본 연구에서는 강합성라멘교의 벽체 배면 철근 커플러 적용 여부에 따른 두 실험체를 제작하여 하 중가력 실험을 수행하였다. 그 결과 공법에 적용된 주요 기술에 대한 구조적 안전성 및 적정성을 확인 하였으며, 실험체는 설계 내하력 대비 충분한 안전성을 확보하고 있음이 확인되었다. 또한, 경간장 17.3m, 교폭 3.0m, 높이 3.25m의 실험체에 대한 정적성능실험 및 동특성 측정 실험을 수행하였으며, 그 결과 설계 내하력 대비 충분한 안전성을 확보하고 있는 것으로 나타났다.

본 연구는 철도교 노후화에 따른 열차운행 중 신속 교체 및 재난·재해에 대한 급속 시공을 통하여 공기단축 및 시공성 확보로 국민의 사회적·경제적 피해를 최소화하고자 한다. 철도교 개량 등에서 필 수적인 8철도하로교 시공고도화 및 성능향상9을 위하여 신속 교체와 성능향상이 가능한 강합성 철도하 로교 설계·제작·시공 기술을 개발하고자 한다. 또한, 개발하고자 하는 강합성 하로교의 경우 철도교뿐 만 아니라 도로교에서 적용하고자 하며, 철도교는 상부구조가 단경간 형식으로 이루어지고 있어 철도 교 사용성 검토에 큰 문제가 없으나 도로교의 경우 바닥판 연속화를 고려 중에 있어, 이에 대한 온도 및 부모멘트 등 여러 문제점을 검토하였다. 상로교의 경우 다수의 거더에 의해 바닥판이 지지되므로 PS의 중요성이 부각될 수 없지만, 하로교의 바닥판은 양단 거더에 의한 고정지지이므로 RC구조 적용 이 어려워, 강합성 또는 PSC 공법을 일반적으로 적용한다. 기존 강합성 구조는 비용, 공기 측면에서 지양하고 PSC 구조의 가로보 및 바닥판과 강재 거더를 합성한 하로교를 개발하고자 한다.

In the present work, we address the new route for the green synthesis of manganese dioxide (MnO2) by an innovative method named the solution plasma process (SPP). The reaction mechanism of both colloidal and nanostructured MnO2 was investigated. Firstly, colloidal MnO2 was synthesized by plasma discharging in KMnO4 aqueous solution without any additives such as reducing agents, acids, or base chemicals. As a function of the discharge time, the purple color solution of MnO4 - (oxidation state +7) was changed to the brown color of MnO2 (oxidation state +4) and then light yellow of Mn2+ (oxidation state +2). Based on the UV-vis analysis we found the optimal discharging time for the synthesis of stable colloidal MnO2 and also reaction mechanism was verified by optical emission spectroscopy (OES) analysis. Secondly, MnO2 nanoparticles were synthesized by SPP with a small amount of reducing sugar. The precipitation of brown color was observed after 8 min of plasma discharge and then completely separated into colorless solution and precipitation. It was confirmed layered type of nanoporous birnessite- MnO2 by X-ray powder diffraction (XRD), fourier-transform infrared spectroscopy (FT-IR), and electron microscopes. The most important merits of this approach are environmentally friendly process within a short time compared to the conventional method. Moreover, the morphology and the microstructure could be controllable by discharge conditions for the appropriate potential applications, such as secondary batteries, supercapacitors, adsorbents, and catalysts.

이 논문은 정적 재하상태에 있는 무피복 강합성보와 내화피복을 적용한 강합성보를 대상으로 화재 시 내부 온도 및 수직처짐에 대 한 내화피복의 영향을 평가한 결과를 제시한다. 열응력해석을 위한 화재하중으로는 American Society for Testing and Materials E119 의 표준화재곡선을 사용했으며, 강재거더 표면에 부착하는 내화재료의 방화효과를 구현하기 위해 외기에서 강합성보로 전달되는 열 의 전달계수를 감소시켰다. 실규모 무피복 강합성보에 대한 구조화재실험에서 내부 온도분포와 수직처짐을 측정하였고 실험 결과와 의 비교를 통해 비선형 구조화재해석 결과의 타당성을 검증하였다. 내화피복이 적용된 강합성보의 구조화재해석 결과로부터 강재거 더 표면에 내화재를 적용할 경우 동일 화재 조건에서 무피복 강합성보에 비해 내부 온도와 수직처짐이 감소함을 알 수 있었다. 또한 열 전달계수의 변화에 따른 열응력 응답으로부터 화재 시 강합성보의 온도 및 구조거동에 대한 내화피복의 영향을 제시하였다.

Li1.3Al0.3Ti1.7(PO4)3(LATP) is considered a promising material for all-solid-state lithium batteries owing to its high moisture stability, wide potential window (~6 V), and relatively high ion conductivity (10-3–10-4 S/cm). Solid electrolytes based on LATP are manufactured via sintering, using LATP powder as the starting material. The properties of the starting materials depend on the synthesis conditions, which affect the microstructure and ionic conductivity of the solid electrolytes. In this study, we synthesize the LATP powder using sol-gel and co-precipitation methods and characterize the physical properties of powder, such as size, shape, and crystallinity. In addition, we have prepared a disc-shaped LATP solid electrolyte using LATP powder as the starting material. In addition, X-ray diffraction, scanning electron microscopy, and electrochemical impedance spectroscopic measurements are conducted to analyze the grain size, microstructures, and ion conduction properties. These results indicate that the synthesis conditions of the powder are a crucial factor in creating microstructures and affecting the conduction properties of lithium ions in solid electrolytes.

In this study, we focus on the feasibility of structural topology optimization for a steel-timber composite beam design of optimally allocating glue-laminated timbers into a web with openings under the condition of given steel flanges. The motivation of this study is to topologically take maximal stiffness harmonizing both tension and compression performance of the steel-timber composite beam and become the eco-frandly timber design for buidling members. As a result of this study, the key web-openings allocation becomes triangle spaces, i.e., empty or no materials, of optimal topologies of both a pure timber plate and a steel flange-web timber plate without web-openings. Several applicable examples verify the effectiveness of topology optimization for steel-timber beams with web-openings.

The capacity of high nickel Li(NixCoyMn1-x-y)O2 (NCM, x ≥ 0.8) cathodes is known to rapidly decline, a serious problem that needs to be solved in a timely manner. It was reported that cathode materials with the {010} plane exposed toward the outside, i.e., a radial structure, can provide facile Li+ diffusion paths and stress buffer during repeated cycles. In addition, cathodes with a core-shell composition gradient are of great interest. For example, a stable surface structure can be achieved using relatively low nickel content on the surface. In this study, precursors of the high-nickel NCM were synthesized by coprecipitation in ambient atmosphere. Then, a transition metal solution for coprecipitation was replaced with a low nickel content and the coprecipitation reaction proceeded for the desired time. The electrochemical analysis of the core-shell cathode showed a capacity retention of 94 % after 100 cycles, compared to the initial discharge capacity of 184.74 mA h/g. The rate capability test also confirmed that the core-shell cathode had enhanced kinetics during charging and discharging at 1 A/g.

In this study, to verify the structural performance of the Composite Joint System (CJS) hybrid structural model, a cyclic load test was performed and evaluated and verified through the test. To verify the structural performance of the CJS hybrid structural systems’ joint and evaluate the seismic performance, four three-dimensional real-size specimens were developed with three internal beam-column specimens and one external beam-column specimen. The three interior column specimens were classified by different methods of joining the upper column and lower column, and the same bonding method as the primary specimen was used for the exterior column. The structural performances in terms of drift, strength, and energy dissipation capacity were analyzed and compared based on the experimental results. From the displacement-based loading experiment, all specimens showed a lateral drift of 4.0% without any significant strength drop and stable energy dissipation capacity.

This paper presents the effect on the inelastic behavior and structural performance of concrete and filled steel pipe through a numerical method for reliable judgment under various load conditions of the CJS composite structural system. Variable values optimized for the CJS synthetic structural system and the effects of multiple variables used for finite element analysis to present analytical modeling were compared and analyzed with experimental results. The Winfrith concrete model was used as a concrete material model that describes the confinement effect well, and the concrete structure was modeled with solid elements. Through geometric analysis of shell and solid elements, rectangular steel pipe columns and steel elements were modeled as shell elements. In addition, the slip behavior of the joint between the concrete column and the rectangular steel pipe was described using the Surface-to-Surface function. After finite element analysis modeling, simulation was performed for cyclic loading after assuming that the lower part of the foundation was a pin in the same way as in the experiment. The analysis model was verified by comparing the calculated analysis results with the experimental results, focusing on initial stiffness, maximum strength, and energy dissipation capability.

2-브로모메틸-1,3-디옥솔란을 이용한 2-에티닐피리딘의 중합을 통하여 측쇄에 디옥솔란 치환기를 갖는 새로운 이온성 공액구조 고분자를 합성하였다. 별도의 촉매없이도 중합반응이 잘 진행되어 높은 수율의 중합체를 얻을 수 있었다(76%). 합성한 고분자의 분자구조를 여러 가지 분석장비를 사용하여 분석한 결과 1,3-디옥솔란 부분을 갖는 설계한 공액구조 고분자임을 확인하였다. 고분자의 적외선분광분석 스펙트럼에서는 2110 cm-1 와 3293 cm-1에 서 관찰되었던 2-에티닐피리딘의 아세틸렌 특성피크를 보여주지 않는 대신 1620 cm-1 인근에서 공액이중결합의 탄소-탄소 이중결합의 특성 피크를 보다 강하게 보여주었다. 합성한 고분자의 전기전도도 및 전기-광학적 특성을 측정하고 분석하였다. 요오드로 도핑한 고분자의 전기전도도는 1.82 x 10-3 S/cm 였다.

본 논문에서는 조립트러스 매립형 합성보의 실험과 해석을 통하여 휨 및 전단의 구조적 거동을 분석한다. 본 합성보는 복부가 개방된 트러스를 콘크리트 속에 매입함으로써 콘크리트와의 맞물림작용 및 일체성이 뛰어남으로 휨재로서 완전합성 거동을 한다. 본 합성보에서는 콘크리트 단면의 복부를 가로지르는 외곽 2열의 강재 복재가 상, 하 접합부로 긴결되어 있어서 철근콘크리트 보의 스터럽(Stirrup)과 같은 전단보강재의 역할을 한다. 그러나 본 합성보에서는 복재 접합부의 강도에 따라서 전 단보강재인 경사재 및 수직재의 전단내력이 변화되므로 이에 맞는 구조적 안전성이 확보된 새로운 전단강도식을 제안한다. 실험 및 해석결과, 조립트러스 매립형 합성보의 모든 실험체는 휨강도에 대하여 강재앵커가 있는 완전합성보로 평가되며, 제안된 전단강도식은 구조적 안전성이 충분히 확보된 것으로 평가된다.

Bismuth vanadate (BiVO4) is considered a potentially attractive candidate for the visible-light-driven photodegradation of organic pollutants. In an effort to enhance their photocatalytic activities, BiVO4 nanofibers with controlled microstructures, grain sizes, and crystallinities are successfully prepared by electrospinning followed by a precisely controlled heat treatment. The structural features, morphologies, and photo-absorption performances of the asprepared samples are systematically investigated and can be readily controlled by varying the calcination temperature. From the physicochemical analysis results of the synthesized nanofiber, it is found that the nanofiber calcines at a lower temperature, shows a smaller crystallite size, and lower crystallinity. The photocatalytic degradation of rhodamine-B (RhB) reveals that the photocatalytic activity of the BiVO4 nanofibers can be improved by a thermal treatment at a relatively low temperature because of the optimization of the conflicting characteristics, crystallinity, crystallite size, and microstructure. The photocatalytic activity of the nanofiber calcined at 350oC for the degradation of RhB under visible-light irradiation exhibits a greater photocatalytic activity than the nanofibers synthesized at 400oC and 450oC.

We prepare ZnO nanoparticles by environmentally friendly synthesis using Cyathea nilgiriensis leaf extract. Various phytochemical constituents are identified through the assessment of ethanolic extract of plant Cyathea nilgiriensis holttum by GC-MS analysis. The formation of ZnO nanoparticles is confirmed by FT-IR, XRD, SEM-EDX, TEM, SAED and PSA analysis. TEM observation reveals that the biosynthesized ZnO nanopowder has a hexagonal structure. The calculated average crystallite size from the high intense plane of (1 0 1) is 29.11 nm. The particle size, determined by TEM analysis, is in good agreement with that obtained by XRD analysis. We confirm the formation of biomolecules in plant extract by FT-IR analysis and propose a possible formation mechanism of ZnO nanoparticles. Disc diffusion method is used for the analyses of antimicrobial activity of ZnO nanoparticles. The synthesized ZnO nanoparticles exhibit antimicrobial effect in disc diffusion experiments. The biosynthesized ZnO nanoparticles display good antibacterial performance against B. subtilis (Gram-positive bacteria) and K. pneumonia (Gram-negative bacteria). Bio-synthesized nanoparticles using green method are found to possess good antimicrobial performance.

최근 건설기술발전은 시공순서 세분화와 단면강성증진과 같은 기술변화로 선형조건 및 시공여건에 따라 요구되고 있는 다양한 교량 상부거더 형식이 개발되고 있다. 즉, 교량하부 형하공간이 부족한 곳에 설치하여야 하는 저형고 또는 장경간 거더와 같이 각각의 교량 설치 위치 상황에 따라 다른 형식을 요구되고 있다. 이러한 요구로 기존의 하로판형교를 개선한 아치 엣지보로 보강된 U형 강합성 교량을 연구대상 교량으로 선정하게 되었다. 따라서 본 연구는 아치 형태로 변화는 I형 강재의 상부 압축부에 고강도 콘크리트를 충전시켜 각각의 주거더를 구성시킨 하로교형식의 강합성 U형거더를 실물제작하여 구조거동을 분석하였다. 실험하중은 2단계로 구분하여 적용하였다. 1단계는 설계하중 1,200kN의 2.5배인 1차 실험하중 3,000kN을 재하하여 실험오차와 재료비선형성을 확인하였다. 2단계 실험하중 2,000kN에서는 선형분포를 나타냈고 하중제거상태에서 잔류변형이 발생하지 않았다. 분석결과, 아치단면으로 변하는 주거더와 주거더 상단의 충전콘크리트의 합성은 단부의 압축력 집중현상과 같은 아칭효과를 나타냈다.

MoO3 metal oxide nanostructure was formed by hydrothermal synthesis, and a perovskite solar cell with an MoO3 hole transfer layer was fabricated and evaluated. The characteristics of the MoO3 thin film were analyzed according to the change of hydrothermal synthesis temperature in the range of 100 ℃ to 200 ℃ and mass ratio of AMT : nitric acid of 1 : 3 ~ 15 wt%. The influence on the photoelectric conversion efficiency of the solar cell was evaluated. Nanorod-shaped MoO3 thin films were formed in the temperature range of 150 ℃ to 200 ℃, and the chemical bonding and crystal structure of the thin films were analyzed. As the amount of nitric acid added increased, the thickness of the thin film decreased. As the thickness of the hole transfer layer decreased, the photoelectric conversion efficiency of the perovskite solar cell improved. The maximum photoelectric conversion efficiency of the perovskite solar cell having an MoO3 thin film was 4.69 % when the conditions of hydrothermal synthesis were 150 ℃ and mass ratio of AMT : nitric acid of 1 : 12 wt%.