The primary heat transport system consists mainly of the in-core fuel channels connected to the steam generators by a system of feeder pipes and headers. The feeders and headers are made of carbon steel. Feeders run vertically upwards from the fuel channels across the face of the reactor and horizontally over the refueling machine to the headers. Structural materials of the primary systems of nuclear power plants (NPPs) are exposed to high temperature and pressure conditions, so that the materials employed in these plants have to take into accounts a useful design life of at least 30 years. The corrosion products, mainly iron oxides, are generated from the carbon steel corrosion which is the main constituent of the feeder pipes and headers of this circuit. Typical film thickness on CANDU-PHWR surface is 75μm or 30mg/cm2. Deposits on PHWR tends to be much thicker than PWR due to use of carbon steel and also for the source of corrosion products available on the carbon steel surface. Degradation of carbon steel for the feeder pipes transferring the primary system coolant by flow-assisted corrosion in high temperature has been reported in CANDU reactors including Point Lapreau, Gentully-2, Darlington and Bruce NPPs. The formation of Fe3O4 film on a carbon steel surface reduces the dissolution rate of steel substantially. The protectiveness of the Fe3O4 film over the carbon steel is affected by the environmental factors and the operational parameters of the feeder pipes, including the velocity, wall shear stress, solution pH, temperature, concentration of dissolved iron, quality of solution, etc. For effective chemical decontamination of these thick oxides containing radionuclides such as Co-60, it is necessary to understand the corrosion behaviors of feeder pipes and the characteristics of oxide formed on it. In this work, we investigated the growth of oxide films that develop on type SA-107 Gr. B carbon steel in high temperature water and steam environment by scanning electron microscopy (SEM) and glow discharge optical emission spectrometry (GD-OES) for the quantification and the solidstate speciation of metal oxide films. This study was especially focused to set the experimental tests conditions how to increase the oxide thickness up to 50 m by changing the oxidation conditions, such as solution chemistry and thermo-hydraulic conditions both temperature and pressure and so on.

Safe management of spent nuclear fuel (SNF) is a key issue to determine sustainability of current light water reactor (LWR) fleet. However, none of the countries are actually conducting permanent disposal of SNFs yet. Instead, most countries are pursuing interim storage of spent nuclear fuels in dry cask storage system (DCSS). These dry casks are usually made of stainlesssteels for resistibility against cracking and corrosion, which can be occurred over a long-term storage period. Nevertheless, some corrosion called Chloride-Induced Stress Corrosion Cracking (CISCC) can arise in certain conditions, exacerbating the lifetime of dry casks. CISCC can occur if the three conditions are satisfied simultaneously: (i) residual tensile stress, (ii) material sensitization, and (iii) chloride-rich environment. A residual tensile stress is developed by the two processes. One is the bending process of stainless-steel plates into a cylindrical shape, and the other is the welding process, which can incur solidification-induced stress. These stresses provide a driving force of pit-to-crack transition. Around the fusion weld areas, chromium is precipitated at the grain boundary as a carbide form while it depletes chromium around it, leading to material susceptible to pitting corrosion. It is called sensitization. Finally, coastal regions, where nuclear power plants usually operate, tend to have a higher relative humidity and more chloride concentration compared to inland areas. This high humidity and chloride ion concentration initiate pitting corrosion on the surface of stainless-steels. To prevent initiation of CISCC, at least one of the three conditions should be removed. For this, several surface engineering techniques are under investigation. One of the most promising approaches is surface peening method, which is the process that impacts the surface of materials with media (e.g., small pins, balls, laser pulse). By this impact, plastic deformation on the surface occurs with compressive stress that counteracts with pre-existing residual tensile stress, so this approach can prevent pit-to-crack transition of stainless-steels. Also, cold spray deposition can prevent CISCC. Cold spray deposition is a method of spraying fine metal powder to a substrate by accelerating them to supersonic velocity with propellant gas. As a result, a thin coating composed of the feedstock powders can protect the substrate from outer corrosive environments. In addition, the impact of the feedstock powder on the substrate during the process provides compressive stress, similar to the peening method.

In Korea, borated stainless steel (BSS) is used as spent fuel pool (SFP) storage rack to maintain nuclear criticality of spent fuels. As number of nuclear power plants and corresponding number of spent fuels increased, density in SFP storage rack also increased. In this regard, maintain subcriticality of spent nuclear fuels was raised as an issue and BSS was selected as structural material and neutron absorber for high density storage rack. Because it is difficult to replace storage rack, corrosion resistance and neutron absorbency are required for long period. BSS is based on stainless steel 304 and it is specified in the ASTM A887-89 standard depending on the boron concentration from 304B (0.20-0.29% B) to 304B7 (1.75-2.25% B). Due to low solubility of boron in austenitic stainless steel, metallic borides such as (Fe, Cr)2B are formed as secondary phase metallic borides could make Cr depletion near it which could decrease the corrosion resistance of material. In this paper, long-term corrosion behavior of BSS and its oxide microstructures are investigated through accelerated corrosion experiment in simulated SFP condition. Because corrosion rate of austenitic stainless steel is known to be dependent on the Arrhenius equation, a function of temperature, corrosion experiment is conducted by increasing the experimental temperature. Detail microstructural analysis was conducted with scanning electron microscope, transmission electron microscope and energy dispersive spectrometer. After oxidation, hematite structure oxide film is formed and pitting corrosions occur on the surface of specimens. Most of pitting corrosions are found at the substrate surface because corrosion resistance of substrate, which has low Cr content, is relatively low. Also, oxidation reaction of B in the secondary phase has the lowest Gibbs free energy compared to other elements. Furthermore, oxidation of Cr has low Gibbs free energy which means that oxidation of B and Cr could be faster than other elements. Thus, the long-term corrosion might affect to boron content and the neutron absorption ability of the material.

In this study, corrosion fatigue crack propagation was investigated in pH buffer environment using the giga strength steel and its heat-affected zone, and the results were compared with theoretical model prediction. Also, the pure corrosion effect on fatigue crack propagation in a corrosive environment was compared with the modified Forman equation. As results, the average value of corrosion rate obtained as the ratio of the net corrosion-induced crack length to the total crack length under cyclic loading in the base metal and heat-affected zone under experimental loading conditions. These results exhibit a new theoretical method for corrosion fatigue crack propagation that predicts a purely corrosion effect on the behavior to be determined.

In this study, using the plasma spray method, tensile and compression fatigue tests are performed in saline solution to examine the effect of Ti undercoat on corrosion fatigue behavior of alumina-coated specimens. The alumina-coated material using Ti in the undercoat shows better corrosion fatigue strength than the base material in the entire stress amplitude range. Fatigue cracking of UT specimens occurs in the recess formed by grit-blasting treatment and progresses toward the base metal. Subsequently, the undercoat is destroyed at a stage where the deformation of the undercoat cannot follow the crack opening displacement. The residual stress of the UT specimen has a tensile residual stress up to about 100 μm below the surface of the base material; however, when the depth exceeds 100 μm, the residual stress becomes a compressive residual stress. In addition, the inside of the spray coating film is compressive residual stress, which contributes to improving the fatigue strength characteristics. A hardened layer due to grit-blasting treatment is formed near the surface of the UT specimen, contributing to the improvement of the fatigue strength characteristics. Since the natural potential of Ti spray coating film is slightly higher than that of the base material, it exhibits excellent corrosion resistance; however, when physiological saline intrudes, a galvanic battery is formed and the base material corrodes preferentially.

Martensitic stainless steel is commonly used in the medical implant instrument. The alloy has drawbacks in terms of strength and wear properties when applied to instruments with sharp parts. 440C STS alloy, with improved durability, is an alternative to replace 420 J2 STS. In the present study, the carbide precipitation, and mechanical and corrosion properties of STS 440C alloy are studied as a function of different heat treatments. The STS 440C alloy is first austenitized at different temperatures; this is immediately followed by oil quenching and sub-zero treatment. After sub-zero treatment, the alloy is tempered at low temperatures. The microstructures of the heat treated STS 440C alloy consist of martensite and retained austenite and carbides. Using EDX and SADP with a TEM, the precipitated carbides are identified as a Cr23C6 carbide with a size of 1 to 2 μm. The hardness of STS 440C alloy is improved by austenitization at 1,100 oC with sub-zero treatment and tempering at 200 oC. The values of Ecorr and Icorr for STS 440C increase with austenitization temperature. Results can be explained by the dissolution of Cr-carbide and the increase in the retained austenite. Sub-zero treatment followed by tempering shows a little difference in the properties of potentiodynamic polarizations.

Here, the stability of stainless steel 316 (SS-316) was investigated to identify its applicability in the oxide reduction process, as a component in related equipment, to produce a complicated gas mixture composed of O2 and Cl2 under an argon (Ar) atmosphere. The effects of the mixed gas composition were investigated at flow rates of 30 mL/min O2, 20 mL/min O2 + 10 mL/min Cl2, 10 mL/min O2 + 20 mL/ min Cl2, and 30 mL/min Cl2, each at 600℃, during a constant argon flow rate of 170 mL/min. It was found that the corrosion of SS-316 by the chlorine gas was suppressed by the presence of oxygen, while the reaction proceeded linearly with the reaction time regardless of gas composition. Surface observation results revealed an uneven surface with circular pits in the samples that were fed mixed gases. Thermodynamic calculations proposed the combination of Fe and Ni chlorination reactions as an explanation for this pit formation phenomenon. An exponential increase in the corrosion rate was observed with an increase in the reaction temperature in a range of 300 ~ 600℃ under a flow of 30 mL/min Cl2 + 170 mL/min Ar.

파이프 골조 온실의 내구성 증대를 위하여 4가지의 부식방지 처리를 한 파이프를 실험온실 내부에 설치하여 20년경과 후 표면부식 상태와 강도 변화 실험을 실시하였다. 대기 중에 노출된 지상부위에서 무처리 파이프는 강도가 1.3%정도 줄었지만 다른 처리와의 차이는 거의 없는 것으로 나타났다. 지하 매설부위에서 중방식 처리한 파이프의 강도는 0.6%정도 줄어 거의 변화가 없었으나 무처리는 15.7% 감소하는 것으로 나타났다. 그리고 방청 페인트나 아스팔트 도포는 4.2~4.4% 정도 감소하는 것으로 나타났다. 지상부위는 모든 시료에서 심한 부식상태를 보이지 않았다. 중방식 처리는 변화가 없었고, 방청페인트 처리도 녹은 발견되지 않고 약간의 변색만 있었다. 아스팔트 도포는 검게 변색되고 약간의 녹이 발견되었으며, 무처리는 표면의 20~30%정도가 녹슨 것으로 나타났다. 지하 매설부위 무처리 파이프의 경우에는 전체가 완전히 녹슬어 있었고, 아스팔트 도포한 파이프도 표면의 80~90%가 녹슬어 있었다. 방청페인트 처리는 20~30%정도 녹슬어 있었고, 중방식 처리는 거의 변화가 없었다. 중방식 처리는 지하 매설부위에서도 확실한 부식 방지 효과를 보이는 것을 확인할 수 있었고, 방청페인트 처리도 어느 정도 부식 방지 효과를 나타내고 있으므로 현장에 적용할 수 있을 것으로 판단된다.

Hot-press forming(HPF) steel can be applied successfully to auto parts because of its superior mechanical properties. However, its resistances to aqueous corrosion and the subsequent hydrogen embrittlement(HE) decrease significantly when the steel is exposed to corrosive environments. Considering that the resistances are greatly dependent on the properties of coating materials formed on the steel surface, the characteristics of the corrosion and hydrogen diffusion behaviors regarding the types of coating material should be clearly understood. Electrochemical polarization and impedance measurements reveal a higher corrosion potential and polarization resistance and a lower corrosion current of the Al-coating compared with Zn-coating. Furthermore, it was expected that the diffusion kinetics of the hydrogen atoms would be much slower in the Al-coating, and this would be due mainly to the much lower diffusion coefficient of hydrogen in the Al-coating with a face-centered cubic structure. The superior surface inhibiting effect of the Al-coating, however, is degraded by the formation of local cracks in the coated layer under severe stress conditions, and therefore further study will be necessary to gain a clearer understanding of the effect of cracks formed on the coated layer on the subsequent corrosion and hydrogen diffusion behaviors.

In this study, the long-term performance of FRP Hybrid Bar made by hybridizing FRP (Fiber Reinforced Polymer) with ordinary reinforcing steel bars was experimentally examined as a part of the development of alternative materials for RC (reinforced concrete) structures especially located in marine or harbor areas. In order to evaluate the field exposure of the FRP Hybrid Bar, the specimen was prepared and the corrosion behavior was evaluated by letting the specimen exposed to the field conditions in the west coast of South Korea. The purpose of this study is to provide important data as a material countermeasure to reduce corrosion of reinforcing steel in future marine port concrete structures based on the results obtained through this study.

Evaluation of the durability and stability of materials used in power plants is of great importance because parts or components for turbines, heat exchangers and compressors are often exposed to extreme environments such as high temperature and pressure. In this work, high-temperature corrosion behavior of 316 L stainless steel in a carbon dioxide environment was studied to examine the applicability of a material for a supercritical carbon dioxide Brayton cycle as the next generation power plant system. The specimens were exposed in a high-purity carbon dioxide environment at temperatures ranging from 500 to 800 oC during 1000 hours. The features of the corroded products were examined by optical microscope and scanning electron microscope, and the chemical compound was determined by x-ray photoelectron spectroscopy. The results show that while the 316 L stainless steel had good corrosion resistance in the range of 500-700 oC in the carbon dioxide environment, the corrosion resistance at 800 oC was very poor due to chipping the corroded products off, which resulted in a considerable loss in weight.

This study investigated the surface pit corrosion of SS420J2 stainless steel accompanied by intergranular crack. To reveal the causes of surface pits and cracks, OM, SEM, and TEM analyses of the microstructures of the utilized SS420J2 were performed, as was simulated heat treatment. The intergranular cracks were found to have been induced by a grain boundary carbide of (Cr,Fe)23C6, which was identified by SEM/EDS and TEM diffraction analyses. The mechanism of grain boundary sensitization occurred at the position of the carbide, followed by its occurrence at the Cr depleted zone. The grain boundary carbide of (Cr,Fe)23C6 type precipitated during air cooling condition after a 1038 °C solid solution treatment. The carbide precipitate formation also accelerated at the band structure formed by cold working. Therefore, using manufacturing processes of cooling and cold working, it is difficult to protect SS420J2 stainless steel against surface pit corrosion. Several counter plans to fight pit corrosion by sensitization were suggested, involving alloying and manufacturing processes.

In this study, we investigated the effect of the residual carbides and tempered carbides precipitated by tempering treatment after quenching on the pitting corrosion of mod. 440A martensitic stainless steel. In quenched specimens and tempered specimens after quenching of mod. 440A martensitic stainless steel, the volume fraction of the residual carbides and total carbides decreased with the increase of the austenitizing temperature. Pitting resistance increased with the increase of austenitizing temperature. With the increase of the volume fraction of the residual and total carbides, the pitting resistance of mod. 440A martensitic stainless steel was decreased. The pitting resistance of mod. 0.5C-17Cr-0.5Ni 440A martensitic stainless steel had stronger affected by residual carbides than precipitated carbides produced by tempering.

In this work, on-site corrosion behavior of heat resistant tubes of T91, used as components of a superheater in a power plant for up to 25,762 h, has been investigated using scanning electron microscopy(SEM), energy dispersive X-ray spectroscopy (EDS), and electron backscattered diffraction(EBSD), with the objectives of studying the composition, phase distribution, and evolution during service. A multi-layer structure of oxide scale was found on both the steamside and the fireside of the tube surface; the phase distribution was in the order of hematite/magnetite/spinel from the outer to the inner matrix on the steamside, and in the order of slag/magnetite/spinel from the outer to the inner matrix on the fireside. The magnetite layer was found to be rich in pores and cracks. The absence of a hematite layer on the fireside was considered to be due to the low oxygen partial pressure in the corrosion environment. The thicknesses of the hematite and of the slag-deposit layer were found to exhibit no significant change with the increase of the service time.

As wrought stainless steel, sintered stainless steel (STS) has excellent high-temperature anti-corrosion even at high temperature of 800ºC and exhibit corrosion resistance in air. The oxidation behavior and oxidation mechanism of the sintered 316L stainless was reported at the high temperature in our previous study. In this study, the effects of additives on high-temperature corrosion resistances were investigated above 800ºC at the various oxides (SiO2, Al2O3, MgO and Y2O3) added STS respectively as an oxidation inhibitor. The morphology of the oxide layers were observed by SEM and the oxides phase and composition were confirmed by XRD and EDX. As a result, the weight of STS 316L sintered body increased sharply at 1000oC and the relative density of specimen decreased as metallic oxide addition increased. Compared with STS 316L sintered parts, weight change ratio corresponding to different oxidation time at 900oC and 1000oC, decreased gradually with the addition of metallic oxide. The best corrosion resistance properties of STS could be improved in case of using Y2O3. The oxidation rate was diminished dramatically by suppression the peeling on oxide layers at Y2O3 added sintered stainless steel.

In this study, nitrogen ions were implanted into STS 316L austenitic stainless steel by plasma immersion ion implantation (PIII) to improve the corrosion resistance. The implantation of nitrogen ions was performed with bias voltages of −5, −10, −15, and −20 kV. The implantation time was 240 min and the implantation temperature was kept at room temperature. With nitrogen implantation, the corrosion resistance of 316 L improved in comparison with that of the bare steel. The effects of nitrogen ion implantation on the electrochemical corrosion behavior of the specimen were investigated by the potentiodynamic polarization test, which was conducted in a 0.5 M H2SO4 solution at 70 oC. The phase evolution and texture caused by the nitrogen ion implantation were analyzed by an X-ray diffractometer. It was demonstrated that the samples implanted at lower bias voltages, i.e., 5 kV and 10 kV, showed an expanded austenite phase, γN, and strong (111) texture morphology. Those samples exhibited a better corrosion resistance.

일반적인 3-전극 시스템의 순환전압전류법을 사용하여 유기부식억제제인 트리에탄올아민 (TEA)을 첨가하여 SCM440 강에 대한 전류-전압 곡선을 측정하였다. 그 결과 SCM440 강의 C-V특성 은 순환전압전류법으로부터 산화전류에 기인한 비가역 공정으로 나타났다. 확산계수는 부식억제제 TEA 의 농도를 2.5 x 10-4 M에서 5,0 x 10-4 M로 2배로 증가시킴에 따라 확산계수는 각각 2.561 x 10-6 cm2s-1에서 1.707 x 10-6 cm2s-1로 1.5배로 감소하므로 부식억제효과가 좋음을 알 수 있었다. 그리고 전 해질 농도변화에 따르는 효과는 전해질 농도를 0.5 N에서 1.0 N로 증가시키면, 확산계수는 각각 5.12 x 10-6 cm2s-1에서 2.56 x 10-6 cm2s-1로 2배로 감소하므로 1.0 N의 전해질의 사용이 적합하였다.

In this study, we investigated the precipitation behavior of the R-phase precipitated at the initial stage of aging and its effect on the pitting corrosion of 25%Cr-7%Ni-4%Mo super duplex stainless steel. The R-phase in super duplex stainless steel was mainly precipitated at the interface of ferrite/austenite phases and inside of the ferrite phase during the initial stage of aging, and it was transformed into the σ-phase with an increase in aging time. The ferrite phase was decomposed into a new austenite phase and σ-phase. The R phase was an intermetallic compound, which represented a lower Ni and higher Mo than the matrix, and also had a higher Mo and Cr concentration than the σ phase. With an increasing aging time, the pitting potential Ep was increased slowly by the precipitation of the R-phase, and it was then steeply decreased by the precipitation of the σ-phase. The R-phase was decreased the pitting potential, but its effect was smaller than effect of σ-phase.