Developing the high-performance semiconductor photocatalytic materials is an eternal topic under the background of the current energy and environment requirements. In recent years, single-atom photocatalysts (SAPCs) have been brought a lot of attention in energy conversion and environmental purification because of their unique characteristics and properties, including the unique coordination patterns, outstanding atomic utilization, quantum confinement effects, high catalytic activity, etc. Hence, this critical review focuses on the summarized various synthetic methods and the recent important applications of SAPCs, including photocatalytic H2 evolution (PHE) from water splitting, photocatalytic CO2 reduction, photodegradation of organic pollutants, etc. The prospects and challenges for future research topics of SAPCs with excellent activity and stability for various photocatalytic applications are prospected at the end of this review. We sincerely expect that this critical review can promote deep-level insight into the SAPCs subject for the future significant applications in other fields.

In this study, we analyzed all of the waste streams associated with household waste to provide a basis for incorporating the individual characteristics of municipalities in setting targets for waste-to-resource circulation. Toward this end, we examined how household waste is treated based on the disposal method (mixed waste disposed of in standard volumerate garbage bags, separation recyclable waste, and food waste) and the amount of residuals generated at their respective treatment facilities. The actual recycling rate or actual waste-to-energy conversion rate was calculated as the ratio of the actual amount of waste that is recycled or converted to energy against the amount of waste intake at waste treatment facilities. The conversion factor of actual recycling rates at 17 municipalities showed an average of 63.9% for public material recovery facilities (MRFs) with those for individual municipalities ranging from 50.4% to 93.2%, and an average of 93.8% for private and public food waste treatment facilities with slightly higher rates found for public facilities (70.4 ~ 100%) than private facilities (63.3 ~ 100%). The actual waste-to-energy conversion factor was 59.3% on average for combustible waste-to-energy facilities (17.2 ~ 72.3%) and 92.0% on average for biological waste-to-energy facilities (77.1 ~ 99.5%). To achieve the national target for the actual recycling rate, additional strategies for recycling or converting the residuals generated at recycling or combustible waste-to-energy facilities into resources are needed. The actual recycling and waste-to-energy conversion rates provided in this study based on a full examination of household waste streams hold valuable insights for incorporating the individual situations of municipalities in setting their targets for wasteto- resource circulation indicators and creating new strategies for improving the actual recycling rate.

In recent years, waste-to-energy conversion using municipal solid waste (MSW) has been gaining attention in municipalities. Such conversion can reduce the dependency of non-renewable energy such as fossil fuels by generating solid refuse fuel (SRF) and diverting landfilling of the waste, although there is debate over the efficiency and economic aspect of the practice. With a growing interest in the conversion, D city is trying to adopt all possible measures towards achieving a material-cycle society by constructing a waste-to-energy town by 2018. The waste-to-energy town will be comprised of energy recovery facilities such as a mechanical treatment facility for fluff-type SRF with a power generation plant, and anaerobic digestion of food waste for biogas recovery. In this paper, we focus on estimating the energy recovery potentials and greenhouse gas (GHG) reduction of MSW by waste-to-energy conversion under three different scenarios. The data required for this study were obtained from available national statistics and reports, a literature review, and interviews with local authorities and industry experts. The lower heating value was calculated using the modified Dulong equation. Based on the results of this study, the energy recovery potential of MSW was calculated to be approximately 14,201-51,122 TOE/y, 12,426-44,732 TOE/y, and 8,520-30,673 TOE/y for Scenarios 1, 2, and 3, respectively. The reduction of GHG by such conversion was estimated to range from 10,074-36,938 tonCO2eq/y, depending on scenario. This study would help determine the production rate of fluff-type SRF to be converted into a form of energy. In addition, this study would aid waste management decision-makers to clarify the effectiveness of recycling of MSW and their corresponding energy recovery potentials, as well as to understand GHG reduction by the conversion.

This paper assesses the feasibility of producing fuel energy from sewage sludge via four processes: microwave-induced pyrolysis/gasification and conventional pyrolysis/gasification. Both pyrolysis and gasification produced gas, char, and tar. The gas produced for the gasification contained mainly hydrogen and carbon monoxide with a small amount of methane and hydrocarbons (C2H4, C2H6, C3H8). However, the gasification produced higher carbon monoxide instead of the hydrogen. The microwave gasification generated higher heavy tar compared to other processes. As a light tar, benzene generated higher value for both the pyrolysis and gasification. The sludge char showed a vitreous-like texture for the microwave process and a deep crack shape for the conventional heating process. These results indicate that the gas produced from the microwave processes of wet sewage sludge might be usable as a fuel energy source, but this would require removal of the condensable PAH tars. The sludge char produced could also be used as a solid fuel or adsorbent.

This study analyzed the effect of Greenhouse of wood pellet fuel conversing from Diesel. Analyzed through a life cycle assessment of greenhouse gas emissions of carbon dioxide for the environmental assessment, In evaluation of the Ministry of the Environment, analyzed through the life cycle assessment of carbon dioxide emissions of the greenhouse gas and, In the case of economic evaluation, we analyzed the investment payback period to the total revenue generated by each of the calculated incentive based on the RHI and institutions reduction projects a reduction of costs associated with the reduction of fuel costs.

In order to cope with resource depletion and global warming, many countries around the world are seeking the technicaland political alternatives and are focusing on production of refuse derived fuel (SRF) as a viable approach. SRF isclassified into pellet SRF and fluff SRF based on the shape. In domestic trend, Pellet RDF has been mainly produceduntil now, but as the quality standard of fluff SRF was set up lately, it is expected to raise supply and demand on FluffSRF after this. Fluff SRF is a solid fuel not to be processed pelletizing step, and has advantages that manufacturing processis simple and economical. In this paper, we selected 3 MBT plants to produce Pellet SRF in Korea and examined reductioneffects of energy and CO2 emission by conversion of pellet SRF to fluff SRF. As a result, the saving energy by theconversion of SRF type is 2,509 Gcal/yr (A), 1,716 Gcal/yr (B) and 1,210 Gcal/yr (C) respectively, and the reductionrate of energy consumption in full process is about 23%~26% by comparison with pellet SRF. Also, the average ofreduction of CO2 emission per unit of MSW is 0.0272 tCO2/ton. After estimating the reduction of CO2 emission of 9MBT plants in Korea, based on the results of a survey of target plants, we concluded that the reduction effect of CO2emission is created 11,374 tCO2/yr.

In the sea various methods have been conducted to capture wave energy which include the use of pendulums, pneumatic devices, etc. Floating devices, such as a cavity resonance device take advantages of both the water motion and the wave induced motions of the floating body itself. The wave energy converter is known commercially as the WAGB(Wave Activated Generator Buoy) and is used in some commercially available buoys to power navigation aids such as lights and horns. This wave energy converter consists of a circular flotation body which contains a vertical water column that has free communication with the sea. A theoretical analysis of this power generated by a pneumatic type wave energy converter is performed and the results obtained from the analysis are used for a real wave energy converter buoy. This paper is shown to have an optimum value for which maximum power is obtained at a given resonant wave period Also, the length of the internal water column corresponds to that of the water mass in the water column. If designed properly, wave energy converter can take advantage not only of the cavity resonance, but also qf the heaving motion of the buoy. Finally, simulation is performed with a LabVIEW program and the simulation results are applied to a wave energy simulator for modifying design data for a wave energy converter.

OWE형 파력발전장치는 해수면의 승강운동을 공기실 내의 공기 흐름으로 전환하고 이를 터빈의 구동력으로 사용하는 발전장치이다. 파랑에너지가, 터빈으로 유입되는 공기에너지로 전환하도록 하는 공기실의 내부 수위의 주기적 변동은 상하대칭이 이루어지지 않고, 공기실 내 공기 유동의 압축과 팽창 과정에서 유량차가 발생하게 된다. 본 논문에서는 이를 이용하여 보다 많은 유량을 임펄스터빈의 압력면으로 유도하여 날개의 압력면과 흡입면의 압력차를 크게 하는 Staggered Blade의 적용에 대해 검토하고 그에 대한 성능 해석을 수행하였다. 터빈의 압력면으로의 공기 흐름을 제어하기 위해 Self-Pitched Blade(가변 피치 날개)를 제안하였고, 이러한 유량차를 토대로 동 조건에서 최대의 발전량과 최고 효율의 터빈을 설계하고자 하는데 그 목적이 있다.

파력발전장치 중 진동수주(Oscillating Water Column)형은 3단계 에너지 변환과정을 거치게 된다. 그 중 파랑에너지를 공기에너지로 변환하는 장치인 공기실의 형상을 바꿔가며 그에 따른 성능을 상용 CFD 코드인 FLUENT를 이용한 수치 해석 기법으로 연구하여 보았다. 통상 OWC형 파력발전장치는 공기실과, 터빈이 설치되는 덕트 간에 효율적인 이유로 급축소 형태를 취하고 있는데 이 때 공기실과 터빈 연결부의 형상이 파력발전 장치 전체 성능에 중요한 영향을 미치므로 공기실내의 압력을 최소화하고 터빈 유입유속의 가속화가 용이한 가장 적합한 형상을 정상 및 비정상 해석을 통하여 찾고자 하였다.