Core-shell polymers of methyl methacrylate-styrene system were prepared by sequential emulsion polymerization in the presence of sodium dodecyl benzene sulfonate(SDBS) as an emulsifier using ammonium persulfate(APS) in an initiator and the characteristics of these core-shell polymers were evaluated. Core-shell composite latex has the both properties of core and shell components in a particle, whereas polymer blends or copolymers show a combined physical properties of two homopolymers. This unique behavior of core-shell composite latex can be used in various industrial fields. However, in preparation of core-shell composite latex, several unexpected matters are observed, for examples, particle coagulation, low degree of polymerization, and formation of new particles during shell polymerization. To solve this matters, we study the effects of surfactant concentrations, initiator concentrations, and reaction temperature on the core-shell structure of PMMA-PSt and PSt-PMMA. Particle size and particles distribution were measured by using particle size analyzer, and the morphology of the core-shell composite latex was observed by using transmission electron microscope. Glass temperature was also measured by using differential scanning calorimeter. To identify the core-shell structure, pH of the composite latex solutions was measured.

The core-shell latex particles were prepared by sequential emulsion polymerization of alkyl methacrylate and styrene(ST) by using an water-soluble initiator(APS) after preparing monomer pre-emulsion in the presence of an anionic surfactant(SDBS). In organic/organic core-shell polymerization, the pre-emulsion method, which minimized required quantity of sulfactant, has been used to increase the conversion rate and the stability of core-shell latex particles as well as to reduce the formation of secondary particle that cause problems of soap-free emulsion during shell polymerization. We used several methods to observe the core-shell structure. The core-shell structure was studied by measuring pH change during hydrolysis by NaOH, glass transition temperature(Tg) by differential scanning calorimeter(DSC), morphology of latex by transmission electron microscope(TEM) and change of particle size and distribution by a particle analyzer.

CaCO3 absorbed sodium lauryl sulfate (SLS) surfactant was prepared, Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using styrene(St) as a shell monomer and potasium persulfate (KPS) as an initiator, We found that when CaCO3; core prepared by adding 2,0 wt% SLS, CaCO3 core/PSt shell polymerization was carried out on the surface of CaCO3 particle without forming the new PSt particle during St shell polymerization in the inorganic/organic core-shell polymer preparation, The structure of core-shell polymer were investigated by measuring the degree of decomposition of CaCO3 using HCl solution, thermal decomposition of polymer composite using thermogravimetric analyzer and morphology by scanning electron microscope.

본 연구에서는 노심지지배럴을 축솜형의 원통형 쉘로 이상화하여, 그의 모드 특성을 고찰하였다. 쉘의 모드 해석은 사용코드인 ANSYS를 이용하였으며, 일반적으로 사용하고 있는 요소인 SHELL61과 SHELL63을 이용하여 해석을 수행하였고 이들의 특성을 비교하였다. 또한 두께에 따른 모드 특성을 검토하여 쉘 요소의 사용 한계를 규정하였다. 한편 구멍이 있는 쉘과 없는 쉘의 모드 특성을 조사하여 구멍 및 그의 위치가 모드 특성에 미치는 영향을 파악하였다. 이들 모든 결과를 실험 및 이론에 의한 결과와 비교하였다.