Molten Salt Reactor (MSR) is one of Generation-IV nuclear reactors that uses molten salts as a fuel and coolant in liquid forms at high temperatures. The advantages of MSR, such as safety, economic feasibility, and scalability, are attributed from the fact that the molten salt fuel in a liquid state is chemically stable and has excellent thermo-physical properties. MSR combines the fuel and coolant by dissolving the actinides (U, Th, TRU, etc.) in the molten salt coolant, eliminating the possibility of a core meltdown accident due to loss of coolant (LOCA). Even if the molten salt fuel leaks, the radioactive fission products dissolved in the molten salt will solidify with the fuel salt at room temperature, preventing potential leakage to the outside. MSR was first demonstrated at ORNL starting with the Aircraft Reactor Experiment (ARE) in 1954 and was extended to the 7.4 MWth MSRE developed in 1964 and operated for 5 years. Recently, various start-ups, including TerraPower, Terrestrial Energy, Moltex Energy, and Seaborg, have been conducting research and development on various types of MSR, particularly focusing on its inherent safety and simplicity. While in the past, fluoride-based molten salt fuels were used for thermal neutron reactors, recently, a chlorine-based molten salt fuel with a relatively high solubility for actinides and advantageous for the transmutation of spent nuclear fuel and online reprocessing has been developing for fast neutron spectrum MSRs. This paper describes the development status of the process and equipment for producing highpurity UCl3, a fuel material for the chlorine-based molten salt fuel, and the development status of the gas fission product capturing technologies to remove the gaseous fission products generated during MSR operation. In addition, the results of the corrosion property evaluation of structural materials using a natural circulation molten salt loop will also be included.

Molten Salt Reactor (MSR) is one of the generation-IV advanced nuclear reactors in which hightemperature molten salt mixture is used as the primary coolant, or even the fuel itself unlike most nuclear reactors that adopt solid fuels. The MSR has received a great attention because of its excellent thermal efficiency, high power density, and structural simplicity. In particular, since the MSR uses molten salts with boiling points higher than the exit temperature of the reactor core, there is no severe accident such as a core melt-down which leads to a hydrogen explosion. In addition, it is possible to remove the residual heat through a completely passive way and when the fuel salt leaks to the outside, it solidifies at room-temperature without releasing radioactive fission products such as cesium, which make the MSR inherently safe. Both fluoride and chloride mixtures can be used as liquid fuel salts by adding actinide halides for MSRs. However, the MSRs using chloride-based salt fuels can be operated for a long time without adding nuclear fuel or online reprocessing because the actinide solubility in chloride salts is about six times higher than that in fluoride salts. Therefore, the chloride-based MSRs are more effective for the transmutation of long-lived radionuclides such as transuranic elements than the fluoride-based MSRs, which is beneficial to resolve the high radioactive spent nuclear fuel generated from light water reactors (LWRs). This paper examines liquid fuel fabrication using an improved U chlorination process for the chloride-based MSRs and presents the strategy for the management of gaseous fission products generated during the operation of MSR.

The aim of this review is to communicate some essential knowledge of the underlying mechanism of the corrosion of structural containment alloys during molten salt reactor operation in the context of prospective online monitoring in future MSR installations. The formation of metal halide species and the progression of their concentration in the molten salt do reflect containment corrosion, tracing the depletion of alloying metals at the alloy salt interface will assure safe conditions during reactor operation. Even though the progress of alloying metal halides concentrations in the molten salt do strongly understate actual corrosion rates, their prospective 1st order kinetics followed by near-linearly increase is attributed to homogeneous matrix corrosion. The service life of the structural containment alloy is derived from homogeneous matrix corrosion and near-surface void formation but less so from intergranular cracking (IGC) and pitting corrosion. Online monitoring of corrosion species is of particular interest for molten chloride systems since besides the expected formation of chromium chloride species CrCl2 and CrCl3, other metal chloride species such as FeCl2, FeCl3, MoCl2, MnCl2 and NiCl2 will form, depending on the selected structural alloy. The metal chloride concentrations should follow, after an incubation period of about 10,000 hours, a linear projection with a positive slope and a steady increase of < 1 ppm per day. During the incubation period, metal concentration show 1st order kinetics and increasing linearly with time1/2. Ideally, a linear increase reflects homogeneous matrix corrosion, while a sharp increase in the metal chloride concentration could set a warning flag for potential material failure within the projected service life, e.g. as result of intergranular cracking or pitting corrosion. Continuous monitoring of metal chloride concentrations can therefore provide direct information about the mechanism of the ongoing corrosion scenario and offer valuable information for a timely warning of prospective material failure.