In this study, the performances of H2S, NH3, and HCl sensors for real-time monitoring in small emission facilities (4, 5 grades in Korea) were evaluated at high concentration conditions of those gases. And the proper approach for the collection of reliable measurement data by sensors was suggested through finding out the effect on sensor performances according to changes in temperature and humidity (relative humidity, RH) settings. In addition, an assessment on sensor data correction considering the effects produced by environmental settings was conducted. The effects were tested in four different conditions of temperature and humidity. The sensor performances (reproducibility, precision, lower detection limit (LDL), and linearity) were good for all three sensors. The intercept (ADC0) values for all three sensors were good for the changes of temperature and humidity conditions. The variation in the slope value of the NH3 sensor showed the highest value, and this was followed by the HCl, H2S sensors. The results of this study can be helpful for data collection by enabling the more reliable and precise measurements of concentrations measured by sensors.

Molten salt solutions consisting of eutectic LiCl-KCl and concentrations of samarium chloride (0.5 to 3.0 wt%) at 500℃ were analyzed using both cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). The CV technique gave the average diffusion coefficient for Sm3+ over the concentration range. Equipped with Sm3+ diffusion coefficient, the Randles-Sevcik equation predicted Sm3+ concentration values that agree with the given experimental values. From CV measurements; the anodic, cathodic, and half-peak potentials were identified and subsequently used as a parameter to acquire EIS spectra. A six-element Voigt model was used to model the EIS data in terms of resistance-time constant pairs. The lowest resistances were observed at the half-peak potential with the associated resistance-time constant pairs characterizing the reversible reaction between Sm3+ and Sm2+. By extrapolation, the Voigt model estimated the polarization resistance and established a polarization resistance-concentration relationship.