In this research, a detailed analysis of the decay heat contributions of both actinides and non-actinides (fission fragments) from spent nuclear fuel (SNF) was made after 50 GWd·tHM−1 burnup of fresh uranium fuel with 4.5% enrichment lasted for 1,350 days. The calculations were made for a long storage period of 300 years divided into four sections 1, 10, 100, and 300 years so that we could study the decay heat and physical disposal ratios of radioactive waste in medium- and long-term storage periods. Fresh fuel burnup calculations were made using the code MCNP, while isotopic content and then decay heat were calculated using the built-in stiff equation solver in the MATLAB code. It is noted that only around 12 isotopes contribute more than 90% of the decay heat at all times. It is also noted that the contribution of actinides persists and is the dominant ether despite decreasing decay heat, while the effect of fission products decreases at a very rapid rate after about 40 years of storage.

The initial development plans for the six reactor designs, soon after the release of Generation IV International Forum (GIF) TRM in 2002, were characterized by high ambition [1]. Specifically, the sodium-cooled fast reactor (SFR) and very-high temperature reactor (VHTR) gained significant attention and were expected to reach the validation stage by the 2020s, with commercial viability projected for the 2030s. However, these projections have been unrealized because of various factors. The development of reactor designs by the GIF was supposed to be influenced by events such as the 2008 global financial crisis, 2011 Fukushima accident [2, 3], discovery of extensive shale oil reserves in the United States, and overly ambitious technological targets. Consequently, the momentum for VHTR development reduced significantly. In this context, the aims of this study were to compare and analyze the development progress of the six Gen IV reactor designs over the past 20 years, based on the GIF roadmaps published in 2002 and 2014. The primary focus was to examine the prospects for the reactor designs in relation to spent nuclear fuel burning in conjunction with small modular reactor (SMR), including molten salt reactor (MSR), which is expected to have spent nuclear fuel management potential.

The objectives of this paper are: (1) to conduct the thermal analyses of the disposal cell using COMSOL Multiphysics; (2) to determine whether the design of the disposal cell satisfies the thermal design requirement; and (3) to evaluate the effect of design modifications on the temperature of the disposal cell. Specifically, the analysis incorporated a heterogeneous model of 236 fuel rod heat sources of spent nuclear fuel (SNF) to improve the reality of the modeling. In the reference case, the design, featuring 8 m between deposition holes and 30 m between deposition tunnels for 40 years of the SNF cooling time, did not meet the design requirement. For the first modified case, the designs with 9 m and 10 m between the deposition holes for the cooling time of 40 years and five spacings for 50 and 60 years were found to meet the requirement. For the second modified case, the designs with 35 m and 40 m between the deposition tunnels for 40 years, 25 m to 40 m for 50 years and five spacings for 60 years also met the requirement. This study contributes to the advancement of the thermal analysis technique of a disposal cell.

A transfer cask serves as the container for transporting and handling canisters loaded with spent nuclear fuels from light water reactors. This study focuses on a cylindrical transfer cask, standing at 5,300 mm with an external diameter of 2,170 mm, featuring impact limiters on the top and bottom sides. The base of the cask body has an openable/closable lid for loading canisters with storage modules. The transfer cask houses a canister containing spent nuclear fuels from lightweight reactors, serving as the confinement boundary while the cask itself lacks the confinement structure. The objective of this study was to conduct a structural analysis evaluation of the transfer cask, currently under development in Korea, ensuring its safety. This evaluation encompasses analyses of loads under normal, off-normal, and accident conditions, adhering to NUREG-2215. Structural integrity was assessed by comparing combined results for each load against stress limits. The results confirm that the transfer cask meets stress limits across normal, off-normal, and accident conditions, establishing its structural safety.

With South Korea increasingly focusing on nuclear energy, the management of spent nuclear fuel has attracted considerable attention in South Korea. This study established a novel procedure for selecting safety-relevant radionuclides for long-term safety assessments of a deep geological repository in South Korea. Statistical evaluations were performed to identify the design basis reference spent nuclear fuels and evaluate the source term for up to one million years. Safety-relevant radionuclides were determined based on the half-life criteria, the projected activities for the design basis reference spent nuclear fuel, and the annual limit of ingestion set by the Nuclear Safety and Security Commission Notification No. 2019-10 without considering their chemical and hydrogeological properties. The proposed process was used to select 56 radionuclides, comprising 27 fission and activation products and 29 actinide nuclides. This study explains first the determination of the design basis reference spent nuclear fuels, followed by a comprehensive discussion on the selection criteria and methodology for safety-relevant radionuclides.

In this study, the impact load resulting from collision with the fuel rods of surrogate spent nuclear fuel (SNF) assemblies was measured during a rolling test based on an analysis of the data from surrogate SNF-loaded sea transportation tests. Unfortunately, during the sea transportation tests, excessive rolling motion occurred on the ship during the test, causing the assemblies to slip and collide with the canister. Hence, we designed and conducted a separate test to simulate rolling in sea transportation to determine whether such impact loads can occur under normal conditions of SNF transport, with the test conditions for the fuel assembly to slide within the basket experimentally determined. Rolling tests were conducted while varying the rolling angle and frequency to determine the angles and frequencies at which the assemblies experienced slippage. The test results show that slippage of SNF assemblies can occur at angles of approximately 14° or greater because of rolling motion, which can generate impact loads. However, this result exceeds the conditions under which a vessel can depart for coastal navigation, thus deviating from the normal conditions required for SNF transport. Consequently, it is not necessary to consider such loads when evaluating the integrity of SNFs under normal transportation conditions.

The need for the development of sustainable, efficient, and green radioactive waste disposal methods is emerging with the saturation of spent nuclear waste storage facilities in the Republic of Korea. Conventional radioactive waste management methods like using cement or glass have drawbacks such as high porosity, less chemical stability, high energy consumption, carbon dioxide production, and the generation of secondary wastes, etc. To address this gigantic issue of the planet, we have designed a study to explore the potential of alternative materials having easy processability, low carbon emissions and more chemical stability such as ceramic (hydroxyapatite, HAP) and alkali-activated materials (geopolymers, GP) to capture the simulated radioactive cobalt ions from the contaminated water and directly solidify them at low temperatures. Physical and mechanical properties of HAP alone and 15wt% GP incorporated HAP (HAP-GP- 15) composite were studied and compared. The surface of both materials was fully sorbed with an excess amount of Co(II) ions in the aqueous system. Co(II) sorbed powders were separated from aqueous media using a centrifuge machine operating at 5,000 RPM for 10 minutes and dried at 100°C for 8 hours. The dried powders were then placed in stainless steel molds, and shaped into cylindrical pellets using a uniaxial press at a pressure of 1 metric ton for 1 minute. The pellets were sintered at 1,100°C for 2 hours at a heating rate of 10°C/min. Following this, the water absorption, density, porosity, and compressive strength of the polished pellets were measured using standard methods. Results showed that HAP has a greater potential for decontamination and solidification of Co(II) due to its higher density (2.65 g/cm3 > 1.90 g/cm3), less open porosity (16.2±2.9% < 42.4 ±0.9%) and high compressive strength (82.1±10.2 MPa > 6.9±0.8 MPa) values at 1,100°C compared to that of HAP-GP-15. Nevertheless, further study with different constituent ratio of HAP and GP at various temperatures is required to fully optimize the HAP-GP matrix for waste solidifications.

A comprehensive understanding of actinide coordination chemistry and its structure is essential in many aspects of the nuclear fuel cycle, such as fuel reprocessing, waste management, reactor safety, and non-proliferation efforts. Managing radioactive waste generated during the nuclear fuel cycle has recently become more important, accordingly increasing the importance of designing appropriate waste forms and storage solutions for long-term waste disposal. Compared to the increase in the need for understanding the chemistry of major radioactive elements, the information on the local structure of the radioactive elements, especially actinides, remains unknown. To probe this issue, X-ray absorption fine structure (XAFS) can be applied. By analyzing the EXAFS (extended X-ray absorption fine structure) and XANES (X-ray absorption near edge structure), the local structure around atoms can be determined. However, the radioactive properties of the nuclides hindered the measurement of EXAFS and XANES, due to the difficulties of preparation, containment, and transfer of the sample. To measure the EXAFS of various compounds regarding the back-end nuclear fuel cycle, laboratory-based EXAFS (hiXAS, HP spectroscopy) has been introduced which can measure the EXAFS and XANES at the energy range of 5-18 keV. Compounds of Copper (Cu foil, CuO samples), Zirconium (Zr foil), and Europium (Eu2O3) were used for the verification of the laboratory -based EXAFS at a given energy range. The measured EXAFS spectrum of various compounds exhibit good agreement with the theoretical data, showing an R-factor of less than 0.02. It was found that each graph has a first peak corresponding to 2.55Å for Cu foil (Cu-Cu), 1.93Å for CuO samples (Cu-O), 3.23Å for Zr foil (Zr-Zr), and from 2.32Å to 2.34Å for Eu2O3 (Eu-O), which agree well with other values from the literature. From the result, it can be implied that this equipment can be used especially in the back-end nuclear fuel cycle field to enhance the understanding of local structure in radiochemistry.

Molten chloride salts have received considerable research attention as potential nuclear fuel and coolant candidates for molten salt reactors. However, there are several challenges, especially for structural materials due to the selective dissolution of chromium (Cr) in the molten chloride salts environment. Understanding the compatibility of uranium (U), which is used as nuclear fuel in molten salt reactors, with Cr in molten chloride salts is critical for designing the molten salt reactor structure. Therefore, in this study, the cyclic voltammetry (CV) was used to investigate the electrochemical behaviors of U and Cr. The diffusion coefficients and formal potentials were obtained. The electrochemical properties of uranium and chromium were investigated by CV in molten NaCl-MgCl2 salt at 600°C. Tungsten rods for working and counter electrode, and Ag/AgCl for reference electrode were utilized in this experiment. UCl3 made from the chemical dissolution of U rods and CrCl2 (Sigma-Aldrich, 99.99%) were used. Diffusion coefficients (D) of U and Cr were calculated by measuring reduction peak current of U3+/U and Cr2+/Cr from CV curves and using the Berzins-Delahay equation; D (U3+/U) = 3.0×10-5 cm2s-1 and D (Cr2+/Cr) = 3.3×10-5 cm2s-1. The formal potentials were also calculated by using the reduction peak potential obtained from CV results; E0’ (U3+/U) = -1.173 V and E0’ (Cr2+/Cr) = -0.321 V. The ionization tendency was investigated by comparing each reduction peak potential. The reduction peak potential Ep,c was increasing order of Ep,c (U3+/U) < Ep,c (Cr2+/Cr) < Ep,c (U4+/U3+). It can be seen that in the presence of U4+ and Cr metals, the Cr in the alloy can dissolve into Cr2+, but in the presence of U3+ and Cr metals, the Cr in the alloy does not dissolve into Cr2+. By analyzing the CV curve, diffusion coefficients and formal standard potentials were obtained. The result of comparing reduction peak potentials suggests that the nuclear fuel using U4+ should be inhibited to prevent the selective dissolution of Cr.

The ultimate objective of deep geological repositories is to achieve complete segregation of hazardous radioactive waste from the biosphere. Thus, given the possibility of leaks in the distant future, it is crucial to evaluate the capability of clay minerals to fulfill their promising role as both engineered and natural barriers. Selenium-79, a long-lived fission product originating from uranium- 235, holds significant importance due to its high mobility resulting from the predominant anionic form of selenium. To investigate the retardation behaviors of Se(IV) in clay media by sorption, a series of batch sorption experiments were conducted. The batch samples consisted of Se(IV) ions dissolved in 0.1 M NaCl solutions, along with clay minerals including kaolinite, montmorillonite, and illite-smectite mixed layers. The pH of the samples was also varied, reflecting the shift in the predominant selenium species from selenious acid to selenite ion as the environment can shift from slightly acidic to alkaline conditions. This alteration in pH concurrently promotes the competition of hydroxide ions for Se(IV) sorption on the mineral surface as the pH increases and impedes the selective attachment of selenium. The acquired experimental data were fitted through Langmuir and Freundlich sorption isotherms. From the Freundlich fit data, the distribution coefficient values of Se(IV) for kaolinite, montmorillonite, and illite-smectite mixed layer were derived, which exhibited a clear decrease from 91, 110, 62 L/kg at a pH of 3.2 to 16, 6.3, 12 L/kg at a pH of 7.5, respectively. These values derived over the pH range provide quantitative guidance essential for the safety assessment of clay mineral barriers, contributing to a more informed site selection process for deep geological repositories.

This program aims to build a specialized and converged educational platform for the training of students in the back-end nuclear fuel cycle and cultivate integrated human resources encompassing majors, generations, and fields. To achieve this, we have established an infrastructure for integrated education and training in the radiochemistry and back-end nuclear fuel cycle and operated specialized educational courses linked with special lectures, experimental practices, and field trips. Firstly, to construct an integrated educational and training infrastructure for the back-end nuclear fuel cycle, we formed a committee of experts from both inside and outside the institution and built an advanced radiochemistry laboratory equipped with physical and chemical analysis instruments. Through a comprehensive educational program involving theory, experiments, and discussions, we have established an integrated curriculum across adjacent majors and interdisciplinary studies. We also operate short-term education and experimental training programs (e.g., summer and winter schools for the back-end nuclear fuel cycle). Secondly, the program has connected leading researchers domestically and internationally, as well as the next generation of scholars. The program offers long-term educational opportunities and internships targeting both undergraduate and graduate students. To support this, we continuously offer expert colloquiums and individual research internships. Through regular committee meetings and workshops, we focus on nurturing the integrated talents necessary for the back-end nuclear fuel cycle. Through this program, students from various fields are being trained as competent integrated human resources capable of addressing various issues in the back-end nuclear fuel cycle. It is expected that this will enable us to supply specialized technical personnel in the back-end nuclear field in line with mid-to-long-term demands.

In the nuclear fuel cycle (NFC) facilities, the failure of Heating Ventilation and Air Conditioning (HVAC) system starts with minor component failures and can escalate to affecting the entire system, ultimately resulting in radiological consequences to workers. In the field of air-conditioning and refrigerating engineering, the fault detection and diagnosis (FDD) of HVAC systems have been studied since faults occurring in improper routine operations and poor preventive maintenance of HVAC systems result in excessive energy consumption. This paper aims to provide a systematic review of existing FDD methods for HVAC systems therefore explore its potential application in nuclear field. For this goal, typical faults and FDD methods are investigated. The commonly occurring faults of HVAC are identified through various literature including publications from International Energy Agency (IEA) and American Society of Heating, Refrigerating and Air-Conditioning Engineers (ASHRAE). However, most literature does not explicitly addresses anomalies related to pressure, even though in nuclear facilities, abnormal pressure condition need to be carefully managed, particularly for maintaining radiological contamination differently within each zone. To build simulation model for FDD, the whole-building energy system modeling is needed because HVAC systems are major contributors to the whole building’s energy and thermal comfort, keeping the desired environment for occupants and other purposes. The whole-building energy modeling can be grouped into three categories: physics-based modeling (i.e., white-box models), hybrid modeling (i.e., grey-box models), and data-driven modeling (i.e., black-box models). To create a white-box FDD model, specialized tools such as EnergyPlus for modeling can be used. The EnergyPlus is open source program developed by US-DOE, and features heat balance calculation, enabling the dynamic simulation in transient state by heat balance calculation. The physics based modeling has the advantage of explaining clear cause-and-effect relationships between inputs and outputs based on heat and mass transfer equations, while creating accurate models requires time and effort. Creating a black-box FDD model requires a sufficient quantity and diverse types of operational data for machine learning. Since operation data for HVAC systems in existing nuclear cycle facilities are not fully available, so efforts to establish a monitoring system enabling the collection, storage, and management of sensor data indicating the status of HVAC systems and buildings should be prioritized. Once operational data are available, well-known machine learning methods such as linear regression, support vector machines, random forests, artificial neural networks, and recurrent neural networks (RNNs) can be used to classify and diagnose failures. The challenge with black-box models is the lack of access to failure data from operating facilities. To address this, one can consider developing black-box models using reference failure data provided by IEA or ASHRAE. Given the unavailability of operation data from the operating NFC facilities, there is a need for a short to medium-term plan for the development of a physics-based FDD model. Additionally, the development of a monitoring system to gather useful operation data is essential, which could serve both as a means to validate the physics-based model and as a potential foundation for building data-driven model in the long term.

After the major radioactivation structures (RPV, Core, SG, etc.) due to neutron irradiation from the nuclear fuel in the reactor are permanently shut down, numerous nuclides that emit alpha-rays, beta-rays, gamma-rays, etc. exist within the radioactive structures. In this study, nuclides were selected to evaluate the source term for worker exposure management (external exposure) at the time of decommissioning. The selection of nuclides was derived by sequentially considering the four steps. In the first stage, the classification of isotopes of major nuclides generated from the radiation of fission products, neutron-radiated products, coolant-induced corrosion products, and other impurities was considered as a step to select evaluation nuclides in major primary system structures. As a second step, in order to select the major radionuclides to be considered at the time of decommissioning, it is necessary to select the nuclides considering their half-life. Considering this, nuclides that were less than 5 years after permanent suspension were excluded. As a third step, since the purpose of reducing worker exposure during decommissioning is significant, nuclides that emit gamma rays when decaying were selected. As a final step, it is a material made by radiation from the fuel rod of the reactor and is often a fission product found in the event of a Severe accident at a nuclear power plant, and is excluded from the nuclide for evaluation at the time of decommissioning is excluded. The final selected Co-60 is a nuclide that emits high-energy gamma rays and was classified as a major nuclide that affects the reduction of radiation exposure to decommissioning workers. In the future, based on the nuclide selection results derived from this study, we plan to study the evaluation of worker radiation exposure from crud to decommissioning workers by deriving evaluation results of crud and radioactive source terms within the reactor core.

The seven-year research project entitled “Development of workflow for integrated 3D geological site descriptive modeling” is being carried out from 2023. This research is funded by Ministry of Trade, Industry, and Energy (MOTIE). Progress of the research is discussed here. The integrated 3D geological SDM (site descriptive model; GSDM hereafter) consists of three part; 1) three dimensional representation of geologic elements, 2) database for material properties and modeling results from SDMs of other disciplines (e.g., rock mechanics), and 3) a visualization tool for geology, material properties and modeling results. The GSDM is comparable to the GDSMs of SKB and POSIVA in its representation of geology by volume of geologic elements. However, our GSDM is different in that extra information of material properties and an extra tool for visualization is included in the GDSM. The rationale for incorporating material properties and a visualization tool into the GSDM is to expedite the development of the GSDM and SDMs of other disciplines by allowing single institution to integrate database and visualization with the GSDM. SKUA-GOCAD is used for representation of geologic surfaces for ductile and brittle shear zones, and also for surfaces for delineation of volumes of rock units. We have adopted SKUAGOCAD because the program offers powerful functions of interpolation including borehole data and geophysical prospecting. So far, we have tested the program for five different geologies, including sedimentary, high-grade metamorphic, and intrusive igneous geology. The test results are promising. Incorporation of data and modeling results for the SDMs of other disciplines is at conceptual stage. The working conceptual model involves the following steps, 1) to provide the modeler of other disciplines with surface information representing geologic elements, 2) the modeler returns not only material properties but the results of numerical analysis, and 3) incorporation of material properties and modeling results into database. Since the numerical codes in other disciplines adopt different types of formats for 3D geology, we plan to adopt the widely used FEM format prepared by Gmsh. The visualization tool will also adopt Gmsh for graphical representation of 3D geology as well as database for material properties and modeling results. When the working model of GSDM becomes available, rapid and significant progress is expected in the SDMs of other disciplines and related areas, for example, geotechnical investigation for deep geological repository.

The HADES (High-level rAdiowaste Disposal Evaluation Simulator) was developed by the Nuclear Fuel Cycle & Nonproliferation (NFC) laboratory at Seoul National University (SNU), based on the MOOSE Framework developed by the Idaho National Laboratory (INL). As an application of the MOOSE Framework, the HADES incorporates not only basic MOOSE functions, such as multi-physics analysis using Finite Element Method (FEM) and various solvers, but also additional functions for estimating the performance assessment of Deep Geological Repositories (DGR). However, since the MOOSE Framework does not have complex mesh generation and data analyzing capabilities, the HADES has been developed to incorporate these missing functions. In this study, although the Gmsh, finite element mesh generation software, and Paraview, finite element analysis software, were used, other applications can be utilized as well. The objectives of HADES are as follows: (i) assessment of the performance of a Spent Nuclear Fuel (SNF) disposal system concerning Thermal-Hydraulic-Mechanical-Chemical (THMC) aspects; (ii) Evaluation of the integrity of the Engineered Barrier System (EBS) of both general and high-efficiency design perspective; (iii) Collaboration with other researchers to evaluate the disposal system using an open-source approach. To achieve these objectives, performance assessments of the various disposal systems and BMTs (BenchMark Test), conducted as part of the DECOVALEX projects, were studied regarding TH behavior. Additionally, integrity assessments of various DGR systems based on thermal criteria were carried out. According to the results, HADES showed very reasonable results, such as evolutions and distributions of temperature and degree of saturation, when compared to validated code such as TOUGH-FLAC, ROCMAS, and OGS (OpenGeoSys). The calculated data are within the range of estimated results from existed code. Furthermore, the first version of the code, which can estimate the TH behavior, has been prepared to share the contents using Git software, a free and open-source distribution system.

For the sake of future generations, the management of radioactive waste is essential. The disposal of spent nuclear fuel (SNF) is considered an urgent challenge to ensure human safety by storing it until its radioactivity drops to a negligible level. Evaluating the safety of disposal facilities is crucial to guarantee their durability for more than 100,000 years, a period sufficient for SNF radioactivity to become ignored. Past studies have proposed various parameters for forecasting the safety of SNF disposal. Among these, radiochemistry and electrochemistry play pivotal roles in predicting the corrosion-related chemical reactions occurring within the SNF and the structural materials of disposal facilities. Our study considers an extreme scenario where the SNF canister becomes compromised, allowing underground water to infiltrate and contact the SNF. We aim to improve the corrosion mechanism and mass-balance equation compared with what Shoesmith et al. proved under the same circumstances. To enhance the comprehensibility of the chemical reactions occurring within the breached SNF canister, we have organized these reactions into eight categories: mass diffusion, alpha radiolysis, adsorption, hydrate formation, solidification, decomposition, ionization, and oxidation. After categorization, we define how each species interacts with others and calculate the rate of change in species’ concentrations resulting from these reactions. By summing up the concentration change rates of each species due to these reactions, we redefine the mass-balance equations for each species. These newly categorized equations, which have not been explained in detail previously, offer a detailed description of corrosion reactions. This comprehensive understanding allows us to evaluate the safety implications of a compromised SNF canister and the associated disposal facilities by numerically solving the mass-balance equations.

As part of the preparation of a glossary of terminologies related to the disposal of spent nuclear fuel, definitions of potentially issuable terminologies used in domestic regulations were inferred from relevant regulations or comparatively analyzed with foreign definitions. These terminologies are safety assessment and performance assessment, safety function and safety performance, disposal containers and package, isolation and containment, and so on. Their concise and easy-to-understand definitions have been proposed in order to obtain these opinions of stakeholders.

The objective of this study is development of graphite-boron composite material as a replacement for metal canisters to Improve the heat dissipation and radiation shielding performance of dry spent nuclear fuel storage system and reduce the volume of waste storage system. KEARI research team plan to use the graphite matrix manufacturing technology to pelletize the graphite matrix and adjust the content of phenolic resin binder to minimize pore formation. Specifically, we plan to adjust the ratio of natural and synthetic graphite powder and use uniaxial pressing technology to manufacture black graphite matrix with extremely high radial thermal conductivity. After optimizing the thermal conductivity of the graphite matrix, we plan to mix it with selected boron compounds, shape it, and perform sintering and purification heat treatments at high temperatures to manufacture standard composite materials.

Currently, the most promising fuel candidate for use in sodium fast reactors (SFRs) is metallic fuel, which is produced by a modified casting method in which the metallic fuel material is sequentially melted in an inert atmosphere to prevent volatilization, followed by melting in a graphite crucible, and then injection casting in a quartz (SiO2) mold to produce metallic fuel slugs. In previous studies, U-Zr metallic fuel slugs have been cast using Y2O3 reaction prevent coatings. However, U-Zr alloy-based metallic fuel slugs containing highly reactive rare earth (RE) elements are highly reactive with Y2O3-coated quartz (SiO2) molds and form a significant thickness of surface reaction layer on the surface of the metallic fuel slug. Cast parts that have reacted with nuclear fuel materials become radioactive waste. To decrease amount of radioactive waste, advanced reaction prevent material was developed. Each RE (Nd, Ce, Ln, Pr) element was placed on the reaction prevent material and thermal cycling experiments were carried out. In casting experiments with U-10wt% Zr, it was reported that Y2O3 layer has a high reaction prevent performance. Therefore, the reaction layer properties for RE elements with higher reactivity than uranium elements were evaluated. To investigate the reaction layer between RE and NdYO3, the reaction composition and phase properties as a function of RE content and location were investigated using SEM, EDS, and XRD. The results showed that NdYO3 ceramics had better antireaction performance than Y2O3.

Dry storage of nuclear fuel is compromised by threats to the cladding integrity, such as creep and hydride reorientation. To predict these phenomena, spent fuel simulation codes have been developed. In spent fuel simulation, temperature information is the most influential factor for creep and hydride formation. Traditional fuel simulation codes required a user-defined temperature history input which is given by separate thermal analysis. Moreover, geometric changes in nuclear fuel, such as creep, can alter the cask’s internal subchannels, thereby changing the thermal analysis. This necessitates the development of a coupled thermal and nuclear fuel analysis code. In this study, we integrated the 2D FDM nuclear fuel code GIFT developed at SNU with COBRA -SFS. Using this, we analyzed spent nuclear stored in TN-24P dry storage cask over several decades and identified conditions posing threats due to phenomena like creep and hydrogen reorientation, represented by the burnup and peak cladding temperature at the start of dry storage. We also investigated the safety zone of spent nuclear fuel based on burnup and wet storage duration using decay heat.