Water quality of the Koejong-reservoir was estimated by using the ecological model to evaluate the effects of industrial sewage discharge. State variables consist of POC, DOC, phytoplankton, DIP, DIN, DO and COD. Initial conditions for the compartment are applied to the model based on the observed results. The reproducibility was found to be satisfactory with the relative error ranging between the calculated value and the observed value. Water quality simulation was conducted by applying additional industrial sewage discharge into the Koejong-reservoir. The concentrations of COD, Chl.a, DIP and COD showed fluctuations of a narrow range. The increment percentages of Chl.a, COD and DIP were 26.6%, 20.2% and 18.2%, respectively. In the case of DO, the concentration decreased 4.8%.

A three-dimensional ecological model (EMT-3D) was applied to Nonylphenol in Tokyo Bay. EMT-3D was calibrated with data obtained in the study area. The simulated results of dissolved Nonylphenol were in good agreement with the observed values, with a correlation coefficient(R) of 0.7707 and a coefficient of determination (R2) of 0.5940. The results of sensitivity analysis showed that biodegradation rate and bioconcentration factor are most important factors for dissolved Nonylphenol and Nonylphenol in phytoplankton, respectively. In the case of Nonylphenol in particulate organic carbon, biodegradation rate and partition coefficient were important factors. Therefore, the parameters must be carefully considered in the modeling. The mass balance results showed that standing stocks of Nonylphenol in water, in particulate organic carbon and in phytoplankton are 8.60×105 g, 2.19×102 g and 3.78×100 g, respectively. With respect to the flux of dissolved Nonylphenol, biodegradation in the water column, effluent to the open sea and partition to particulate organic carbon were 6.02×103 g/day, 6.02×102 g/day and 1.02×101 g/ day, respectively.