 계면활성제를 합성하였다. 반응성 계면 활성제는 메타아크릴 산, 아크릴산과 비이 온성 계면 활성제인 폴리 옥시 에틸렌 라우릴 에테르 (POE 23)를 사용하여 합성되었으며 벤젠을 용매 로서 사용하였고, P-TsOH를 촉매로서 사용 하였다. 합성된 계면 활성제는 FT-IR, 1H-NMR 스펙트 럼, 원소 분석을 하였다. 물성 평가는 HLB, Cloud point, 표면 장력, 임계 미셀 농도를 측정 하였다. HLB 값은 11.62∼12.09 범위로 평가 하였다. cmc 값은 표면 장력 법으로 측정하였을 때 1×10-4~5×10-4 의 값을 가졌다. 실험을 통해 측정된 Cloud point은 35, 39℃ 이었다. 합성 계면 활성 제의 유화 특성은 polyoxyethylene lauryl ether보다 낮았다. 또한, 유화력은 벤젠에서 보다 대두유에서 더 좋았다. 실험결과 합성 수율은 93.27 ∼ 94.49%로 확인되었다.

태양광 발전시스템은 태양복사에너지를 반도체의 광전효과를 이용하여 전기에너지로 직접 전환시키는 에너지변환 시스템이다. 태양전지의 내구성과 에너지변환율에 영향을 미치는 핵심소재로는 다층형 필름구조를 갖는 백시트를 들 수 있다. 대표적인 상용 백시트는 고내구성 poly(vinyl fluoride) (PVF) 필름이 중심축에 위치하고 가격저감을 위해 도입된 poly(ethylene terephthalate) (PET) 필름이 그 양쪽에 접합된 삼층구조로 구성된다. 하지만, PVF 필름의 높은 가격은 저렴한 고내구성 백시트 를 요구하는 시장상황을 반영하기 어렵게 한다. 이를 위한 해결책으로는 PVF 필름을 결정성 PET 필름으로 대체한 탄화수소계 백시트가 될 수 있다. 하지만, PET 필름의 본질적인 가수분해에 대한 취약성으로 인해, 추가적인 수분에 대한 배리어성 부여 는 필수적이다. 이를 위해 본 연구에서는 소수성 실리카 나노입자 분산기술을 활용한 수분차단성 폴리우레탄 접착제를 개발 코자 하였다. 개발된 접착제는 내부에 위치한 PET 필름으로의 수분침투를 약화시켜, 가수분해속도를 지연시킬 것이라 기대 되었다. 본 개념의 효용성을 확인하기 위해, 표준화된 온습도조건에 노출된 이후의 일반접착제와 수분차단성 접착제가 도입 된 백시트의 기계적 강도 및 시간당 태양전지성능 변화가 비교평가되었다.

The porous metallic material has the most superior physical property and the best mechanical capability. This study is investigated with the simulation analysis by compressing three kinds of specimens. Three aluminum foams with the thickness of 10 mm are bonded at Case 1. Two aluminum foams with the thicknesses of 10 mm and 20 mm are bonded at Case 2. It is one aluminum foam with the thickness of 30 mm at Case 3. The two dimensional model is done by ANSYS design modeler and the finite element analysis is performed by ANSYS structural analysis. As the forced displacement of 1 mm during the elapsed time of 60 sec is applied, the forced displacement of 10 mm during the total elapsed time of 600 sec is applied. As the analysis result, the most reaction force is shown at case 2 among three cases. Case 2 is estimated as the best structure. The analysis result of this study is thought to be the data necessary for the safe design about mechanical structure and the development of composite material.

The natures of fatigue crack growth under Mode Ⅱ loading are studied. End notched flexure beam specimens were used. The effects of adherend thickness, rubber modification and adhesive thickness on fatigue crack growth were examined. The experimental results show that some of these parameters apparently do affect fatigue crack growth. Resistance to ModeⅡ fatigue crack growth are increased by rubber modification. The effects of adhesive thickness and rubber content on fatigue crack growth were explained by von Mises's equivalent stress using BEM analysis. For unmodified epoxy adhesives, the fatigue crack growth properties under Mode Ⅱ loadings were significantly different in all regions. For rubber-modified epoxy adhesives, they were also different in the first and second regions, but in the third region, they were similar

Tapered double cantilever beam (TDCB) specimens are the most commonly used test configurations to measure the fracture toughness of composites and adhesive joints. The material used in this study is aluminum alloy. For the impact analysis, load and displacement applied from pin onto end block as well as the crack energy release rate are calculated and compared with the finite element analysis results. The energy release rate increases with the velocity increases. As TDCB model with the same condition as experiment is simulated and analyzed, the fracture behavior can be estimated with the analysis result similar to experiment. The simulation results can be agreed with experimental graph and all experimental data at this study can be verified. These experimental results can be applied into real field effectively. It is found that the energy release rates measured from impact tests on the specimens can be predicted by the finite element model suggested in this study.

알루미늄 폼을 볼트나 너트를 이용하여 체결한다면 경량성이 감소되므로 접착제로 접합하는 것이 가 장 효율적이다. 이런 알루미늄 폼 접착 구조물에 대한 충격 피로 특성과 접착 합면에 대한 파괴인성 연 구는 매우 부족하며 또한 중요하다. 이에 따라 본 연구에서는 알루미늄 폼으로 만들어진 DCB모델을 접 착제로 접합한 후 두께를 변수로 하여 25mm 부터 45mm까지 10mm차이를 두어 실험과 컴퓨터 시뮬레 이션을 통하여 수행하였다. 실험은 MTS사의 인장 시험기를 사용하여 강제 변위 100mm를 주어 변위에 따른 전단력을 알아보았고, 실험과 똑같은 조건하에 ANSYS를 이용하여 유한요소해석을 수행하였다. 실험과 유한요소해석 값을 비교하여 접착제로 접합된 알루미늄 폼 구조물의 접착 합면에 대한 파괴인성을 고찰하였다.

Aluminum foam has many superb properties such as light weight, impact absorption and thermal resistance by comparing with original metallic materials. Composite materials made of aluminum foam have used at various fields as automotive bumper, shock absorption, vessel and aircraft. But it is inefficient to join aluminum foam with bolt and nut because of the property of light weight. In this study, this approach is investigated by joining aluminum foam with adhesive. Impact fatigue and failure toughness at the commissure of adhesive structure are studied by simulation analysis. This study aims to investigate the shear strength evaluation at shear mode of adhesively bonded joint with double cantilever beam(DCB) made of aluminum foam.

four kinds of models designed by the basis of British industrial standard and ISO international standard in this study. Energy release rates at mode 1 are investigated by the fatigue analysis of aluminum foam TDCB model bonded with adhesive. These analysis models are compared each other by classifying four models into m values with 2, 2.5, 3 and 3.5. The value of m as the gradient of model is represented with the function of crack length(a) and height of model(h). Through the correlation relation, the fracture behavior of bonded material is analyzed and these analysis results can be applied to composite structures of various areas. Mechanical property and fracture toughness of composite material are also analyzed in this study.