In this study, we introduce a novel TiN/Ag embedded TiO2/FTO resistive random-access memory (RRAM) device. This distinctive device was fabricated using an environmentally sustainable, solution-based thin film manufacturing process. Utilizing the peroxo titanium complex (PTC) method, we successfully incorporated Ag precursors into the device architecture, markedly enhancing its performance. This innovative approach effectively mitigates the random filament formation typically observed in RRAM devices, and leverages the seed effect to guide filament growth. As a result, the device demonstrates switching behavior at substantially reduced voltage and current levels, heralding a new era of low-power RRAM operation. The changes occurring within the insulator depending on Ag contents were confirmed by X-ray photoelectron spectroscopy (XPS) analysis. Additionally, we confirmed the correlation between Ag and oxygen vacancies (Vo). The current-voltage (I-V ) curves obtained suggest that as the Ag content increases there is a change in the operating mechanism, from the space charge limited conduction (SCLC) model to ionic conduction mechanism. We propose a new filament model based on changes in filament configuration and the change in conduction mechanisms. Further, we propose a novel filament model that encapsulates this shift in conduction behavior. This model illustrates how introducing Ag alters the filament configuration within the device, leading to a more efficient and controlled resistive switching process.

Yeosu National Industrial Complex is one of Korea’s representative petrochemical industrial complexes where crude oil refining and petrochemical companies are concentrated. According to the results of the 2021 chemical emissions survey, during the process of manufacturing, storage, and transportation at the Yeosu National Industrial Complex, various hazardous chemicals, including hazardous air pollutants, volatile organic compounds and odorous substances are being emitted into the air, affecting the surrounding environment and the health of residents. The Ministry of Environment is applying strengthened standards by designating the Yeosu National Industrial Complex as an air conservation special measure area and establishing odor management areas to manage the air environment. Nevertheless, odor complaints continue to be registered and related complaints increase when turnaround work is carried out. Since air emissions are not counted during periods of turnaround as normal operations are temporarily suspended, it was difficult to establish policies to reduce odor complaints because the source of emissions and emission quantities cannot be ascertained with certainty. In this study, the extensive Yeosu National Industrial Complex was subdivided into 4 areas using a mobile vehicle equipped with PTR-ToF-MS capable of real-time analysis without sample pretreatment being carried out. Measurements were repeated during the day, night, and dawn while moving around the internal boundary of the plant and the boundary of each region where turnaround activities were being carried out. As a result, the recorded measurement for acrylonitrile was the highest at 6340.0 ppb and propyne and propene were measured the most frequently at 128 times each. Based on these results, it will be possible to help reduce emissions through process improvement by efficiently operating air measurement networks and odor surveys that conduct regular measurements throughout the year and providing actual measurement data to the plant. Also, it will help reduce odor complaints and establish systematic air management policies.

The complexation of silicon with carbon materials is considered an effective method for using silicon as an anode material for lithium-ion batteries. In the present study, carbon frameworks with a 3D porous structure were fabricated using metal–organic frameworks (MOFs), which have been drawing significant attention as a promising material in a wide range of applications. Subsequently, the fabricated carbon frameworks were subjected to CVD to obtain silicon-carbon complexes. These siliconcarbon complexes with a 3D porous structure exhibited excellent rate capability because they provided sufficient paths for Li-ion diffusion while facilitating contact with the electrolyte. In addition, unoccupied space within the silicon complex, combined with the stable structure of the carbon framework, allowed the volume expansion of silicon and the resultant stress to be more effectively accommodated, thereby reducing electrode expansion. The major findings of the present study demonstrate the applicability of MOF-based carbon frameworks as a material for silicon complex anodes.

The purpose of this study was to propose an operational concept for a ship in a fleet equipped with an interceptor missile system, a naval surface to air defense system, and to develop a simulation program that reflects it. The results of the defense activities of other ships in the fleet can be reflected by receiving information about the status of the enemy missiles. The allocation of defensive assets is based on the survival probability of the ship, not on the destruction of enemy attacks, which can be obtained as the product of the expected survival probability for each enemy missile. In addition, the concept of predicted survivability was introduced to assess the loss of future defense opportunities that would result from assigning a new command. A simulation program was also developed as a tool for realizing the proposed concept of operations, which generated cases.

본 연구에서는 인디안구스베리(암라), 찔레나무, 쏘팔메토열매를 5:1:1 비율로 Complex하고 추 출하여 0%, 0.5%, 2.5%, 12.5%, 100%의 NF Complex를 제조하였다. 제조한 NF Complex로 탈색한 시 료 모발에 도포 후 손상된 모발과 비교 · 분석하였다. 개선 효과를 확인하기 위해 인장강도, 광택, 흡광도, 명도를 측정하였다. 측정 결과 인장강도는 증가하였다. 광택은 함량이 100%는 감소하고 나머지 함량은 증 가하였다. 흡광도는 손상모와 대조군과의 차이가 있어 개선 효과가 있는 것으로 보인다. 명도는 변화는 있 으나 미미하였다. NF Complex의 평균값은 유의미한 차이가 있음을 확인하였으며 추후 다양한 추출방법 및 혼합 비율에 따른 연구가 필요하다고 판단된다.

우리나라는 초고령화 사회진입에 전세계적으로 보기드문 급속한 추세에 있다. 또한 코로나19로 인해 대 면적인 사회서비스 제한이 장기화된 상황에서 우리나라 서울보다 1.4배 넓은 소농·도시형인 포천시에 거주 하는 재가노인의 가장 우선시되는 욕구는 먼저 육체적으로 면역력 강화를 위한 영양섭취이고 다음으로는 사회관계를 통한 정신적인 스트레스 해소로 나타났다. 이에 포천시에 위치한 포천노인복지센터는 2004년부터 ‘재가노인지원서비스사업’을 수행하면서 집안에 서 적용 가능한 현관문 개폐와 노인 움직임 감지 등 IOT(Internet Of Things)를 실행하였다. 본 연구에서는 포천시에 거주하는 재가노인을 대상으로 경기도 특화사업인 ‘재가노인 건강기능강화를 위한 맞춤형영양지원사업’을 사회복지사 한명이 식재료와 조리방법을 직접 전달, 설명하는 ‘대면그룹 7명’ 과 수행했다. 그리고 자원봉사자와 재가노인이 일대일 재택대면매칭에 추가하여 ICT를 기반으로 원격화상 을 통해 조리사와 실시간 동시접속 하는 ‘비대면그룹 10명’으로 구분하였다. 8개월 동안 총17명의 대상자에게 음식요리와 섭취를 통해 ‘노인의 영양상태 간이조사’, ‘영양이 노인의 정서· 심리에 미치는 상관관계’ 설문조사와 인바디/혈압측정 등으로 정량적인 결과를 도출함으로써 재가노 인의 건강이 강화됨을 알 수 있었다.

본 연구는 전원주택단지를 대상으로 한 경관영향평가에서 진행하고 있는 각 단계별 계획항목과 내용 등에 대한 분석을 바탕으로 체계적인 경관영향평가 수립을 위한 기초자료를 제시하는데 주안점을 두 었다. 각 평가항목 별 중요도는 전문가 설문을 바탕으로 수행하였으며, 구체적인 분석방법으로는 기술 통계분석, 요인분석, MCB분석 등의 통계분석방법이 사용되었다. 분석결과 평가항목의 중요도 평균은 5.73(7)으로 높게 나타났으나 ‘이용자 안전을 고려한 가로시설물 시설계획’의 중요도가 6.38(7)로 가장 높게 나타난 것에 비해 문헌분석 출현빈도는 8%로 나타나 그 중요도에 비해 기존 경관영향평가에 활용 된 평가항목은 미흡했던 것으로 분석되었다. 평가항목은 33개의 평가항목이 7개의 평가항목 군과 3개 의 경관영역에 유형화되어 평가항목 리스트로 구성되었다. 평가항목 군별 중요도 분석결과 모두 5점 이상으로 높게 나타났으며, 그 중 색채 군에서 6.04로 가장 높게 나타났다. 본 연구는 문헌분석으로 도출 된 평가항목이 전문가 설문 분석결과 대부분 중요도가 5점대 이상으로 높게 나타나 경관영향평가 평가 항목 리스트에 적용함에 무리가 없을 것으로 판단된다.

During the operation of a nuclear power plant (NPP), corrosion products called CRUD (Chalk River unidentified deposit) accumulate on the surface of the primary system. The CRUD components of pressurized light water reactors or heavy water reactors, represented by (NixFe1-x)(FeyCr1-y)2O4, are composed of Fe3O4, NiFe2O4, FeCr2O4, NiCr2O4, etc. Radionuclide such as Co-60 are deposited within this CRUD, so the entire deposited material must be dissolved and removed for decontamination. Chemical decontamination has the advantage of being able to decontaminate a wide metal surface, but has the disadvantage of generating a large amount of secondary waste. Recently, chemical decontamination methods that add an electrodynamic process are being studied to overcome these shortcomings. This technology is a method of dissolving CRUD by applying an electric field in the anodic compartment of a cell separated by CEM. It is a method of accelerating CRUD dissolution by generating a large amount of hydrogen ions in the anodic compartment. Dissolved metal ions pass through the CEM (cation exchange membrane) and move to the cathodic compartment (pH > 12), where they are removed by adsorption or precipitation process. Therefore, the speciation characteristics between decontamination agent (oxalic acid) and metal ions are very important. In this study, we investigated the speciation characteristics of Fe(II), Ni(II), Co(II) - oxalate, which are important complex species in CRUD dissolution cells. The thermodynamic equilibrium constant for hydrolysis of each ion and of M(II)-oxalate were collected and speciation characteristics were analyzed using the MINEQL 5.0 program. From the speciation characteristics of M(II)-oxalate, effective radionuclide removal methods in an electrodynamic cell were considered.

Decontamination is one of the important processes for dismantling nuclear power plants. The purpose of decontamination is to reduce the radiation levels of contaminated nuclear facilities, ensuring the safety of workers involved in decommissioning and minimizing the amount of radioactive waste. In this study, we investigate the reaction mechanisms and their thermodynamic energies of the HyBRID (Hydrazine-Based Reductive participated metal Ion Decontamination) process for decontamination of the primary coolant system of a nuclear power plant. We computed the thermodynamic properties of HyBRID dissolution mechanisms in which corrosion metal oxides accumulated in the primary coolant systems along with radionuclides are dissolved by HyBRID decontamination agents (H2SO4/N2H4/CuSO4). The HyBRID reaction mechanism has been studied using a commercial database (HSC Chemistry®), but Cu ions have been used instead of Cu-hydrazine complexes when calculating reactions due to the absence of thermodynamic properties for Cu-hydrazine complexes. To address this limitation, we supplemented the quantum calculations with Cu-hydrazine complexes using the density functional calculations. It is intended to simulate a more practical reactions by calculating the reactions considering Cu-hydrazine complexes, and to improve understanding of the HyBRID dissolution reactions by qualitatively and quantitatively comparing the reactions without considering the complex formation.

A Partially hydrolyzed poly (vinyl acetate) (PHPVA)-borax complex-based gel-like coating was successfully developed for the decontamination of Simulated nuclear fallout (SFO) from surfaces. The sprayable coating was self-generated on the surface by borate-diol ester bonds after simultaneously mixing two solutions of borax and PHPVA. The SFO particles, synthesized at 1,200°C for melting, were glassy while some crystalline phases (e.g., SiO2 and Fe2O3) existed together. The SFO particles were fixed onto the Stainless steel (SS) substrate by dropping and evaporating water. for examination of the dust-removal performance of PHPVA-borax based coating. The dusts on the SS surface was successfully removed by casting the PHPVA-borax based coating within 1 minute, demonstrating the excellent dust-removal property of the PHPVA-borax based coating. The used PAB complex in wet state was recovered by using vacuum suction machine in short time. The solid-state PHPVA-borax based film was self-delaminated from the SS substrate after fully drying the used PHPVA-borax coating but this requires long period of time.

Among nuclear power plants in the Republic of Korea, Kori Unit 1 and Wolsong Unit 1 have been permanently shut down, and Kori Unit 1 is preparing to be decommissioned. According to the decommissioning plan (DP) of Kori Unit 1, a radioactive waste processing complex will be built on the Kori site to reduce radioactive waste generated during decommissioning actively, and various types of decommissioning waste are expected to be treated in the complex. It is judged that matters related to the safety assessment of the complex are not included in the DP since the equipment and treatment processes have not been determined. IAEA GSR Part 5 states that radioactive waste processing complex shall be operated according to national regulations and the conditions imposed by the regulatory body. However, it has been confirmed that separate regulatory requirements for the complex have not yet been established in Korea. It is expected that the Regulation on Technical Standards for Nuclear Facilities, etc. will be applied mutatis mutandis. Liquid and gaseous radioactive materials can be expected to be released into the sea or atmosphere during the operation of the complex. Accordingly, it should be proved that standards such as discharge limits of radioactive effluents are met. Although the assessment of radioactive effluent discharged from nuclear power plants to the environment is systematically conducted, it has been confirmed that the safety assessment framework for radioactive effluents discharged from the complex has not yet been established. Currently, the SAFRAN Tool is based on SADRWMS (Safety Assessment Driving Radioactive Waste Management Solutions), an IAEA safety assessment methodology for pre-disposal management, which uses Pathway Dose Factors (PDFs) derived from generic environmental models. Therefore, in order to conduct a more detailed safety assessment of the complex on a specific site, site characteristic data should be reflected. Although safety assessment using the SAFRAN Tool was conducted at the Thailand Institute of Nuclear Technology (TINT) facility, detailed data were not provided, and PDFs reflecting site characteristic data were not applied. Also, no other studies that considered many types of waste and provided detailed data on the safety assessment were not confirmed. Therefore, this study developed K-CRAFT (Kyung Hee – Comprehensive RAdioactive waste treatment Facility safety assessment Tool), this tool that can derive PDFs by reflecting site characteristic data based on the SADRWMS methodology and conducted preliminary safety assessment for the complex which will be built in Kori site by this tool.

Over the years, in the field of safety assessment of geological disposal system, system-level models have been widely employed, primarily due to considerations of computational efficiency and convenience. However, system-level models have their limitations when it comes to phenomenologically simulating the complex processes occurring within disposal systems, particularly when attempting to account for the coupled processes in the near-field. Therefore, this study investigates a machine learning-based methodology for incorporating phenomenological insights into system-level safety assessment models without compromising computational efficiency. The machine learning application targeted the calculation of waste degradation rates and the estimation of radionuclide flux around the deposition holes. To develop machine learning models for both degradation rates and radionuclide flux, key influencing factors or input parameters need to be identified. Subsequently, process models capable of computing degradation rates and radionuclide flux will be established. To facilitate the generation of machine learning data encompassing a wide range of input parameter combinations, Latin-hypercube sampling will be applied. Based on the predefined scenarios and input parameters, the machine learning models will generate time-series data for the degradation rates and radionuclide flux. The time-series data can subsequently be applied to the system-level safety assessment model as a time table format. The methodology presented in this study is expected to contribute to the enhancement of system-level safety assessment models when applied.

This study presents a method for analyzing the surface temperatures of specific facilities, such as the 5 MWe reactor within the Yongbyon Nuclear Complex, to explore its potential utility in monitoring suspected nuclear-related activities in North Korea using thermal infrared (TIR) satellite imagery (Landsat series). TIR band data is utilized to derive surface temperatures in the specified areas, and the temperatures are analyzed on a monthly basis to examine any patterns within these regions. This research provides a pattern-of-life on temperature variation for the target areas through multiple TIR image datasets, offering additional information to analyze facilities’ operational status in remote and inaccessible regions.

철근콘크리트는 가장 널리 사용되는 건축자재로 최근 노후 시설물이 증가하면서 노후 구조물에 대한 안전성 검토가 매우 중요한 문제로 대두되고 있다. 본 연구에서는 대표적인 열화 인자인 동결융해와 철근부식 그리고 동결융해와 철근부식의 복합적 열화에 따른 RC 휨 부재의 거동을 실험적으로 평가하였다. 4개의 철근콘크리트 휨 부재를 제작하였으며 각 열화 인자에 따른 RC 휨 부재의 거동을 평가하기 위해 4점 재하법을 이용하여 정적실험을 수행하였다. 동결융해는 총 300 사이클의 급속동 결융해실험을 수행하였으며, 부식은 전위차부식촉진실험을 수행하였다. 실험 결과, 동결융해로 인해 콘크리트의 압축강도가 12% 감소하였으며 RC 보 부재의 상부 압축부의 파쇄 범위가 증가하였고 최대강도가 6% 감소하였다. 철근부식으로 인해 RC 휨 부 재의 항복강도가 1.2%, 최대강도가 7% 감소하였으며, 복합열화로 인해 RC 휨 부재의 항복강도가 2.4%, 최대강도가 9% 감소하 였다.

유기농 생태농업단지 논에서 출현하는 수서곤충의 생태자원 분포 특성을 비교하고자 유기농 단지 논에 둠벙 이 있는 조건과 둠벙이 없는 조건에서의 수서곤충상을 조사하여 관행 논의 분포 특성을 비교하였다. 수서곤충 출현은 둠벙이 있는 유기농 논 5목 15과 26종 413개체, 둠벙이 없는 유기농 논 5목 14과 22종 236개체, 관행 논 5목 11과 16종 155개체로 유기농 논에서 관행 논에 비해 수서곤충의 출현 과, 종 및 출현 개체수가 많았고, 유기농 논에서도 둠벙이 있는 조건에서 종수 및 개체수가 많음을 확인하였다. 특히 잠자리목의 경우 유기농 논 4과 8종 134개체, 둠벙이 없는 유기농 논 3과 5종 35개체, 관행 논 2과 4종 12개체로 전체 출현 종의 발생특성과 유사한 경향을 보였는데, 유기농 재배의 특성상 농약의 피해로부터 수서곤충에 안전한 환경이 조성된 점과 둠벙의 담수 및 다양한 수서생물의 발생으로 수서곤충의 서식조건에 유리하게 작용되었다고 보인다. 반면 파리목에서는 둠벙이 있는 유기농 논 3과 3종 18개체, 둠벙이 없는 유기농 논 3과 3종 25개체로 관행 논 2과 2종 24개체보다 발생양상이 다른 수서곤충에 비해 상대적으로 낮고, 관행 논보다 깔다구류의 개체수 19개체보다 각각 6개체, 12개체로 적게 출현한 점에서 유기농 재배유형과 둠벙의 서식처 제공이 수서곤충의 출현 및 분포에 건전성을 조장하는 방안이라고 판단된다.

Phosphine is a common pesticide used to control grain pests in Rice Processing Complex(RPC). However, increasing use of aluminum phosphide caused the occurrence of phosphine resistance pests. In this study, phosphine resistance pests collected at RPC in 2023 was investigated with FAO No. 16 test, Dihydrolipomaide dehydrogenase(DLD) test and amino acid mutation analysis to identify the occurrence of phosphine resistance in Korea. Tested pests were collected in the 7 province 35 region. As a result of the FAO test of 21 regions, all sample were phosphine sensitives. In DLD test and amino acid analysis, 7 region samples were weak resistances. It is required to inspect the RPC and other grain storage continuously to inhibit the widespread of resistant pest.

Culex pipiens complex는 West Nile virus의 주요 매개체이며, 대한민국에는 Cx. pipiens pallens와 Cx. pipiens f. molestus가 서식한다고 알려져 있다. 그러나 현재까지 대한민국에서 진행된 Culex pipiens complex의 살충제 관련 실험은 종 수준 이하의 단계에서 비교가 이루어지지 않고 있다. 이에 본 연구에서는 대한민국의 13개 지역에 서 Culex pipiens complex를 채집하였고, 분자 마커를 이용해 종 수준 이하 단계까지 분류를 진행한 뒤 각 분류군의 Acetylcholinesterase-1(Ace-1)와 Voltage-gated sodium channel(Vgsc) 유전자에 대한 저항성 돌연변이 존재 유무를 확인하였다. Ace-1 영역 확인 결과, Cx. pipiens f. molestus에서는 저항성이 확인되지 않았으며, 목포에서 채집된 Cx. pipiens pallens 1개체에서 저항성 개체가 발견되었다. Vgsc 영역에서는 저항성 유전형질을 보유한 개체가 Cx. pipiens pallens와 Cx. pipiens f. molestus에서 모두 발견되었으며, 다양한 지역에서 서로 다른 비율로 존재하는 것을 확인하였다. 본 조사 결과는 향후 대한민국에 서식하는 Culex pipiens complex의 효율적인 방제를 위한 기초자료로 활용될 수 있을 것이다.