The decommissioning of nuclear power plant (NPP) consists of various activities, such system decontamination, take out of activated components, segmentation of the activated components, site remediation, etc. During various activities, the generation of radioactive wastes and radiation exposure to workers is expected. The systematic waste management during the activities is important to implement the decommissioning. The inefficient waste management usually bring significant delay in decommissioning process and results in increase of decommissioning cost. The radiation exposure management is also an important issue. It is generally accepted that the hot spot, generated from operation and decommissioning of NPP, is observed in many places within containment building. Although the health physicists measure the radiation in various points, the unintended hot spots are sometimes generated and observed. The effective radiation exposure management also requires the control of personnel and space during various activities. In this study, the radiation exposure and waste management experiences of Zion NPP is reviewed. The primary nuclides and radiation exposure during various activities are systematically studied to achieve the main objectives of this paper.