The pursuit of sustainable and durable cementitious composites has led to a growing interest in alternative materials that can improve mechanical performance while reducing CO2 emissions. Nanomaterials, in particular, offer promising avenues due to their unique properties, including high surface area to volume ratio and increased reactivity. This study investigates the efficacy of Cellulose Nanofibers (CNF) in enhancing the durability of mortar exposed to sulfate attacks and alkali-silica reactions (ASR). Both MgSO4 and Na2SO4 solutions were employed to simulate sulfate attacks, while the role of CNF in mitigating ASR was also evaluated. Results indicate that CNF incorporation positively impacts the resistance of mortar against sulfate attacks and ASR, paving the way for eco-friendly and durable cement-based structures with extended service life.

Seawater evaporation and purification powered by solar energy are considered as a promising approach to alleviate the global freshwater crisis, and the development of photothermal materials with high efficiency is imminent. In this study, cellulose nanofiber (CNF)/MXene/Ni chain (CMN) aerogels were successfully synthesized by electrostatic force and hydrogen bond interaction force. CMN10 achieved a favorable evaporation rate as high as 1.85 kg m− 2 h− 1 in pure water, and the corresponding evaporation efficiency could be up to 96.04%. Even if it is applied to seawater with multiple interference factors, its evaporation rate can still be 1.81 kg m− 2 h− 1. The superior seawater evaporation activity origins from the promoted separation of photoexcited charges and photothermal conversion by the synergy of Ni chain and MXene, as well as the water transport channel supported by the 3D structure frame of CNF. Most importantly, CMN aerogel can maintain water vapor evaporation rates above 1.73 kg m− 2 h− 1 under extreme conditions such as acidic (pH 2) and alkaline (pH 12) conditions. In addition, various major ions, heavy metals and organic pollutants in seawater can be rejected by CMN10 during desalination, and the rejection rates can reach more than 99.69%, ensuring the purity of water resources after treatment. This work shows the great potential of CMN aerogel as a high-efficiency solar evaporator and low-cost photothermal conversion material. Cellulose nanofiber (CNF)/MXene/Ni chain (CMN) aerogels demonstrated high evaporation of water from sea water.

In order to increase the usability of PLA in tissue engineering, we tried to improve the hydrophobicity and low mechanical properties of PLA. The basic solutions were prepared by mixing 3, 5, and 7wt.% of PLA in a solution of chloroform and acetone in a volume ratio of 3:1. Several types of nanofiber mats were fabricated using a mixed solution in which 0.5, 1, and 3wt.% of PEO and PVAc, which are biodegradable polymers, were added to these solutions, respectively, through the SBS method. As a result, it was found that when the content of PEO increased, the diameter and surface state of nano fibers became uniform and the water contact angle significantly decreased, but it did not affect the tensile strength. In addition, the hydrophobicity of PLA was improved to hydrophilicity by mixing with PVAc, but the strain was greatly reduced.

Renewed interest in the reinforced carbon graphite composites has intrigued the community in the advanced materials fields. In this work, we present a simple carbon nanofibers reinforced carbon graphite composites synthetic method by incorporating mixture of coal tar pitch, synthetic graphite, pitch coke and the dispersion liquid of carbon nanofibers via liquid-phase mixing process. The impact of carbon nanofiber utilization on the microstructures and mechanical properties of carbon graphite composites are studied systematically. The covalent surface modification of carbon nanofibers effectively improves its microstructure and thereby promotes the carbon graphite composites’ dispersion behavior. We propose that a small amount of carbon nanofibers could promote the carbonization process of carbon graphite composites, facilitating the densification of carbon graphite composites and reducing the undesired open porosity. The amount of 0.7 wt % of carbon nanofiber concentration allows the enhancement of bend and compressive strength of carbon graphite composites up to 36.50 MPa and 60.46 MPa, increased by 167.9% and 146.9% compared with the pure carbon graphite composite, respectively. Our findings can be rationalized due to the improvement in the mechanical strength of carbon graphite composites could be attributed due to pull-out of carbon nanofibers from the matrix and bridging effect across the crack pores within the matrix.

Transition-metal phosphides (TMPs), a promising anode material for lithium-ion batteries (LIBs), are limited in application because of its serious volume effect in the cycle. In this work, a simple electrospinning strategy was proposed to restrict the grain size of CoP nanocrystals by nano-confined effect of carbon nanofibers with ligands. The addition of ligands not only could realize the uniform dispersion of CoP nanocrystals, but also strengthen the bond between the metals and carbon nanofibers. As a result, the CoP/CNF composite exhibits excellent lithium storage performance, and its reversible specific capacity could reach 1016.4 mAh g− 1 after 200 cycles at a current density of 200 mA g− 1. The research is anticipated to provide a new idea for the preparation of anode materials for lithium ion batteries.

In this work, a nanocomposite containing gold (Au) nanofibers decorated iron-metal–organic framework (Fe-MOF) was successfully synthesized for electrochemical detection of acetaminophen (AAP). The as-synthesized Au@Fe-MOF nanocomposite was confirmed by various characterization techniques. Morphological analysis showed that the Au nanofibers with an average size of less than 10 nm were dispersed on the Fe-MOF. Cyclic voltammetric analysis showed that the Au@Fe-MOF nanocomposite showed well-defined redox peaks with higher current than that of GCE and Fe-MOF. The Au@Fe-MOF/ GCE exhibited a linear range, sensitivity, and detection limit of 0.5–18 μM, 4.95 μM/μA/cm2, and 0.12 μM, respectively. The Au@Fe-MOF/GCE showed a very low response for the interference materials. The real sample analysis revealed that the Au@Fe-MOF/GCE showed good recovery towards the AAP in urine and paracetamol. Therefore, the developed sensor can be used for quality control of AAP.

In this article, nitrogen (N) doped porous carbon nanofibers (N-PCNF) were prepared by carbonization of polymer-silica nanocomposite precursor, and its application for heavy metal ion removal was demonstrated. Carbon–silica composite nanofibers were obtained by carbonization of electrospun polyacrylonitrile (PAN)-silica nanofiber composites. Subsequent selective etching of silica porogen produced porous carbon nanofibers (PCNF). It was revealed by surface characterization with X-ray photoelectron spectroscopy (XPS) that the surface of the PCNF was nitrogen-doped because N atom from cyanide group in PAN chains remained in the hexagonal carbon structure. The use of the obtained N-PCNF for heavy metal ion ( Hg2+) removal was demonstrated using a simple adsorption test apparatus and 5, 10, 15, 20-tetraphenylporphine tetrasulfonic acid (TPPS) as an indicator. The N-PCNF showed a removal efficiency of 96 and 99% in 10 and 120 min, respectively, indicating a maximum heavy metal ion adsorption capacity at pH 7.0. In addition, heavy metal ion adsorption behavior was also analyzed using common adsorption isotherms. This article provides important information for future research activities regarding control over hazardous substances.

Cost-effective and sustainable high-performance supercapacitor material was successfully prepared from cellulosic waste (Sapindus trifoliatus nut shells) biomass-derived activated carbon (CBAC) by physical activation method. The CBAC displays nanofiber morphology, high specific surface area (786 m2/ g), large pore volume (0.212 cm3 g− 1) which are evaluated using FESEM, BET and possessed excellent electrochemical behavior analyzed through various electrochemical methods. Moreover, the assembled symmetric CBAC//CBAC device exhibits high specific capacitance of 240.8 F g− 1 with current density of 0.2 A g− 1 and it is maintained to 65.6 F g− 1 at high current density of 2.0 A g− 1. In addition, the symmetric device delivers an excellent specific energy maximum of over 30 Wh kg− 1 at 400 W kg− 1 of specific power and excellent cycling stability in long term over 5000 cycles. The operation of the device was tested by light-emitting diode. Hence, CBAC-based materials pave way for developing large-scale, low-cost materials for energy storage device applications.

A carbon nanofiber was produced from the Areca catechu husk as a supercapacitor electrode, utilizing a chemical activation of potassium hydroxide (KOH) at different concentrations. One-stage integrated pyrolysis both carbonization and physical activation were employed for directly converting biomass to activated carbon nanofiber. The morphology structure, specific surface area, pore structure characteristic, crystallinity, and surface compound were characterized to evaluate the influence on electrochemical performance. The electrochemical performance of the supercapacitor was measured using cyclic voltammetry (CV) through a symmetrical system in 1 M H2SO4. The results show that the KOH-assisted or absence activation converts activated carbon from aggregate into a unique structure of nanofiber. The optimized carbon nanofiber showed the large specific surface area of 838.64 m2 g−1 with the total pore volume of 0.448 cm3 g−1, for enhancing electrochemical performance. Beneficial form its unique structural advantages, the optimized carbon nanofiber exhibits high electrochemical performance, including a specific capacitance of 181.96 F g−1 and maximum energy density of 25.27 Wh kg−1 for the power density of 91.07 W kg−1. This study examines a facile conventional route for producing carbon nanofiber from biomass Areca catechu husk in economical and efficient for electrode supercapacitor.

Tungsten disulfide (WS2), a typical 2D layerd structure, has received much attention as a pseudocapacitive material because of its high theoretical specific capacity and excellent ion diffusion kinetics. However, WS2 has critical limits such as poor long-term cycling stability owing to its large volume expansion during cycling and low electrical conductivity. Therefore, to increase the high-rate performance and cycling stability for pseudocapacitors, well-dispersed WS2 nanoparticles embedded in carbon nanofibers (WS2-CNFs), including mesopores and S-doping, are prepared by hydrothermal synthesis and sulfurizaiton. These unique nanocomposite electrodes exhibit a high specific capacity (159.6 F g−1 at 10 mV s−1), excellent high-rate performance (81.3 F g−1 at 300 mV s−1), and long-term cycling stability (55.9% after 1,000 cycles at 100 mV s−1). The increased specific capacity is attributed to well-dispersed WS2 nanoparticles embedded in CNFs that the enlarge active area; the increased high-rate performance is contributed by reduced ion diffusion pathway due to mesoporous CNFs and improved electrical conductivity due to S-doped CNFs; the long-term cycling stability is attributed to the CNFs matrix including WS2 nanoparticles, which effectively prevent large volume expansion.

The (Ga1-xZnx)(N1-xOx) solid solution is attracting extensive attention for photocatalytic water splitting and wastewater treatment owing to its narrow and controllable band gap. To optimize the photocatalytic performance of the solid solution, the key points are to decrease its band gap and recombination rate. In this study, (Ga1-xZnx)(N1-xOx) nanofibers with various Zn fractions are prepared by electrospinning followed by calcination and nitridation. The effect of the composition and crystallinity of electrospun oxide nanofibers on the morphology and optical properties of the obtained solid-solution nanofibers are systematically investigated. The results show that the final shape of the (Ga1-xZnx) (N1-xOx) material is greatly affected by the crystallinity of the oxide nanofibers before nitridation. The photocatalytic properties of (Ga1-xZnx)(N1-xOx) with different Ga:Zn atomic ratios are investigated by studying the degradation of rhodamine B under visible light irradiation.

To improve the performance of carbon nanofibers as electrode material in electrical double-layer capacitors (EDLCs), we prepare three types of samples with different pore control by electrospinning. The speciments display different surface structures, melting behavior, and electrochemical performance according to the process. Carbon nanofibers with two complex treatment processes show improved performance over the other samples. The mesoporous carbon nanofibers (sample C), which have the optimal conditions, have a high sepecific surface area of 696 m2 g−1, a high average pore diameter of 6.28 nm, and a high mesopore volume ratio of 87.1%. In addition, the electrochemical properties have a high specific capacitance of 110.1 F g−1 at a current density of 0.1 A g−1 and an excellent cycling stability of 84.8% after 3,000 cycles at a current density of 0.1 A g−1. Thus, we explain the improved electrochemical performance by the higher reaction area due to an increased surface area and a faster diffusion path due to the increased volume fraction of the mesopores. Consequently, the mesoporous carbon nanofibers are demonstrated to be a very promising material for use as electrode materials of high-performance EDLCs.

A heterogeneous photocatalytic system is attracting much interest for water and air purification because of its reusability and economical advantage. Electrospun nanofibers are also receiving immense attention for efficient photocatalysts due to their ultra-high specific surface areas and aspect ratios. In this study, ZnO nanofibers with average diameters of 71, 151 and 168 nm are successfully synthesized by facile electrospinning and a subsequent calcination process at 500 ℃ for 3 h. Their crystal structures, morphology features and optical properties are systematically characterized by X-ray diffraction, scanning electron microscopy, UV-Vis and photoluminescence spectroscopies. The photocatalytic activities of the ZnO nanofibers are evaluated by the photodegradation of a rhodamine B aqueous solution. The results reveal that the diameter of the nanofiber, controlled by changing the polymer content in the precursor solution, plays an important role in the photocatalytic activities of the synthesized ZnO nanofibers.

Mesoporous carbon nanofibers as electrode material for electrical double-layer capacitors(EDLCs) are fabricated using the electrospinning method and carbonization. Their morphologies, structures, chemical bonding states, porous structure, and electrochemical performance are investigated. The optimized mesoporous carbon nanofiber has a high sepecific surface area of 667 m2 g−1, high average pore size of 6.3 nm, and high mesopore volume fraction of 80 %, as well as a unifom network structure consiting of a 1-D nanofiber stucture. The optimized mesoporous carbon nanofiber shows outstanding electrochemical performance with high specific capacitance of 87 F g−1 at a current density of 0.1 A g−1, high-rate performance (72 F g−1 at a current density of 20.0 A g−1), and good cycling stability (92 F g−1 after 100 cycles). The improvement of the electrochemical performance via the combined effects of high specific surface area are due to the high mesopore volume fraction of the carbon nanofibers.

In this study, composite PAN-based ACNFs embedded with MgO and MnO2 were prepared by the electrospinning method. The resultant pristine ACNFs, ACNF/MgO and ACNF/MnO2 were characterized in terms of their morphological changes, SSA, crystallinity and functional group with FESEM-EDX, the BET method, XRD and FTIR analysis, respectively. Results from this study showed that the SSA of the ACNF/MgO composite (1893 m2 g–1) is significantly higher than that of the pristine ACNFs and ACNF/MnO2 which is 478 and 430 m2 g–1, respectively. FTIR analysis showed peaks of 476 and 547 cm–1, indicating the presence of MgO and MnO2, respectively. The FESEM micrographs analysis showed a smooth but coarser structure in all the ACNFs. Meanwhile, the ACNF/MgO has the smallest fiber diameter (314.38±62.42 nm) compared to other ACNFs. The presence of MgO and MnO2 inside the ACNFs was also confirmed with EDX analysis as well as XRD. The adsorption capacities of each ACNF toward CH4 were tested with the volumetric adsorption method in which the ACNF/MgO exhibited the highest CH4 adsorption up to 2.39 mmol g–1. Meanwhile, all the ACNF samples followed the pseudo-second order kinetic model with a R2 up to 0.9996.