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        검색결과 1,979

        101.
        2023.08 KCI 등재 구독 인증기관 무료, 개인회원 유료
        Small-film-type ion sensors are garnering considerable interest in the fields of wearable healthcare and home-based monitoring systems. The performance of these sensors primarily relies on electrode capacitance, often employing nanocomposite materials composed of nano- and sub-micrometer particles. Traditional techniques for enhancing capacitance involve the creation of nanoparticles on film electrodes, which require cost-intensive and complex chemical synthesis processes, followed by additional coating optimization. In this study, we introduce a simple one-step electrochemical method for fabricating gold nanoparticles on a carbon nanotube (Au NP–CNT) electrode surface through cyclic voltammetry deposition. Furthermore, we assess the improvement in capacitance by distinguishing between the electrical double-layer capacitance and diffusion-controlled capacitance, thereby clarifying the principles underpinning the material design. The Au NP–CNT electrode maintains its stability and sensitivity for up to 50 d, signifying its potential for advanced ion sensing. Additionally, integration with a mobile wireless data system highlights the versatility of the sensor for health applications.
        4,000원
        102.
        2023.08 KCI 등재 구독 인증기관 무료, 개인회원 유료
        Perfluorooctanoic acid(PFOA) was one of widely used per- and poly substances(PFAS) in the industrial field and its concentration in the surface and groundwater was found with relatively high concentration compared to other PFAS. Since various processes have been introduced to remove the PFOA, adsorption using GAC is well known as a useful and effective process in water and wastewater treatment. Surface modification for GAC was carried out using Cu and Fe to enhance the adsorption capacity and four different adsorbents, such as GAC-Cu, GAC-Fe, GAC-Cu(OH)2, GAC-Fe(OH)3 were prepared and compared with GAC. According to SEM-EDS, the increase of Cu or Fe was confirmed after surface modification and higher weight was observed for Cu and Fe hydroxide(GAC-Cu(OH)2 and GAC-Fe(OH)3, respectively). BET analysis showed that the surface modification reduced specific surface area and total pore volumes. The highest removal efficiency(71.4%) was obtained in GAC-Cu which is improved by 17.9% whereas the use of Fe showed lower removal efficiency compared to GAC. PFOA removal was decreased with increase of solution pH indicating electrostatic interaction governs at low pH and its effect was decreased when the point of zero charges(pzc) was negatively increased with an increase of pH. The enhanced removal of PFOA was clearly observed in solution pH 7, confirming the Cu in the surface of GAC plays a role on the PFOA adsorption. The maximum uptake was calculated as 257 and 345 μg/g for GAC and GAC-Cu using Langmuir isotherm. 40% and 80% of removal were accomplished within 1 h and 48 h. According to R2, only the linear pseudo-second-order(pso) kinetic model showed 0.98 whereas the others obtained less than 0.870.
        4,000원
        103.
        2023.08 KCI 등재 구독 인증기관 무료, 개인회원 유료
        이 연구는 팬데믹(pandemic) 전후 국제항공여객 운송시장을 대상으로 항공편 운항에 의한 CO2 배출 특성과 변화를 체계적으 로 파악하는 것을 주요 목적으로 한다. 이를 위해 2019년과 2021년 2분기 전 세계 국제여객 항공편 스케줄 데이터를 기반으로 ICAO(International Civil Aviation Organization)의 CERT(CO2 Estimation and Reporting Tool) 인벤토리를 이용하여 노선 단위의 CO2 배출량을 추정한 후, 노선의 대권 거리와 항공기의 크기를 기준으로 구분된 하부시장에 따른 CO2 배출량과 배출 효율성의 분포와 변화를 비교분석하였다. 주요 분석 결과는 다음과 같다. 첫째, 2021년 2분기 전 세계 국제항공여객 운송시장의 CO2 배출량은 약 31.6백만 톤으로 추정되었으며. 2019년 동 분기(117.95백만 톤) 대비 약 73.21% 감소하였다. 두 시기 모두 5,000km 이상의 장거리 시장, 그리고 100~400석 항공기 운용 시장에서의 배출량 비중이 높게 나타났다. 다만 팬데믹 기간에는 5,000km 이상, 그리고 400석 이상 항공기 시장에서 CO2 배출량의 감소가 두드러지게 나타났다. 둘째, 2021년 2분기 시장의 CO2 배출 효율성은 2019년 동 분기 대비 약 4% 향상되었다. 두 시기 모두 노선의 대권 거리와 항공기의 크기가 증가할수록 배출 효율성이 감소하는 경향이 존재하였으며, 팬데믹 기간 중 일부 하부시장에서는 구형 및 초대형 기종들의 운항 감축(혹은 중단)이 두드러짐에 따라 배출 효율성이 향상되기도 하였다. 마지막으로 팬데믹 전후 주요 국제노선들의 CO2 배출 효율성 변화를 탐색한 결과, 글로벌 허브 공항들을 연결하는 대륙 간 장거리 노선들을 중심으로 효율성이 낮게 나타난 반면, 차상위 계층 공항들과 연결된 일부 노선들, 그리고 동남아・동북아의 주요 공항들을 연결하는 역내 노선들은 상대적으로 효율성이 높게 나타났다. 본 연구는 팬데믹 전후 전 세계 국제항공여객 운송시장의 운영 실적과 CO2 배출에 대한 세부 특성과 변화를 실증적으로 분석했다는 점에서 의의가 있다.
        5,100원
        104.
        2023.08 KCI 등재 구독 인증기관 무료, 개인회원 유료
        본 연구는 경남지역 대나무림에 대한 면적 및 입목축적량 산정과 함께 탄소저장량을 추정하기 위하여 수행되었다. 현재 산림청의 임업통계연보에는 대나무림에 대한 공간정보인 면적만 제시되고 있을 뿐, 입목축적에 대한 정보는 전혀 제공되고 있지 못하다. 따라서 본 연구에서는 최근에 만들어진 대나무 재적표를 활용하여 경남지역의 입목축적량을 계산하고, 여기에 탄소배출계수를 이용하여 탄소저장 량을 계산하였다. 대나무림에 대한 면적은 1/5,000 수치임상도에서 추출하였으며, 입목축적을 산정하기 위해 현지조사한 표준지 자료를 활용하였다. 표준지의 대나무는 개체목 별로 흉고직경과 수고에 재적표를 적용하여 표준지의 재적을 산정하였다. 경남지역 대나무의 공간분포 면적은 총 6,038ha로서, 전국 대나무림(20,262 ha)중 약 30%를 차지하는 것으로 나타났다. 경남지역 중에서는 하동군이 가장 많은 면적인 1,027 ha가 분포하는 것으로 나타났다. 경남지역의 시계열적인 분포면적 변화는 2013년 대비 2022년에 약 20.3% 감소하였으 며, 2019년 대비 약 0.4%가 감소하였다. 경남지역 대나무의 입목축적량은 2022년말 현재 148,510 ㎥인 것으로 계산되었으며, ha당 축적은 약 25 ㎥으로 나타났다. 그리고 경남지역 대나무 숲의 이산화탄소저장량은 287,277 tCO2 이었으며, ha당 저장량은 47.6 tCO2 인 것으로 나타났다.
        4,000원
        105.
        2023.08 KCI 등재 구독 인증기관 무료, 개인회원 유료
        본 연구는 에너지 저장 응용을 위한 PVI-PGMA/LiTFSI 고분자 막 전해질 및 CxNy-C 유연 전극의 합성 및 특성 에 관한 연구이다. 이중 기능을 갖는 PVI-PGMA 공중합체는 우수한 이온 전도성을 나타내었으며, PVI-GMA73/LiTFSI200 막 전해질은 1.0 × 10-3 S cm-1의 최고 전도도를 달성하였다. CxNy-C 전극의 전기화학적 성능을 체계적으로 분석하였으며, C3N2-C는 나노와이어와 다면체로 구성된 높은 연결성을 갖는 하이브리드 구조와 이중 Co/Ni 산화물을 포함하여 풍부한 산 화환원 활성 부위와 이온 확산을 용이하게 하는 특징으로 인해 958 F g-1의 최고용량 및 최소한의 전하 전달 저항(Rct)을 달성 하였다. 흑연 탄소 껍질의 존재는 충전-방전 동안 높은 전기화학적 안정성에 기여하였다. 이러한 결과들은 고성능 에너지 저 장 장치인 슈퍼커패시터 및 리튬 이온 전지와 같은 첨단 에너지 저장 장비에 PVI-PGMA/LiTFSI 고분자 막 전해질과 CxNy-C 전극을 활용하는 잠재력을 보여주었으며, 지속 가능하고 고성능의 에너지 저장 기술을 더욱 발전시키는 길을 열어가 고 있다.
        4,200원
        106.
        2023.08 KCI 등재 구독 인증기관 무료, 개인회원 유료
        본 총설은 탄소중립 및 에너지순환을 실현하기 위한 재생에너지로부터 그린수소 생산 전략 중 하나인 바이오수소 생산 및 정제법에 관해 소개하고자 한다. 바이오수소는 생물질과 미생물과 같은 재생에너지원을 이용하며, 상온 및 상압 등의 마일드한 실험조건에서 작동하여 에너지소비 및 공정비용이 적게 드는 친환경 공정으로 알려져 있다. 하지만, 이러한 바이오 수소를 상업적으로 이용하기 위해서는 해결해야 할 중요한 도전적인 과제가 존재한다. 특히, 바이오수소는 생물반응기내의 복합한 화학반응으로 합성되어, 낮은 수소생산 속도 및 반응기내 다양한 혼합물이 존재하여, 바이오수소 고순도화를 위해서 연속공정 형태의 분리 및 정제 기술이 반드시 필요하다. 이를 위해, 저온 증류법, 압력 흡착법, 분리막법 등을 비롯한 다양한 분리 및 정제 기술이 고순도 바이오수소를 얻기 위해 제안되었다. 본 총설에서는 바이오수소 생산 및 정제 연계화를 위한 비 다공성 고분자 분리막의 가능성에 대해 소개하고자 한다.
        4,500원
        107.
        2023.07 KCI 등재 구독 인증기관 무료, 개인회원 유료
        본 연구는 등유를 사용하는 농업용 난방기에서 배출되는 가 스를 포집하고, 농업용 난방기의 사용 연식에 따른 이산화탄 소의 배출농도를 파악하고자 수행되었다. 선형 회귀분석의 결과로 농업용 난방기의 연식에 따른 이산화탄소의 배출량은 R2 = 0.84로 y = 26.99x+721.98의 식을 따른다고 나타났다. 농업용 난방기의 사용 연식에 따라 세 그룹으로 분류하여 분 산분석을 수행하였다. 분산분석을 수행한 결과, 분석을 위해 설정한 유의확률 0.05보다 작은 2.1961×10-13으로 나타났으 며 이는 적어도 한 그룹에서 차이가 나타난다는 것을 의미한 다. 본 연구에서는 농업용 난방기의 기본적인 배출농도의 차 이를 분석하고자 기기의 제작사와 상관없이 농업용 난방기의 기기 연식만을 고려하여 배출가스 데이터를 수집하였다. 기 기의 연소 방식에는 제작사에 따라 연소 방식에 차이가 미미 하게 있었을 것으로 판단되며 데이터 변수의 개수가 늘어난다 면, SVR(support vector regression) 기반의 선형회귀 분석 등 을 실시하여 농업용 난방기의 이산화탄소 데이터가 온실가스 발생량 파악에 더욱 활용도가 높아질 것으로 판단된다. 추후 연구에서는 더욱 세분화된 데이터의 수집 방식을 따라 더욱 높은 정확도를 가진 결과값을 도출할 수 있다고 판단된다. 이 처럼 우리나라의 농업 분야에서 용도별 온실가스 발생량을 조 사하기 위하여 고정형 농기계인 농업용 난방기의 이산화탄소 발생량을 정확히 파악하여 온실가스 배출량 조사에 활용할 수 있을 것으로 판단된다.
        4,000원
        108.
        2023.07 KCI 등재 구독 인증기관 무료, 개인회원 유료
        이 연구는 한국과 호주 간 양자 협력 의제 중 자원 안보와 밀접한 관 련이 있는 탄소중립 기술 개발, 핵심 광물 공급망 그리고 농업 협력을 중심으로 살펴본다. 탄소중립 기술과 핵심 광물 공급망 같은 경우 2021 년 양국의 포괄적 동반자 관계 수립 이후 급격하게 협력이 시작되었고 정부와 주요 기업들이 적극적으로 참여하였다. 이에 반해 농업 협력은 2014년 양국의 자유 무역 협정 이후 협력위원회가 단 한 차례밖에 열리 지 않았다. 농업 협력은 향후 식량안보와 밀접한 관련이 있기에 협력이 순조롭게 진행될 수 있도록 노력을 기울일 필요가 있다. 향후 자원확보 와 공급망 구축이 그 무엇보다 중요한 시기에 양국의 상황을 면밀하게 관찰하고 부족한 부분의 협력을 적극적으로 모색하는 노력이 매우 중요 하다.
        5,800원
        109.
        2023.06 KCI 등재 구독 인증기관 무료, 개인회원 유료
        Selective doping of pyridinic nitrogen in carbon materials has attracted attention due to its significant properties for various applications such as catalysts and electrodes. However, selective doping of pyridinic nitrogen together with controlling skeletal structure is challenging in the absence of catalysts. In this work, four precursors including four fused aromatic rings and pyridinic nitrogen were simply carbonized in the absence of catalysts in order to attain mass synthesis at low cost and a high percentage of pyridinic nitrogen in carbon materials with controlled edges. Among four precursors, dibenzo[f,h] quinoline (DQ) showed an extremely high percentage of pyridinic nitrogen (96 and 86%) after heat treatment at 923 and 973 K, respectively. Experimental spectroscopic analyses combined with calculated spectroscopic analyses using density functional theory calculations unveiled that the C-H next to the pyridinic nitrogen in DQ generated gulf edge structures with controlled pyridinic nitrogen after carbonization. By comparing the reactivities among the four precursors, three main factors required for maintaining the pyridinic nitrogen in carbon materials with controlled edges, such as (1) high thermal stability of the pyridinic nitrogen, (2) the presence of one pyridinic nitrogen in one ring, and (3) the formation of gulf edges including pyridinic nitrogen to protect the pyridinic nitrogen by the C-H groups on the gulf edges, were revealed.
        6,000원
        110.
        2023.06 KCI 등재 구독 인증기관 무료, 개인회원 유료
        The development of functional carbon materials using waste biomass as raw materials is one of the research hotspots of lithium-sulfur batteries in recent years. In this work, used a natural high-quality carbon source—coffee grounds, which contain more than 58% carbon and less than 1% ash. Honeycomb-like S and N dual-doped graded porous carbon (SNHPC) was successfully prepared by hydrothermal carbonization and chemical activation, and the amount of thiourea used in the activation process was investigated. The prepared SNHPC showed excellent electrochemical energy storage characteristics. For example, SNHPC-2 has a large pore volume (1.85 cm3·g− 1), a high mesoporous ratio (36.76%), and a synergistic effect (S, N interaction). As the cathode material of lithium-sulfur batteries, SNHPC-2/S (sulfur content is 71.61%) has the highest specific capacity. Its initial discharge-specific capacity at 0.2 C is 1106.7 mAh·g−1, and its discharge-specific capacity after 200 cycles is still as high as 636.5 mAh·g−1.
        4,600원
        111.
        2023.06 KCI 등재 구독 인증기관 무료, 개인회원 유료
        Carbon/carbon composites are widely used in re-entry engineering applications thanks to their excellent mechanical properties at high temperatures, but they are easily oxidized in the oxygenated atmosphere. It is important to research their residual mechanical properties influenced by oxidation behaviour, in order to ensure the in-service safety. A microscale degradation model is proposed to predict the oxidation behavior based on the mass conservation and diffusion equations, the derived equivalent steady recession rate of composite is employed to evaluate the residual mechanical properties of the oxidized composite theoretically. A numerical strategy is proposed to investigate the oxidation mechanism of this composite. The differences in the degradation rate between the fiber and the matrix resulted in the steady state and an unchanged shape of the front. Residual mechanical properties of composite with three different domains of oxidation were simulated with a multiscale coupled model. The numerical results demonstrated that the mechanical properties of this composite decreased by 24–32% after oxidation for 30 min at 850 °C. Oxidation also caused the stress redistribution inside components, with the stress concentration diminishing their load-bearing capacity. The local areas of increased stress in the pyrocarbon matrix provided new ways for diffusion of oxygen into the pyrocarbon matrix and fibers.
        4,300원
        112.
        2023.06 KCI 등재 구독 인증기관 무료, 개인회원 유료
        In this study, gold nanoparticles (AuNPs) were synthesised using green chemistry to decorate multi-walled carbon nanotubes (MWCNTs) made from walnut shells transmission electron microscopy, field-emission scanning electron microscopy (FESEM), atomic force microscopy and fourier transforms infrared spectroscopy were used to diagnose MWCNTs and AuNPs. MWCNT-COOAu, MWCNT-COO and MWCNT-Au were diagnosed by Raman, energy dispersive X-ray analysis and FESEM. The effect of AuNPs, MWCNT-COO, MWCNT-COOAu and MWCNT-Au on pure and serum alkaline phosphatase (ALP) enzyme activity was studied in vitro using the enzyme-substrate 4-nitrophenyl disodium orthophosphate. For pure enzymes, Vmax slightly increased as the concentration of MWCNT-Au, MWCNT-COOAu and MWCNTCOO increased, whereas the Vmax values decreased as the concentration of AuNPs increased. The inhibition type for all NPs varied. For serum ALP enzyme, the Vmax values for Au-based NPs decreased as the concentration of NPs increased. The Vmax values exceeded the standard value at the concentrations of 25, 50 and 75 ppm for MWCNT-Au and MWCNT-COOAu, whereas the Vmax values increased over the standard value for all concentrations of AuNPs.
        4,500원
        113.
        2023.06 KCI 등재 구독 인증기관 무료, 개인회원 유료
        In this study, waste corrugated paper was used as carbon precursor with KOH-NaOH mixture (mole ratio was 51:49 and the melting point is 170 °C) as activator to prepare porous carbon at different reaction temperature and different mass ratio of KOH-NaOH mixture/waste corrugate paper fiber. The micro-morphology, pore structure information and composition of porous carbon were analyzed, and the formation mechanism of pores was investigated. The effect of activator amount and pyrolysis temperature on the morphology and structure of porous carbon were studied. The adsorption capacity of porous carbon was evaluated with the methylene blue as model pollutant. The effect of adsorbent amount, adsorption time and temperature on the adsorption performance of the porous carbon were analyzed. The maximum specific surface area is 1493.30 m2 ·g−1 and the maximum adsorption capacity of methylene blue is 518 mg·g−1. This study provides a new idea for efficient conversion and utilization of waste paper.
        4,200원
        114.
        2023.06 KCI 등재 구독 인증기관 무료, 개인회원 유료
        Single-walled carbon nanotube (SWNT) has gained significant interest as a transducer in various electrochemical sensing devices due to their unique structure, compatibility with biomolecules, and excellent electronic properties. As-prepared SWNTs are usually a mixture of semiconducting and metallic ones. Despite of the higher content of semiconducting components in mixed SWNTs, metallic properties are predominantly expressed due to the bundling issue of the SWNT during the fabrication process, limiting the applicability to bio-transistor application. Here, we present a multi-scale semiconducting electronic film of SWNTs as a transducing platform for electrochemical field-effect-transistor (eFET) suitable for the sensitive detection of subtle biological modulation. A genetically engineered filamentous M13 phage showing strong binding affinity toward SWNTs on its body surface was used as a biological material, allowing us to fabricate a large-scale transparent semiconducting nanocomposite. As the relative ratio of SWNT to M13 phage decreases, the on–off ratio of SWNT electronic film increases by 1200%. To show broad applicability, the multi-scale SWNT nanomesh-based eFET is applied for monitoring a variety of biological reactions in association with enzymes, aptamers, and even cyanobacteria. The biomimetic electronic material system with the capability of transducing biological responses at a large scale over a broad dynamic range holds excellent promise for biosensors, biofuel cells, and environment monitoring.
        4,000원
        115.
        2023.06 KCI 등재 구독 인증기관 무료, 개인회원 유료
        Carbon-based materials have emerged as an excellent class of biomedical materials due to their exceptional mechanical properties, lower surface friction, and resistance to wear, tear, and corrosion. Experimental studies have shown the promising results of carbon-based coatings in the field of biomedical implants. The reasons for their successful applications are their ability to suppress thrombo-inflammatory reactions which are evoked as an immune response due to foreign body object implantation. Different types of carbon coatings such as diamond-like carbon, pyrolytic carbon, silicon carbide, and graphene have been extensively studied and utilized in various fields of life including the biomedical industry. Their atomic arrangement and structural properties give rise to unique features which make them suitable for multiple applications. Due to the specificity and hardness of carbon-based precursors, only a specific type of coating technique may be utilized for nanostructure development and fabrication. In this paper, different coating techniques are discussed which were selected based on the substrate material, the type of implant, and the thickness of coating layer. Chemical vapor deposition-based techniques, thermal spray coating, pulsed laser deposition, and biomimetic coatings are some of the most common techniques that are used in the field of biomaterials to deposit a coating layer on the implant. Literature gathered in this review has significance in the field of biomedical implant industry to reduce its failure rate by making surfaces inert, decreasing corrosion related issues and enhancing biocompatibility.
        5,200원
        116.
        2023.06 KCI 등재 구독 인증기관 무료, 개인회원 유료
        This study investigated durian (Durio zibethinus) peels to produce powdered activated carbon (DPAC). The influence of process variables such as carbonization temperature, activation time, contact time, CO2 flow rate, and adsorption dosage was optimized using response surface methodology (RSM). A six-factor and two levels Box–Behnken design (BBD) was used to optimize the parameters. The independent variables were activation temperature (°C), duration (min), CO2 flow rate during the activation process (L/min), irradiation of adsorbent (kGy), irradiation duration (min), and adsorbent dosage (g) while phenol removal (mg/L) was the dependent variable (response). Following the observed correlation coefficient values, the design was fitted to a quadratic model (R2 = 0.9896). The optimal removal efficiency (97.25%) was observed at an activation temperature of 900 °C, activation time of 30 min, CO2 flow rate of 0.05 L/min, irradiation dose of 100 kGy, contact time of 35 min and adsorption dosage of 0.75 g. The optimal DPAC showed a BET surface of 281.33 m2/ g. The removal efficiency was later compared with a commercially available activated carbon which shows a 98.56% phenol removal. The results show that the durian peel could be an effective precursor for making activated carbon for phenol removal, and irradiation can significantly enhance surface activation.
        4,000원
        117.
        2023.06 KCI 등재 구독 인증기관 무료, 개인회원 유료
        In this work, subabul wood biomass was used to prepare carbon adsorbents by physical and chemical activation methods at various carbonization temperatures. The properties of the carbon adsorbents were estimated through characterization techniques such as X-ray diffraction, Fourier transform infrared spectroscopy, X–ray photo electron spectroscopy, laser Raman spectroscopy, scanning electron microscopy, CHNS-elemental analysis and N2 adsorption studies. Subabul-derived carbon adsorbents were used for CO2 capture in the temperature range of 25–70 °C. A detailed adsorption kinetic study was also carried out. The characterization results indicated that these carbons contain high surface area with microporosity. Surface properties were depended on treatment method and carbonization temperature. Among the carbons, the carbon prepared after treatment of H3PO4 and carbonization at 800 °C exhibited high adsorption capacity of 4.52 m.mol/g at 25 °C. The reason for high adsorption capacity of the adsorbents was explained based on their physicochemical characteristics. The adsorbents showed easy desorption and recyclability up to ten cycle with consistent activity.
        4,900원
        118.
        2023.06 KCI 등재 구독 인증기관 무료, 개인회원 유료
        This work reports the fabrication of a flexible Photodetector (PD) using Carbon Dots (CDs)/Polymer composite for Deep UV (DUV) photodetection. The CDs have been prepared using a simple and inexpensive heating process. The syncretic studies reveal the disordered graphitic core with surface functional groups and the excitation-dependent character of CDs. The synthesized CDs are stabilized via Poly Vinyl Alcohol (PVA) through a synergistic effect and investigated for different compositions (2–10 weight %) of CDs. The CDs/PVA composites shows improved absorbance at 208 and 335 nm compared to pure CDs owing to the bonding between them. This advantageous property of high absorption and photo response in the DUV region is utilized by employing CDs/PVA composite as a photo-sensing layer on the ITO-coated PET substrate in the PD. The performance of the PD was measured under dark, short (254 nm) and long (365 nm) UV region. Among all the compositions, 4% CDs/PVA PD exhibits superior performance in terms of high photo-to-dark current ratio (IPh/Id), responsivity and detectivity. The PD functioning and other parameters are discussed in detail and reported.
        4,200원
        119.
        2023.06 KCI 등재 구독 인증기관 무료, 개인회원 유료
        Volatile organic compounds (VOCs) are a paramount factor in air pollution of the environment. VOCs are vastly present in the wastewater discharged by the pharmaceutical industries. As it is evaporative in nature, it enters the environment spontaneously and causes air pollution, global warming, acid rain and climate change. VOCs must be treated before discharging or any other aerobic methods using an efficient catalyst. As the catalytic oxidation in the liquid phase is facile compared to the gas phase, this study investigated on catalytic liquid-phase oxidation of VOCs in model and real pharmaceutical wastewater. The model compounds of toluene-, ethylbenzene- and chlorobenzene-contaminated waters were treated separately along with the VOCs present in real pharmaceutical wastewater using a tungsten-based carbon catalyst. The tungsten was impregnated on the low-cost activated carbon matrix as it has good selectivity and catalytic property toward VOCs for facile catalytic operations. The metal catalysts were characterised by Fourier transform infrared spectroscopy, X-ray diffraction studies, and scanning electron microscopy with elemental and mapping analysis. The treatability was monitored by total organic carbon, ultra-violet spectroscopy and high-pressure liquid chromatography analysis. The tungsten-impregnated activated carbon matrix (WACM) has a catalytic efficiency toward toluene by 85.45 ± 1.78%, ethylbenzene by 93.9 ± 1.16%, chlorobenzene by 85.9 ± 2.26% and pharmaceutical VOCs by 85.05 ± 1.73% in 20 treatment cycles. The results showed that WACM worked efficiently in VOCs treatment, preventing the environment from air pollution. Furthermore, liquid-phase oxidation could easily be implementable on an industrial scale.
        5,200원
        120.
        2023.06 KCI 등재 구독 인증기관 무료, 개인회원 유료
        In this study, a milled carbon nanofiber-reinforced composite paint was prepared to enhance the anti-corrosive properties of concrete structures. Shorter-length (40 μm) milled carbon fibers (MCFs) showed an increased viscosity relative to longer MCFs (120 μm) owing to their 2 weeks (the decrease was especially strong in the acid solution). A carbon nanotube (CNT)- reinforced composite paint showed similar results in uniform distribution in the epoxy resin. The latter showed a decrease in viscosity owing to agglomerative movement in the epoxy resin. The surface hardness and tensile strength of the composite paint linearly increased as the carbon nanofiber loading was increased by up to 7.2 wt% in the epoxy resin, and slowly decreased after soaking in a sulfuric acid or sodium hydroxide solution for to those of the MCFs, whereas CNTs dispersed in isopropyl alcohol (IPA) in advance and mixed with resin showed lower hardness values than those without dispersion in IPA at the same loading. The mechanical properties such as the Shore D hardness and tensile strength of the MCF-reinforced composite paint increased significantly, resulting in a slower surface degradation of the composite paint concrete in a sulfuric acid and sodium hydroxide solution.
        4,000원