최근 여러 연구에서 Hg2+에 선택적으로 반응해 형광을 강화시키거나 소광시키는 thiophene을 기반으로한 probe가 많이 개발되어 왔지만, 이에 따른 분광학적 현상에 대한 정확한 분자적 수준의 이론적 해석이 이루어지지 않 았다. 이에 따라 우리는 Hg2+와 thiophene간 상호작용을 면밀히 분석하기 위해 Hg2+와 thiophene간 거리에 따른 에너 지 포텐셜을 구하였다. Hg2+ 이온에 대한 모든 전자(all electron, AE) basis set인 x2c-TZVPPall와 effective core potential (ECP) 기반인 LANL2DZ는 모두 상대성 효과가 고려된 바닥 상태에서 Hg2+와 thiophene이 결합력이 없이 해 리가 되는 에너지 포텐셜을 보여주었지만, 용매인 물이 고려된 시스템에서는 Hg2+와 thiophene이 결합력을 가지는 것 을 보였으며 이것은 실험적인 결과를 잘 재현하는 것이었다. 따라서 Hg2+ 이온을 포함하는 착화합물 시스템에서 올바 른 에너지 상태를 구하기 위해서는 상대성효과와 더불어 solvent 영향도 잘 고려돼야 함을 알 수 있다.

본 연구에서는 Monopile 방식 풍력발전기 강구조물의 부식을 방지하기 위하여 S355 steel의 표면 거칠기에 따른 용사 코팅 상태에 관한 연구를 수행했다. 일차적으로는 시편별 서로 다른 표면거칠기를 부여하기 위해 밀링머신에 페이스 커터를 결합하여 시편별로 다른 조건의 Ra값 기준 표면거칠기를 부여했다. 실험 조건으로는 시편 가공 시 4가지의 회전속도(60, 400, 1200, 2000 rpm), feed rate 150(mm/min) 조건을 선정했다. 2차로는 와이어 용융 방식의 아크 용사 코팅을 실시했다. 코팅 조건으로는 분사 거리 200mm, 전압 24V, 전류 120A, 분사 압력 5bar, 와이어 삽입 속도 30g/mm, 와이어 직경 2mm이다. 용사 코팅 후 FE-SEM으로 표면을 관찰한 결과 모든 시편의 S355 면과 코팅층(아연-알루미늄) 사이에 유격이 발생하지 않고 성공적으로 안착이 되었음을 확인할 수 있었다.

In this study, in order to confirm the machining characteristics of AISI 1020 CD-Bar, cutting was performed after strength measurement, and surface roughness analysis was performed according to cutting conditions. Tensile strength was reduced by about 27.7% compared to AISI 1045 material, and Rockwell hardness HRC was reduced by 46.7%. The surface roughness measurement after cutting was divided into roughing, semi-finishing and finishing turning. In particular, in finishing machining, the best surface roughness was confirmed when the cutting speed was 150m/min and the depth of cut was 0.6mm based on the feed rate of 0.05mm/rev.

In this study, nitric acid oxidation with varied treatment temperature and time was conducted on the surfaces of polyacrylonitrile- based ultrahigh modulus carbon fibers. Scanning electron microscopy, X-ray photoelectron spectroscopy, Raman spectroscopy and surface tension/dynamic contact angle instruments were used to investigate changes in surface topography and chemical functionality before and after surface treatment. Results showed that the nitric acid oxidation of ultrahigh modulus carbon fibers resulted in decreases in the values of the crystallite thickness Lc and graphitization degree. Meanwhile, increased treating temperature and time made the decreases more obviously. The surfaces of ultrahigh modulus carbon fibers became much more activity and functionality after surface oxidation, e.g., the total surface energy of oxidized samples at 80 °C for 1 h increased by 27.7% compared with untreated fibers. Effects of surface nitric acid oxidation on the mechanical properties of ultrahigh modulus carbon fibers and its reinforced epoxy composites were also researched. Significant decreases happened to the tensile modulus of fibers due to decreased Lc value after the nitric acid oxidation. However, surface treatment had little effect on the tensile strength even as the treating temperature and processing time increased. The highest interfacial shear strength of ultrahigh modulus carbon fibers/epoxy composites increased by 25.7% after the nitric acid oxidation. In the final, surface oxidative mechanism of ultrahigh modulus carbon fibers in the nitric acid oxidation was studied. Different trends of the tensile strength and tensile modulus of fibers in the nitric acid oxidation resulted from the typical skin–core structure.

This study analyzes the internal temperature characteristics of heater module using a numerical method when the constant heat flux and heat flux time are applied to the surface heating element. The horizontal and vertical dimensions of heater module are 100mm, and the height is 5mm. The heat flux is 10,000W/m2, 15,000W/m2, and 20,000W/m2, and heat flux time is 5 seconds, 10 seconds, 15 seconds, 20 seconds, 30 seconds and 50 seconds, respectively. When the heat flux time was 50 seconds, the temperature of the surface heating element rose to 120.5°C, while the skin epidermis temperature rose 1.7°C. As a result, the surface temperature of the surface heating element increased greatly in the horizontal direction, while it increased low in the depth direction. This is because the heat conduction of the surface heating element is transmitted in the X-Y plane direction, and the thermal conductivity of the pet(polyethylene terephthalate) film and insulation sheet under the surface heating element is very low. when the heat flux at the surface heating element is 20,000W/m2, the skin's epidermal temperature rises up to 0.82℃ compared to 10,000W/m2 and 15,000W/m2.

This paper reports slug bubble dynamics on modified surface with two-dimensional graphene film in downward-facing nucleate boiling. Behaviors of slug bubbles were observed with high speed camera, and post-processing was followed to measure departing speed, frequency, and diameter of slug bubbles, which were important to analyze boiling performance change. The graphene-modified surface showed enhanced boiling heat transfer coefficient (BHTC) and critical heat flux (CHF). The effect of surface modification on slug bubble dynamics was quantitatively analyzed; bigger slugs departed from the modified surface with faster speed but same frequency, compared with the bare. It seems that the BHTC enhancement is caused by increase of bubble diameter, resulting in increase of its departing speed. The higher speed of departing bubble could extend the hydrodynamic limit of vapor removal from downward-facing surface, so that CHF performance could be enhanced.

목적 : 조절력이 충분한 20대 성인이 단일 및 다중 전면 비구면 기능성 콘택트렌즈 착용 후 시각의 질 및 조절 기능의 차이를 비교하고자 하였다. 방법 : 13명(21.38±0.65세)의 대상자들을 두 종류의 콘택트렌즈를 각각 착용 후 시력, 대비감도, 스트레이라 이트, 총 고위수차, 구면수차, 코마수차, 조절반응, 양안조절용이성, 조절근점을 평가하였다. 결과 : 시력, 대비감도, 스트레이라이트, 총 고위수차, 구면수차, 양안조절용이성은 유의한 차이가 없었고 코마수차 는 4, 5 mm 동공크기에서 다중 전면 비구면 기능성 콘택트렌즈를 착용 시 경미하게 증가하였다(p=0.037). 조절반 응(p=0.006)과 조절근점(p=0.005)은 다중 전면 비구면 기능성 콘택트렌즈를 착용 시 유의하게 더 감소하고 짧아졌다. 결론 : 다중 전면 비구면 기능성 콘택트렌즈 착용 시 단일 전면 비구면 콘택트렌즈 착용 시와 비교하여 시각의 질 은 차이가 없었지만 조절부담을 감소시켜주는 효과가 있으므로 젊은 성인의 기능성 렌즈로서 유용할 것으로 사료된다.

필로티는 현대건축에서 주차공간의 활용, 보행자의 통로 등 여러 가지 이점을 가지고 있기 때문에 아파트와 오피스텔과 같은 고층건축물에 많이 사용되고 있다. 이러한 고층건축물의 필로티 형태 특성상 강풍이 불 때 바람이 집중되기 때문에 필로티 천장과 벽 면에 위치하고 있는 외장재 및 주골조가 파손되기 쉽다. 그리고 이러한 외장재 및 주골조의 탈락으로 인해 2차 피해가 발생할 우려가 있다. 하지만 건축구조기준(KBC-2016)에서는 고층건축물에 대한 천장 및 벽면의 풍압계수만을 제시할 뿐 필로티에 대한 기준이 명시 되어 있지 않다. 본 논문은 고층건축물에서 사용되는 필로티의 종류로서 관통형, 개방형 필로티를 선정하였고, 필로티의 폭과 깊이를 변수로 하여 풍동실험을 진행하였다. 그리고 변수에 따른 풍압계수의 특성을 파악하였고 비교 및 분석하였고 본 논문의 실험결과를 통 하여 필로티 설계 시 활용할 수 있는 주골조 및 외장재 설계용 풍압계수를 제시하였다.

Generally, ceramic tiles for building construction are manufactured by dry forming process using granular powders prepared by spray drying process after mixing and grinding of mineral raw materials. In recent years, as the demand for large ceramic tiles with natural texture has increased, the development of granule powders with high packing ratio and excellent flowability has become more important. In this study, ceramic tile granule powders are coated with hydrophobically treated silica nanoparticles. The effects of hydrophobic silica coating on the flowability of granule powders and the strength of the green body are investigated in detail. Silica nanoparticles are hydrophobically treated with GPTMS(3-glycidoxypropyl trimethoxy silane), which is an epoxy-based silane coupling agent. As the coating concentration increases, the angle of repose and the compressibility decrease. The tap density and flowability index increase after silica coating treatment. These results indicate that hydrophobic treatment can improve the flowability of the granular powder, and prevent cracking of green body at high pressure molding.

Background: Functional ankle instability (FAI) indicating a decrease in muscle strength, proprioception, neuromuscular control, balance and postural control function. Objective: To investigate the effect of jumping exercise on the supporting surface on the ankle muscle thickness, proprioceptive sensation, and balance in adults with FAI. Design: Randomized Controlled Trial. Methods: Twenty young people with FAI were randomly assigned to the unstable supporting surface jump group (N=10) and the stable supporting surface jump group (N=10). The intervention was conducted three times a week for eight weeks, and for 30 minutes per session. Trampoline was used as an unstable support surface and the stable support surface was carried out on a regular floor. The thickness of the tibialis anterior muscle and medial gastrocnemius muscle was measured by ultrasonography, and the proprioception of dorsiflexion and plantarflexion was measured using an electrogoniometer. The dynamic balance was also measured with a balance meter. Results: The the muscle thickness of the medial gastrocnemius muscle was significantly higher in the stable supporting surface jump group than in the unstable supporting surface jump group (p<.05). Furthermore, the plantar flexion proprioception and dynamic balance were significantly improved in the unstable supporting surface jump group than in the stable supporting surface jump group in the intergroup comparison (p<.05). Conclusions: The conclusion has been reached in this study that the jumping exercise on the unstable supporting surface could be a more effective in improving FAI than the regular surface.

철도 분기기는 결선부와 곡선부의 존재로 인하여 선로에서 가장 손상이 많이 발생하는 구간이며, 구조적 건전성을 유지관리하기 위하여 매년 상당한 비용이 투입되고 있다. 레일연마는 이러한 분기기의 레일 손상을 감소시켜 유지관리 비용을 저감할 수 있는 방안 중 하나로 알려져 있으나, 현재까지 국내에서는 분기기 레일 연마를 통한 유지관리 비용 절감 효과를 정 량적으로 연구한 사례가 거의 없는 상황이다. 이 논문에서는 분기기 레일 연마를 통한 유지관리 비용 절감 효과를 다물체 동적 해석프로그램인 VI-Rail을 이용하여 검토하였다. 레일 연마 효과는 레일 표면의 조도를 이용하여 모사하였으며, VI-Rail 프로 그램의 Flextrack 모델을 이용하여 차량-궤도 상호작용해석을 수행하였다. 수치해석은 60kg #8 분기기와 EMU 차량 모델을 이용 하여 수행하였으며, 레일 표면 조도는 실제 궤도에서 측정된 값을 기반으로 작성한 PSD 함수를 이용하여 모사하였다. 해석 결 과 레일 연마는 분기기 레일의 피로 수명을 6.5% 가량 증가시키는 것으로 나타났다.

The microstructure, hardness, and wear behaviors of a High Velocity Oxygen Fuel(HVOF) sprayed WC-CoFe coating are comparatively investigated before and after laser heat treatments of the coating surface. During the spraying, the binder metal is melted and a small portion of WC is decomposed to W2C. A porous coating is formed by evolution of carbon oxide gases formed by the reaction of the free carbon and the sprayed oxygen gas. The laser heat treatment eliminates the porosity and provides a more densified microstructure. After laser heat treatment, the porosity in the coating layer decreases from 1.7% to 1.2 and the coating thickness decreases from 150 μm to 100 μm. The surface hardness increases from 1440 Hv to 1117 Hv. In the wear test, the friction coefficient of coating decreases from 0.45 to 0.32 and the wear resistance is improved by the laser heat treatment. The improvement is likely due to the formation of oxide tribofilms.

The objective of this study was to determine the effect of goat grazing on the surface water quality of the alpine grasslands. Seven sites were selected across the goat farm for water sample collection and analysis. Samples were analyzed for BOD (Biological oxygen demand), total nitrogen, total phosphorous, electrical conductivity and water turbidity. All the above-mentioned parameters remained below the standard limit of Korean government at the end site. Puddles showed higher values, but below standard, as stagnant water has lower physico-chemical properties as of flowing water. The present study clearly showed that goat grazing doesn’t affect water quality in grasslands if grazing is according to carrying capacity of grassland and fertilizer application is judicious.