In this study, graphene oxide (GO) was synthesized by the improved Hummers’ method. The degree of oxidation from graphite (Gi) to GO was determined through interlayer spacing calculated from X–ray diffraction. Besides, the effect of KMnO4: Gi ratios (X1), H2SO4 volume (X2), oxidation temperature (X3), oxidation time of stage 1 (X4), and oxidation time of stage 2 (X5) was screened by the Plackett–Burman model. The simultaneous impact of three factors that influenced the degree of oxidation (X1, X2, and X3) was studied by the Box–Behnken experimental model of response surface methodology to achieve suitable conditions for the GO synthesis process. The characterization of GO product was investigated via the modern analytical methods: X-ray diffraction, Raman spectroscopy, Fourier transform infrared spectroscopy, UV–Vis spectroscopy, field emission scanning electron microscopy, transmission electron microscopy, and atomic force microscopy. Inaddition, the study was also carried out on a pilot scale for orientation in industrial application with the yield of 14 g/batch.

본 연구의 목적은 스마트시티 구축의 핵심인 수소연료전지의 활용형태를 분석하고 해결방안을 제시하는 것이다. 수소연료전지를 활용하는 발전소의 경우 간헐성 문제가 없다는 장점 때문에 향후 가장 유망한 사용 형태로 분석됐다. 다만 많은 장점에도 불구하고 폭발 우려와 특정 수소 생산방식의 경우 이산화탄소 발생 문제 등으로 지역주민들의 반발이 지속적 으로 나타나고 있어 이를 해결하는 것이 스마트시티 구축의 주요 관건이 될 것으로 분석된다. 마지막으로 현재의 수소 생산 방식을 분석하고 이에 따른 문제점을 파악하여 스마트시티의 완전한 구축을 위한 해결책을 제시하였다.

PURPOSES : In this study, an eco-friendly mastic asphalt backfill material is developed to reduce production and construction temperatures by 40 ℃ compared with those recorded when using conventional hot-mix mastic asphalt backfill materials. METHODS : To reduce the production and construction temperatures, SIS polymer modifiers and gum rosin were selected, and gum rosin-modified SIS materials were applied to the mastic asphalt binder mix design. SIS is less viscous than SBS at high temperatures owing to its thermal characteristics, and incorporating gum rosin into SIS causes the latter to exhibit a loose and soft structure. To improve the performance of the mastic asphalt modified with SIS and gum rosin, three different filler mixes, i.e., 100% PMMA, 50% PMMA and 50% calcium carbonate, and 40% PMMA and 60% calcium carbonate were applied. RESULTS : The rosin-modified SIS reduces the viscosity of the developed mastic asphalt binders. In particular, incorporating 3.7% of gum rosin is beneficial to the mastic binder and does not degrade its low-temperature performance. Similarly, using 100% PMMA as a filler improves the performance but results in workability issues at high temperatures. CONCLUSIONS : Rosin-modified SIS and PMMA are promising alternatives for increasing the workability at high temperatures while maintaining the target performance of grade PG82-22 binders if the appropriate ratio of calcium carbonate is mixed with PMMA and an alternative filler comprising calcium carbonate is used.

돌발성 해충인 매미나방의 방제체계 수립을 위해 시판 유기농업자재 21종에 대한 살충 활성을 실내 검정하였다. 90% 이상의 살충 활성을 보인 유기농업자재 11종을 선발하였으며, 유효성분들을 분석하였다. PLS 제도의 대응하여 본 연구 결과는 돌발성 매미나방의 친환경 방제 및 향후 유기농업자재의 개발에도 활용이 가능할 것으로 생각된다.

The overall process, from the pre-treatment of aluminum substrates to the eco-friendly neutral electroless Ni-P plating process, was observed, compared, and analysed. To remove the surface oxide layer on the aluminum substrate and aid Ni-P plating, a zincation process was carried out. After the second zincation treatment, it was confirmed that a mostly uniform Zn layer was formed and the surface oxide of aluminum was also removed. The Ni-P electroless plating films were formed on the secondary zincated aluminum substrate using electroless plating solutions of pH 4.5 and neutral pH 7.0, respectively, while changing the plating bath temperature. When a neutral pH7.0 electroless solution was used, the Ni-P plating layer was uniformly formed even at the plating bath temperature of 50 oC, and the plating speed was remarkably increased as the bath temperature was increased. On the other hand, when a pH 4.5 Ni-P electroless solution was used, a Ni-P plating film was not formed at a plating bath temperature of 50 oC, and the plating speed was very slow compared to pH 7.0, although plating speed increased with increasing bath temperature. In the P contents, the P concentration of the neutral pH 7.0 Ni-P electroless plating layer was reduced by ~ 42.3 % compared to pH 4.5. Structurally, all of the Ni-P electroless plating layers formed in the pH 4.5 solution and the neutral (pH 7.0) solution had an amorphous crystal structure, as a Ni-P compound, regardless of the plating bath temperature.

In this paper, cycle performance analysis of two-stage compression two-stage expansion refrigeration system using eco-friendly refrigerants is presented to offer the basic design data for the operating parameters of the system. Eco-friendly refrigerant R600a(Isobutane) for freon refrigerant R22 were used working fluids in this study. The coefficient of performance(COP) of R600a is about 5% greater than that of R22 two-stage compression refrigeration system in the range of evaporation temperature –30℃∼-60℃. The coefficient of performance of two-stage compression and two-stage expansion refrigeration system decreases with the increasing condensation temperature and superheating degree but increases with the increasing evaporation temperature, subcooling degree and mass flow rate ration of intercooler.

In the 21st century, the demand for eco-friendly leather, such as eco-leather and vegan leather, is steadily increasing. This study examines the influence of eco-friendliness on consumers’ purchasing intentions and the possibility of eco-friendly changes in the fashion accessory market, which is dominated by leather material and leather substitutes. This study administered a questionnaire survey to 227 males and females between 20 and 60 years of age in Korea. With a 5-point Likert scale, data were collected on evaluation criteria when purchasing shoes and bags and purchasing intention of various leather substitute materials according to the democratic variables. The eco-friendliness attitude was divided into eco-consciousness and green behavior. As the eco-friendly attitude increased, most purchasing standards increased, but the purchasing criteria, such as trends, brands, and prices, did not correlate with the eco-friendly attitude. The eco-consciousness of a consumer had a high correlation with the design evaluation criteria, while the green behavior of the consumer aligned with durability and comfort criteria when purchasing a bag. There was a preference for recycled leather, vegetable leather, synthetic leather, and chemical leather, and the fabric type was ranked as natural fiber, biodegradable fiber, and synthetic fiber. Consumers with both green behavior and eco-consciousness are more likely to purchase biodegradable textiles and vegetable leather for the material of shoes and bags.

Various eco-friendly seed disinfection technologies have been developed due to the increase in the global demand for organic food. In order to produce sustainable and eco-friendly agricultural products in Korea, seed disinfection technologies for the production of wholesome seedlings have been researched in diverse ways compared to how they were examined in advanced countries. Both domestically and internationally, the eco-friendly seed disinfection technologies to secure the horticultural crops have been treated by biological or physical methods, such as hot water treatment with ultrasonic disinfection technology, or applying organic agricultural materials like organic acids in plant extracts. However, from a practical perspective, various applied technologies can be implemented in farm fields to disinfect significant agricultural crops, such as lettuce, Chinese cabbage, radish, watermelon, cucumber, paprika, red pepper, ginger, ginseng, and sesame seeds.

곤충생장조절제(IGR)은 대상 해충에 대한 특이성이 높고 환경에 대한 독성이 상대적으로 낮다는 장점으로 유기합성 살충제를 효과적으로 대체할 수 있는 유망한 수단으로 여겨진다. 현재 시판되는 곤충생장조절제는 작용 기작에 따라 유충호르몬 작용제(JHA), 탈피호르몬 작용제 (EA) 및 키틴 합성 저해제(CSI)의 세 가지로 구분된다. 최근 들어, 이집트숲모기의 Met과 FISC/CYC 유전자를 yeast two-hybrid system에 도 입하여 유충호르몬에 의해 매개되는 Met과 FISC/CYC의 결합을 in vitro에서 구현하였으며, yeast two-hybrid β-galactosidase assay를 통하 여 식물과 미생물 및 화합물 library로부터 다양한 유충호르몬 길항제(JHAN)가 분리되고 있다. 유충호르몬은 곤충의 발달, 생식, 휴면 등을 포함 한 다양한 생리 작용을 조절하기 때문에, 유충호르몬 길항제는 대상 해충의 내분비 신호 전달을 방해하여 비정상적인 발달 및 유충 단계에서의 치 사를 초래하며, 이는 유충호르몬 길항제가 넓은 기주 범위를 가진 살충제 개발에 효과적으로 이용될 수 있다는 것을 시사하였다. 따라서 본 논문 에서는 유충호르몬 길항제의 작용점인 Met에 의해 매개되는 유충호르몬의 신호 전달 체계와 친환경 살충제로서의 유충호르몬 길항제의 전망에 대해 알아보고자 하였다.

국제해사기구(IMO)에서 선박으로부터 배출되는 온실가스 등 대기오염물질을 감축하기 위해 해운분야 환경규제를 강화하고 있 어 전 세계적으로 조선․해운산업의 패러다임이 친환경․고효율 선박으로 전환되고 있다. 우리나라도 친환경선박을 보급하기 위해 2020 년부터 친환경선박 보급 확대 정책을 추진하고 있다. 본 논문은 우리정부의 친환경선박 보급정책에 대하여 전문가 12명을 대상으로 설문 조사를 실시하고, 계층분석법(AHP)을 활용하여 정책의 중요도를 평가하였다. 분석결과, 6개 중점추진과제 중에서 무탄소 및 저탄소 선박 개발을 위한 “미래 친환경선박 세계 선도 기술확보” 정책이 가장 중요한 것으로 나타났다. AHP 분석을 통한 친환경선박 정책의 중요도를 분석한 본 연구는 국제해양환경규제에 선제적으로 대응하고, 우리 해운 및 조선 산업의 보호와 신산업 육성 측면에서 예산 배분 및 정책 개발 등 정책 집행의 효율성을 제고할 수 있는 방향 설정을 위한 자료로 활용할 수 있을 것이다.

친환경 폴리우레탄은 다양한 분야에서 다양하게 사용되는 활용성이 높은 소재로 정의 할 수 있다. 이소시아네이트와 폴리올의 합성에 따른 다양한 구조적 특성 관계는 제조현장에서 사용상의 다양 성과 맞춤화를 제공하고 있다. 폴리우레탄의 특성은 부드러운 터치 코팅부터 바위처럼 단단한 건축 자재 에 이르기까지 활용 범위가 매우 다양하다. 이러한 기계적, 화학적 및 생물학적 특성과 맞춤의 용이성은 연구분야에서 뿐만 아니라 관련 산업에서도 엄청난 관심을 불러오고 있다. 수분산 폴리우레탄 재료의 성 능향상을 높이기 위해서는 원료의 배합을 조정하고 첨가제와 나노 소재등을 추가하는 등의 과정을 통해 이끌어 낼 수 있다. 본 연구에서는 의료 과학, 자동차, 코팅, 접착제, 페인트, 섬유, 해양 산업, 목재 복 합 재료 및 의류분야의 친환경 수분산 폴리우레탄 기본 화학 구조를 조명한다.

This paper considers the influence of internal heat exchanger and capillary tube on the efficiency of small refrigeration system using eco-friendly refrigerants such as R290, R600a, R1270, and R717. A refrigeration system using such internal heat exchanger and capillary tube may improve performance, but may degrade performance. Therefore, this paper used a mathematical model in a normal state to understand performance characteristics as to what change occurs when internal heat exchanger and capillary tube are attached to eco-friendly refrigerant based on R134a. In addition, the effects of operating conditions such as refrigerant flow rate, evaporation temperature, condensation temperature, subcooling degree internal heat exchanger length and capillary tube length were analyzed. The result showed that the evaporation temperature, condensation temperature, subcooling degree, internal heat exchanger length and capillary tube length had an effect on the refrigeration capacity and compression power. Therefore, it is necessary to design a refrigeration cycle using an eco-friendly refrigerant by grasping these effects in detail.