Twenty organic chemical substances (Table 2) were isolated from untreated wastewater, as well as treated wastewater, collected at 76 companys of 9 industry group located in the basin of Youngsan River. Those organic compounds were analyzed by Gas Chromatography/Mass Spectrometry(GC/MS) and confirmed through comparison with each standard reagents. Phenol, which was not detected in the raw wastewater, was identified in the effluent of treatment facility, indicating that phenol is generated from isopropylbenzene of plant wastewater.

To study the optimum conditions of composting with industrial wastewater sludge, the variations of temperature and CO_2 generation amount during the composting periods were investigated. The conditions were that industrial wastewater added to bulking agents such as sawdust and rice hull was used, and differently treated with microorganism seeding or not, initial C/N ratios, air flow rate and initial moisture contents, respectively. The results were summarized as follows ; Seeding 5% of microorganism was higher the temperature than not seeding. And using sawdust as bulking agents, and adjusting 30∼40 of initial C/N ratio, 200㎎/ℓ·min. of air flow rate and 67∼68% of initial moisture contents were higher the temperature than any other conditions. Seeding 5% of microorganisms was higher CO_2 generation amount than not seeding. And that was much in the order of 7∼40, 30∼34 and 22∼23 of initial C/N ratio. Judging from the results, it should be considered that the optimum conditions in the composting of industrial wastewater sludge were seeding of 5% microorganisms, and adjusting 30∼34 of initial C/N ratio, 200㎎/ℓ·min. of air flow rate and 67∼68% of initial moisture contents. The contents of inorganic matters and C/N ratio during the composting periods at optimum condition were a little increased, and heavy metals contents after composting were lower than standard for fertilizer.

Mercury- and cadmium-resistant bacteria were isolated from an industrial complex wastewater of Taejon area. All of them were motile, gram negative rods. In the results of physicochemical test and VITEK card test, HMI was identified with Acinetobacter calcoaceticus, CM3 was identified with Comamonas acidovorans, HM2, HM3, CM1, and CM4 were Pseudomonas sp., but HM4 and CM2 were unidentified. They were tested for susceptibility to 14 heavy metals. Mercury-resistant bacteria(HM1, HM2, HM3, and HM4) were sensitive to low concentration(100∼400ppm) of Cd^2+, Co^2+, Zn^2+, and Ni^2+ while cadmium-resistant bacteria(CM1, CM2, CM3, and CM4) showed resistance up to the high concentration(600∼1,200ppm) of these metal ions. As a result of resistance spectrum test of mercury-resistant bacteria, HM1 was broad-spectrum strain, HM2, HM3, and HM4 were narrow-spectrum strains. Transmission electron microscopic examination of cell wall of HM1 culture grown with and without 100ppm of HgCl_2 showed remarkably morphological abnormalities. In the result of atomic absorption spectrometric analysis of cadmium-resistant bacteria grown at 200ppm of CdCl_2 for 6h, all of them accumulated cadmium(14ppm∼57ppm) in cell. In cadmium-resistant bacteria, CM1, CM2, and CM4 were spared from the inhibitory effect of Cd^2+ by the addition of Mn^2+, CM4 were also spared from the inhibitory effect of Cd^2+ by the addition of Mn^2+ as well as Zn^2+.

Chemical characteristics of the industrial wastewater sludge, degradation of the sludge in soil and CO2 generation and changes of nitrogen in soil treated with the sludge were investigated. The results obtained were summarized as follows: 1. Degradation rate of the sludge in soil was 26% at natural temperature, and 33% at incubation temperature at 12 weeks after treatment. 2. T-C, T-N and the C/N ratio of sludge in soil was 16.0%, 0.63% and 26, respectively, at natural temperature, and 15.0%, 0.65% and 23, respectively, at incubation temperature at 12 weeks after treatment. 3. Camulative CO2 generation in soil treated with 1%, 3% and 5% of sludge was 284, 440 and 512 ㎎/100g, respectively, at natural temperature, and 440, 558 g and 654 ㎎/100 g, respectively, at incubation temperature at 12 weeks after treatment. 4. Changes of inorganic nitrogen in soil treated with 1%, 3% and 5% of sludge were 7.8, 12.8 and 16.3 ㎎/100g, respectively, at incubation temperature at 12 weeks after treatment. Mineralization ratio of organic nitrogen in soil treated with 1%, 3% and 5% of sludge was 10.7%, 13.6% and 15.2%, respectively, at incubation temperature at 12 weeks after treatment. 5. Changes of pH in soil treated with 1%, 3% and 5% of Industrial wastewater sludge were in the range of 6.7∼7.5 at natural temperature, and 6.1∼7.9 at incubation temperature at 12 weeks after treatment.