BNKT Ceramics, one of the representative Pb free based piezoelectric ceramics, constitutes a perovskite(ABO3) structure. At this time, the perovskite structure (ABO3) is in the form where the corners of the octahedrons are connected, and in the unit cell, two ions, A and B, are cations, A ion is located at the body center, B ion is located at each corner, and an anion O is located at the center of each side. Since Bi, Na, and K sources constituting the A site are highly volatile at a sintering temperature of 1100℃ or higher, it is difficult to maintain uniformity of the composition. In order to solve this problem, there should be suppression of volatilization of the A site material or additional compensation of the volatilized. In this study, the basic composition of BNKT Ceramics was set to Bi0.5(Na0.78K0.22)0.5TiO3 (= BNKT), and volatile site (Bi, Na, and K sources) were coated in the form of a shell to compensate additionally for the A site ions. In addition, the physical and electrical properties of BNKT and its coated with shell additives(= @BNK) were compared and analyzed, respectively. As a result of analyzing the crystal structure through XRD, both BNKT(Core) and @BNK(Shell) had perovskite phases, and the crystallinity was almost similar. Although the Curie temperature of the two sintered bodies was almost the same (TC = 290 ~ 300 ℃), it was confirmed that the d33 (piezoelectric coefficient) and Pr (residual polarization) values were different. The experimental results indicated that the additional compensation for a shell additive causes the coarsening, resulting in a decrease in sintering density and Pr(remanent polarization). However, coating shell additives to compensate for A site ion is an effective way to suppress volatilization. Based on these experimental results, it would be the biggest advantage to develop an eco-friendly material (Lead-free) that replaced lead (Pb), which is harmful to the human body. This lead-free piezoelectric material can be applied to a biomedical device or products(ex. earphones (hearing aids), heart rate monitors, ultrasonic vibrators, etc.) and skin beauty improvement products (mask packs for whitening and wrinkle improvement).

The study used the whole-life carbon assessment method to conduct a thorough carbon-neutral evaluation of a standard steel structure. To further assess carbon emissions, 11 design-changed models were evaluated, with changes made to the span between beams and columns. The results of the carbon emission assessment showed savings of approximately 13.1% by implementing the stage of the beyond life cycle. Additionally, the evaluation of carbon emissions through design changes revealed a difference of up to 42.2%. These findings confirmed that recycling and structural design changes can significantly reduce carbon emissions by up to 48.6%, making it an effective means of achieving carbon neutrality. It is therefore necessary to apply the stage of beyond life cycle and structural change to reduce carbon emissions.

Hexagonal bolt, nut, fittings, and high-pressure valves with special alloy play an important role in many industrial products, for instance, such as semiconductor facilities, hydrogen stations and fuel cell electric vehicles. The purpose of this study is to investigate the structural stability of turning wheel using the reaction force of roller in variable hexagonal rolling die. As the results, the bearing groove had the possibility of damage in turning wheel, especially, in case of Bottom condition. Furthermore, the turning wheel showed structural instability by using safety factor but structural stability using strength, respectively, as a safety criterion.

본 논문에서는 3차원 엮임 재료의 재료 물성치들을 효율적으로 분석하고 추후 최적설계 연구에 활용하기 위해서 파라메트릭 배치 해석 워크플로우를 제시하였다. 3차원 엮임 재료를 구성하는 와이어들 사이의 간격을 설계 매개변수로 하는 파라메트릭 모델에 대해 서 임의의 변수 조합을 가지는 2,500개의 수치 모델을 생성하였으며, 상용 프로그램인 매트랩과 앤시스의 여러 모듈을 사용하여 체적 탄성계수, 열전도도, 유체투과율과 같은 다양한 재료 물성치들을 배치 해석을 통해서 자동으로 얻어질 수 있도록 구성하였다. 이와 같 이 얻어진 대용량의 재료 물성치 데이터베이스를 활용해서 회귀 분석을 수행하였으며, 그 결과 설계 변수들과 재료 물성치 사이의 경 향성과 수치 해석 결과의 정확도를 검증하였다. 또한 확보된 데이터베이스를 통해서 3차원 엮임 재료의 물성치를 예측할 수 있는 인 공 신경망을 구성하고 학습시켰으며, 그 결과 임의의 설계 매개변수 값들을 가지는 엮임 재료 모델에 대해서 구조 및 유체해석 과정 없 이도 높은 정확도로 재료 물성치들을 추정할 수 있음을 확인하였다.

PURPOSES : The numeric-based Highway Pavement Management System (HPMS), along with an advanced three-dimensional pavement condition monitoring profiler vehicle (3DPM), in South Korea has presented remarkable advancements in pavement management since the early 2000. Based on these results, visual distress on pavement surfaces can be easily detected and analyzed. Additionally, the entire expressway pavement surface conditions in South Korea can be easily monitored using the current graphical user interface-based advanced information graphic (AIG) approach. Therefore, a critically negative pavement section can be detected and managed more easily and efficiently. However, the actual mechanical performance of the selected pavement layer still needs to be investigated in a more thorough manner not only to provide more accurate pavement performance results but also to verify the feasibility of the current 3DPM and AIG approaches. In this study, the low-temperature performance of the selected asphalt pavement layer section was evaluated to further verify and strengthen the feasibility of the current 3DPM and AIG approaches developed by the Korea Expressway Corporation. METHODS : Based on 3DPM and AIG approach, the positive and negative-riding-quality road sections were selected, respectively. The asphalt material cores were extracted from each section then bending beam rheometer mixture creep test was performed to measure their low-temperature properties. Based on the experimental results, thermal stress results were computed and visually compared. RESULTS : As expected, the asphalt material from the negative driving performance section presented a poorer low-temperature cracking resistance than that from the positive driving performance section. CONCLUSIONS : Current 3DPM equipment can successfully evaluate expressway surface conditions and the corresponding material performance quality. However, more extensive experimental studies are recommended to verify and strengthen the findings of this study

Studies regarding the relationship between purchases and happiness have consistently found an experiential advantage: people are happier when purchasing experiential products (e.g., vacations and concerts) than material products (e.g., clothes and electronics) (Caprariello & Reis, 2013; Carter & Gilovich, 2010, 2012; Pchelin & Howell, 2014; van Boven and Gilovich, 2003). This phenomenon (i.e., experiential advantage) may make marketing efforts of service firms or any companies selling experiences relatively more effective and productive in that consumers will derive a great amount of purchase happiness. On the other hand, the same phenomenon may indicate innate challenges and hurdles for firms selling products carrying materialistic features. Considering the material-experiential spectrum, approximately 50% of the industries are seeming faced with this issue. In this research, we propose a solution with which mainly material-focused products can loom more experiential, thereby benefiting from the experiential advantage. In other words, we investigate how material goods can be perceived as experiential and they can offer greater purchase satisfaction compared to when they remain as merely materialistic. Specifically, noting that reasons for experiential advantages are originated from social aspects of experiential goods (e.g., self-presentation to other people, conversational values, reputation-building, etc.), the current study shows that posting on social media can imbue social aspects, which is a key drive of the experiential advantage.

The development of functional carbon materials using waste biomass as raw materials is one of the research hotspots of lithium-sulfur batteries in recent years. In this work, used a natural high-quality carbon source—coffee grounds, which contain more than 58% carbon and less than 1% ash. Honeycomb-like S and N dual-doped graded porous carbon (SNHPC) was successfully prepared by hydrothermal carbonization and chemical activation, and the amount of thiourea used in the activation process was investigated. The prepared SNHPC showed excellent electrochemical energy storage characteristics. For example, SNHPC-2 has a large pore volume (1.85 cm3·g− 1), a high mesoporous ratio (36.76%), and a synergistic effect (S, N interaction). As the cathode material of lithium-sulfur batteries, SNHPC-2/S (sulfur content is 71.61%) has the highest specific capacity. Its initial discharge-specific capacity at 0.2 C is 1106.7 mAh·g−1, and its discharge-specific capacity after 200 cycles is still as high as 636.5 mAh·g−1.

For the commercialization of hydrogen energy, a technology enabling safe storage and the transport of large amounts of hydrogen is needed. Porous materials are attracting attention as hydrogen storage material; however, their gravimetric hydrogen storage capacity (GHSC) at room temperature (RT) is insufficient for actual use. In an effort to overcome this limitation, we present a N-doped microporous carbon that contains large proportion of micropores with diameters below 1 nm and small amounts of N elements imparted by the nitrogen plasma treatment. The N-doped microporous carbon exhibits the highest total GHSC (1.59 wt%) at RT, and we compare the hydrogen storage capacities of our sample with those of metal alloys, showing their advantages and disadvantages as hydrogen storage materials.

Hexagonal bolt, nut, fittings, and high-pressure valves with special alloy play an important role in many industrial products, for instance, such as semiconductor facilities, hydrogen stations and fuel cell electric vehicles. The purpose of this study is to predict the reaction force of roller in drawing system. Numerical analysis was conducted to obtain data for designing the turning wheel, which is key parts in drawing system, using the reaction force of roller. As the results, the reaction force of X axis direction was about 9~20 times larger than that of Z axis direction and the reaction force of Y axis direction was negligible. The maximum reaction force of roller was the case of 4 stage and the numerical results in this study could be helped for designing the mechanical parts of variable hexagonal rolling die.

The Ag/WC electrical contacts were prepared via powder metallurgy using 60 wt% Ag, 40 wt% WC, and small amounts of Co3O4 with varying WC particle sizes. After the fabrication of the contact materials, microstructure observations confirmed that WC-1 had an average grain size (AGS) of 0.27 μm, and WC-2 had an AGS of 0.35 μm. The Ag matrix in WC-1 formed fine grains, whereas a significantly larger and continuous growth of the Ag matrix was observed in WC-2. This indicates the different flow behaviors of liquid Ag during the sintering process owing to the different WC sizes. The electrical conductivities of WC-1 and WC-2 were 47.8% and 60.4%, respectively, and had a significant influence on the Ag matrix. In particular, WC-2 exhibited extremely high electrical conductivity owing to its large and continuous Ag-grain matrix. The yield strengths of WC-1 and WC-2 after compression tests were 349.9 MPa and 280.7 MPa, respectively. The high yield strength of WC-1 can be attributed to the Hall–Petch effect, whereas the low yield strength of WC-2 can be explained by the high fraction of high-angle boundaries (HAB) between the WC grains. Furthermore, the relationships between the microstructure, electrical/mechanical properties, and deformation mechanisms were evaluated.

층상 반무한체에서의 확률론적 완전파형역산을 위한 Markov chain Monte Carlo (MCMC) 모사 기법을 정식화한다. Thin-layer method를 사용하여 조화 수직 하중이 작용하는 층상 반무한체의 지표면에서 추정된 동적 응답과 관측 데이터와의 차이 및 모델 변수 의 사전 정보와의 차이를 최소화하도록 목적함수와 모델 변수의 사후 확률밀도함수를 정의한다. 목적함수의 기울기에 기반하여 MCMC 표본을 제안하기 위한 분포함수와 이를 수락 또는 거절할지 결정하는 수락함수를 결정한다. 기본 진동모드 뿐만이 아니라 고 차 진동모드가 우세한 경우를 포함하여 다양한 층상 반무한체의 전단파 속도 추정에 제안된 MCMC 모사 기법을 적용하고 그 정확성 을 검증한다. 제안된 확률론적 완전파형역산을 위한 MCMC 모사 기법은 층상 반무한체의 전단파 속도와 같은 재료 특성의 확률적 특 성을 추정하는 데 적합함을 확인할 수 있다.

Cyanobacteria Pseudanabaena strains are known to produce 2-MIB (odorous material) in freshwater systems, thereby causing problems in water use. However, their physiological responses to environmental factors in relation with 2-MIB production is not well explored. This study was conducted to evaluate the effect of temperature on the growth and 2-MIB production of Pseudanabaena redekei. The experimental cyanobacteria strains were separated from the Uiam Reservoir (North Han River) and cultured in the BG-11 medium. Temperature was set to 10, 15, 20, 25, and 30℃ for the experiment, in the reflection of the seasonal water temperature variation in situ. For each temperature treatment, cyanobacterial biomass (Chl-a) and 2-MIB concentration (intra-cellular and extra-cellular fractions) were measured every 2 days for 18 days. Both maximal growth and total 2-MIB production of P. redekei appeared at 30℃. While intra-cellular 2-MIB contents were similar (26~29 ng L-1) regardless of treated temperatures, extra-cellular 2-MIB concentration was higher only in high temperature conditions (25~30℃), indicating that the extents of 2-MIB biosynthesis and release by P. redekei vary with temperature. The 2-MIB productivity of P. redekei was much higher in low-temperature conditions (10~15℃) than high temperature conditions (25~30℃). This study demonstrated that temperature was a critical factor contributing to 2-MIB biosynthesis and its release in cell growth (r=0.605, p<0.01). These results are important to understand the dynamics of 2-MIB in the field and thereby provide basic information for managing odorous material in drinking water resources.

The operation and decommissioning of nuclear power plants (NPPs) creates waste in the process of handling radioactively contaminated material, which must be disposed of in a repository or can be recovered of in the same way as conventional waste in the course of handling radioactively contaminated materials. For buildings or sites of NPPs it also has to be decided under what conditions they can continue to be used for other, conventional purposes or demolished. This decision is referred to as “release from supervision under nuclear and radiation protection law” or “clearance” in short. The clearance levels applicable in Germany according to the Radiation Protection Ordinance have been defined such that a radiation dose (hereinafter referred to as “dose”) of 10 μSv per year is not exceeded. The vast majority of the materials resulting from the dismantling of a nuclear power plant (e.g. most of the massive concrete structures) are neither contaminated nor activated. Thus, there is no need to treat these materials as radioactive waste. Emplacement of uncontaminated masses which in Germany is essentially several million tonnes of building rubble in a repository would require additional construction of such facilities, which, in view of the negligible hazard potential, from the point of view of the Nuclear Waste Management Commission (ESK) is clearly to be rejected both economically and, in particular, ecologically. Alternative ways are increasingly discussed in public, such as the abandonment of buildings after gutting, i.e. refraining from demolition of the controlled area buildings of NPPs. Also, another proposal discussed in public, the landfilling or the long-term storage of cleared material at the site, does not offer any safety-related advantages either in the view of the ESK. If, after completion of all dismantling work, the building has been decontaminated such that the clearance levels for buildings are complied with further use of the building rubble resulting from demolition is harmless from a radiological point of view. For these reasons, Germany has deliberately decided to use clearance as an essential measure in the dismantling of NPPs. If it is intended to conventionally reuse or depose of virtually contaminant-free material from controlled areas, it must first undergo a clearance procedure. The prerequisites that must be fulfilled for clearance are regulated in the Radiation Protection Ordinance, which includes two basic clearance pathways: unrestricted and specific clearance. In the following, the basic process of clearance is briefly presented and illustrated for a better understanding. It comprises five steps. Step 1-Radiological characterization by sampling, Step 2-Dismantling of plant components in the controlled area, Step 3- Decontamination, Step 4-Decission measurements, Step 5-Clearacnce and further management. The entire clearance process is governed by a clearance notice and is carried out under the supervision of the competent authority under nuclear and radiation protection law or the independent authorized expert commissioned by it. The clearance pathways contained in the Radiation Protection Ordinance have proven themselves in practice. They permit safe and proper management of material from dismantling and release of the site from supervision under nuclear and radiation protection law. These German regulatory procedures should be taken into account and deregulation and removal should be used as appropriate and necessary tools in the process of decommissioning NPPs in order to return non-hazardous materials to the material cycle or for conventional disposal.

Backfill is one of the key elements of deep geological disposal. The backfill material is used to fill disposal tunnels and is mainly composed of swellable clay, preventing the migration of nuclide and structurally supporting the tunnel. The selection and application of backfill material are critical for the stable and efficient disposal of spent fuel. Therefore, it is essential to secure various candidate materials for backfill and to comprehensively understand the properties and behavior of these materials. Recently, the Korea Atomic Energy Research Institute has selected a candidate material called Bentonil-WRK and is evaluating its applicability. To utilize this material as backfill, the safety function of a mixed backfill concept, consisting of sand and Bentonil-WRK, was assessed. The swelling pressure was measured as a function of dry density for a bentonite/silica sand mix ratio of 3/7. The results showed that the swelling pressure ranged from 0.15 to 0.273 MPa, depending on the dry density, with higher dry densities resulting in higher swelling pressures. The measured swelling pressure met the target performance criteria suggested by SKB and Posiva (i. e., 0.1 MPa), but did not meet the design requirement for swelling pressure (i. e., 1 MPa). This indicate the need for further research after increasing the mass fraction of bentonite (e. g., mix ratio 4/6 or more). The results of this study are expected to be used in the selection of candidate backfill materials and the establishment of design guidelines for engineered barrier backfill.

A disposal system for spent nuclear fuel divides into two parts; (1) engineered barriers including spent nuclear fuel, canister, buffer and backfill, (2) natural barriers surrounding engineered barriers. Sorption and diffusion are main retardation mechanisms for the migration of released radionuclides. We analyzed the sorption properties of radionuclides for bentonite as a buffer material and collected/ evaluated the distribution coefficients for the purpose of safety assessment for the deep geological disposal of a spent nuclear fuel. Through this, we presented recommended distribution coefficients for radionuclides required for the safety assessment. This work included the radionuclides as follows; alkali and alkaline earth metals (Cs, Sr, Ba), lanthanides (Sm), actinides (Ac, Am, Cm, Np, Pa, Pu, Th U), transition elements (Nb, Ni, Pd, Tc, Zr), and others (C, Cl, I, Rn, Se, Sn). The sorption of radionuclides affected various geochemical conditions such as pH/carbonates, redox potential, ionic strength, radionuclide concentration, kinds and amounts of minerals, and microbes. Among the evaluated radionuclides, Cs, Ni, Pd, and Ra is sensitive to the ionic strength, while Np, Pu, U, Se, and, Tc is sensitive to the redox condition. For the evaluation of distribution coefficients, the data from Sweden (SKB), Finland (Posiva), Switzerland (Nagra), and Japan (JAEA) were collected, analyzed, and the recommended distribution coefficients were suggested.

The damaged spent fuel rods must be stabilized by encapsulation or dry re-fabrication technologies before geological disposal. For applying the dry re-fabrication technology, we manufactured a vertical type furnace to perform the fuel material recovery from damaged fuel rods by oxidative decladding technology. As driving forces to accelerate oxidative decladding rate, magnetic vibration and pulse hammering generated by a pneumatic cylinder were used in this study. The oxidative decladding efficiency and recovery rate of fuel oxide powder with rod-cut length, oxidation temperature and time, oxygen concentration, and gas mixtures were investigated using simfuel rod-cuts in a vertical furnace for fuel material recovery and powder quality improvement. The oxidative decladding was performed for 2.5-10 h as following operation parameters: simfuel rod-cut length of 50-200 mm, oxidative temperature from 450 to 580°C, oxygen concentration of 49.5 or 75.6%, and gas mixtures in O2/Ar or O2/N2. In magnetic vibration, oxidative decladding was progressed only at bottom portion of fuel rodcut. Whereas, oxidative decladding in pulse hammering was occurred at both top and bottom portions of fuel-rod. In pulse hammering method, the oxidative decladding conditions to declad rod-cuts of 50- 200 mm in length were established to achieve both decladding efficiency of ~100% and fuel material recovery rate of > 99%. These conditions were as follows: oxidation temperature and time at 500°C and 2.5-10 h, oxygen concentration at 75.6% under O2/N2 gas mixtures. As operation conditions for a pneumatic cylinder, stroking, actuating, and waiting times were 0.5, 3, and 12 s.