One of the options for spent fuel dry storage systems is to store them in canisters using metal or concrete casks close to shore. The interaction between the austenitic stainless steel and the chloride atmosphere generated from the sea creates detrimental conditions leading to chloride induced stress corrosion cracking (CISCC) in the canister. The corrosion integrity of the canister in the concrete cask is very important because the canister is sealed and used for a long period of time. A canister made of austenitic stainless steel has several welding lines on the wall and lid, which are generated during the welding process and have high residual tensile stress. The interaction between the austenitic stainless steel and the chloride atmosphere generated from the sea creates detrimental conditions leading to chloride induced stress corrosion cracking (CISCC) in the canister. The corrosion integrity of the canister in the concrete cask is very important because the canister is sealed and used for a long period of time. In order to evaluate such soundness, an accelerated test capable of simulating the CISCC crack propagation phenomenon of the canister weld is required. In this study, a test device for performing the CISCC simulation test was constructed using the DCPD device. The direct current potential drop (DCPD) technique is a widely accepted method of monitoring crack initiation and growth in controlled laboratory tests. Total 10 types of test specimens with varying welds, base metal, salinity and stress were selected and a sealed chamber with DCPD test apparatus were designed and constructed to evaluate them. The chamber for CISCC simulation was manufactured as a sealed with a solution containing 10% MgCl2. A 1/2 CT specimen with precracked pre-cracks was loaded into the prepared container, and gauze was attached from the bottom for smooth delivery to the specimen to facilitate penetration of chloride. After the test, the measured DCPD data were correlated with Electron Back scattered Diffraction (EBSD) data.

An austenitic stainless steel canister functions as a containment barrier for spent nuclear fuel and radioactive materials. The canister on the spent fuel storage system near the coastal area has several welding lines in the wall and lid, which have high residual tensile stresses after welding procedure. Interaction between austenitic stainless steel and chloride environment from a sea forms a detrimental condition causing chloride induced stress corrosion cracking (CISCC) in the canister. The South Korea is concerned with the dry storage of high-level spent nuclear fuel and radioactive wastes to be built on the site of a nuclear power plant. The importance of aging management has recently emerged for mitigating CISCC of dry storage canisters. When a corrosive pit is created by a localized corrosion in a sea water atmosphere, it initiates and grows as CISCC crack. Surface stress improvement works by inducing plastic strain which results in elastic relaxation that generates residual compressive stress. Surface stress improvement methods such as roller burnishing process can effectively mitigate the potential for CISCC of the canister external surfaces. The generation of compressive stress layer can inhibit the transition to cracking initiation. In this study, a flat roller burnishing process was applied as a prevention technology to CISCC of stainless steel canisters. Roller burnishing process parameters have been selected for 1:3 scale canister model having a diameter of 600 mm, a length of 1,000 mm and a thickness of 10 mm on the basis of the burnishing conditions available to control residual tensile stress of austenitic stainless steel plate specimens. The surface roughness of the scaled canister model was investigated using a surface roughness measurement equipment after roller burnishing treatment. The surface residual stresses of the scaled canister model were measured by a hole drilling contour method attached with strain gauge. The burnishing test results showed that the surface roughness of the scaled canister model was considerably improved with flat rollers having the tip width of 4 mm. The surface of the scaled canister model had significant residual compressive stress after burnishing treatment. The roller burnished canister with good surface roughness could reduce the number of crack initiation sites and the residual compressive stress formed on the welded surface might prevent the crack initiation by reducing tensile residual stress in the weld zone, finally leads to CISCC resistance.

Safe management of spent nuclear fuel (SNF) is a key issue to determine sustainability of current light water reactor (LWR) fleet. However, none of the countries are actually conducting permanent disposal of SNFs yet. Instead, most countries are pursuing interim storage of spent nuclear fuels in dry cask storage system (DCSS). These dry casks are usually made of stainlesssteels for resistibility against cracking and corrosion, which can be occurred over a long-term storage period. Nevertheless, some corrosion called Chloride-Induced Stress Corrosion Cracking (CISCC) can arise in certain conditions, exacerbating the lifetime of dry casks. CISCC can occur if the three conditions are satisfied simultaneously: (i) residual tensile stress, (ii) material sensitization, and (iii) chloride-rich environment. A residual tensile stress is developed by the two processes. One is the bending process of stainless-steel plates into a cylindrical shape, and the other is the welding process, which can incur solidification-induced stress. These stresses provide a driving force of pit-to-crack transition. Around the fusion weld areas, chromium is precipitated at the grain boundary as a carbide form while it depletes chromium around it, leading to material susceptible to pitting corrosion. It is called sensitization. Finally, coastal regions, where nuclear power plants usually operate, tend to have a higher relative humidity and more chloride concentration compared to inland areas. This high humidity and chloride ion concentration initiate pitting corrosion on the surface of stainless-steels. To prevent initiation of CISCC, at least one of the three conditions should be removed. For this, several surface engineering techniques are under investigation. One of the most promising approaches is surface peening method, which is the process that impacts the surface of materials with media (e.g., small pins, balls, laser pulse). By this impact, plastic deformation on the surface occurs with compressive stress that counteracts with pre-existing residual tensile stress, so this approach can prevent pit-to-crack transition of stainless-steels. Also, cold spray deposition can prevent CISCC. Cold spray deposition is a method of spraying fine metal powder to a substrate by accelerating them to supersonic velocity with propellant gas. As a result, a thin coating composed of the feedstock powders can protect the substrate from outer corrosive environments. In addition, the impact of the feedstock powder on the substrate during the process provides compressive stress, similar to the peening method.

One of the options for spent fuel dry storage systems is to store them in canisters using metal or concrete casks close to shore. The interaction between the austenitic stainless steel and the chloride atmosphere generated from the sea creates detrimental conditions leading to chloride induced stress corrosion cracking (CISCC) in the canister. The corrosion integrity of the canister in the concrete cask is very important because the canister is sealed and used for a long period of time. A canister made of austenitic stainless steel has several welding lines on the wall and lid, which are generated during the welding process and have high residual tensile stress. The interaction between the austenitic stainless steel and the chloride atmosphere generated from the sea creates detrimental conditions leading to chloride induced stress corrosion cracking (CISCC) in the canister. The corrosion integrity of the canister in the concrete cask is very important because the canister is sealed and used for a long period of time. In order to evaluate such soundness, an accelerated test capable of simulating the CISCC crack propagation phenomenon of the canister weld is required. In this study, a test device for performing the CISCC simulation test was constructed using the DCPD device. The direct current potential drop (DCPD) technique is a widely accepted method of monitoring crack initiation and growth in controlled laboratory tests. In its simplest form it involves passing a constant current through the test piece and accurately measuring the electrical potential across the crack plane, and it is a suitable device to measure crack growth in real time. The requirements for the CISCC simulation test selected based on the literature search results include test material 316 L, load range 1.75YS, positive displacement load, and 7% MgCl2 concentration. In order to smoothly evaluate these various conditions, it was determined that it is advantageous to collect crack length data in real time using a DCPD device, rather than receiving and analyzing specimens maintained for a certain time in the chamber. Therefore, in this study, 4 types of test conditions in real time was built, and data collection on crack propagation could be performed in real time by using it.

The spent fuel storage canister is generally made of austenitic stainless-steel and has the role of an important barrier to encapsulate spent fuels and radioactive materials. Canister near coastal area has welding lines, which have high residual tensile stresses after welding process. Interaction between austenitic stainless steel and chloride environment forms detrimental condition causing chloride induced stress corrosion cracking (CISCC) in canister. Reducing or eliminating tensile stress on canister can significantly decrease probability of crack initiation. Surface stress improvement works by inducing plastic strain which results in elastic relaxation that generates compressive stresses. Surface stress improvement methods such as burnishing process can effectively prevent for CISCC of canister surfaces. In this study, burnishing treatment has been evaluated to control residual tensile stress practically applicable to atmospheric CISCC for aging management of steel canisters. Burnishing process was selected as a prevention technology to CISCC of stainless steel canisters to improve resistance of CISCC through enhancement of surface roughness and generation of compressive residual stress. SUS 316 SAW (Submerged Arc Welding) specimens were burnished with flat roller and round roller after manufactured and assembled on CNC machine using base plate. The burnishing test results showed that the surface roughness of SUS 316 SAW welded specimens after roller burnishing of pass No. 5 was improved with 85% with flat roller and 93% with round roller, individually. Surface roughness showed the best state when burnished at pressure of 115 kgf, feeding rate of 40 m/stroke and pass No. of 5 turns with round roller. The surface of SUS 316 SAW welded specimens had much high residual compressive stress than yield stress of SUS 316 materials with roller burnishing treatment, independently of kinds of roller. The surface of the welded specimen by round roller burnishing showed smaller compressive stress and deeper stress region than in the surface of flat round roller burnishing. The roller burnished canister with good surface roughness could reduce the number of crack initiation sites and the high residual compressive stress formed on the welded surface might prevent the crack initiation by reducing or eliminating tensile residual stress in the weld zone, finally leads to excellent CISCC resistance. The crack growth behavior of SUS 316 welded specimens will need to investigate to evaluate the corrosion integrity of the canister materials under chloride atmosphere according to burnishing treatment.

The spent fuel dry storage canister is generally made of austenitic stainless-steel and has the role of an important barrier to encapsulate spent fuels and radioactive materials. The canister on the dry storage system has several welding lines in the wall and lid, which have high residual tensile stresses after welding procedure. Interaction between stainless steel and chloride environment from a sea results in an aged-related degradation phenomenon causing chloride induced stress corrosion cracking (CISCC) in the dry storage system. A pending issue to the interim storage of spent fuel awaiting repository disposal is their susceptibility to CISCC of stainless steel canisters. The available mitigation technology should be studied sufficiently to prevent the degradation phenomenon. This paper assesses stress-based mitigation to control residual tensile stress practically applicable to the atmospheric CISCC for the aging management of the stainless steel canisters. There are major components, that is, elevated tensile stress, susceptible material and corrosive environment that must be simultaneously present for CISCC degradation to occur. Surface stress improvement can effectively mitigate the potential for CISCC of the canister external surfaces. The potential deleterious effect of the additional work is negated by the presence of compressive residual stress, which removes the tensile stress needed for CISCC to occur. Surface stress improvement methods such as shock-based peening, shot peening and low plasticity burnishing can be applied for surface stress improvement of the canisters. Stress relaxation processes and advanced welding methods such as laser beam welding and friction stir welding can be also available to mitigate the susceptibility to CISCC. As the result assessing the stress-based mitigation technologies, promising candidate methods could be selected to reduce the residual tensile stresses and to control an aged-related degradation condition causing CISCC in the spent fuel dry storage canister.

One of the options for spent fuel dry storage systems is to store them in canisters using metal or concrete casks close to shore. The interaction between the austenitic stainless steel and the chloride atmosphere generated from the sea creates detrimental conditions leading to chloride induced stress corrosion cracking (CISCC) in the canister. The corrosion integrity of the canister in the concrete cask is very important because the canister is sealed and used for a long period of time. A canister made of austenitic stainless steel has several welding lines on the wall and lid, which are generated during the welding process and have high residual tensile stress. The interaction between the austenitic stainless steel and the chloride atmosphere generated from the sea creates detrimental conditions leading to chloride induced stress corrosion cracking (CISCC) in the canister. The corrosion integrity of the canister in the concrete cask is very important because the canister is sealed and used for a long period of time. In order to evaluate such soundness, an accelerated test capable of simulating the CISCC crack propagation phenomenon of the canister weld is required. In this study, the current status of CISCC simulation tests performed around the world to build a test equipment for the CISCC simulation accelerated test is investigated, and based on this, the test conditions suitable for the simulation test and specimen specifications are selected to establish the test equipment. The settings were performed. In consideration of the set device requirements, the essential limiting conditions for device manufacturing were derived, and detailed design was performed to satisfy them, and it was used to build a CISCC simulation test device for welding parts. The CISCC simulation test equipment requires performance to maintain the test temperature range of room temperature to 80°C and humidity 35 to 95%. In addition, it should be manufactured in consideration of humidity and temperature maintenance in the chamber of the complex corrosion tester, measures to prevent leakage of the connection part between the chamber and the salt water tank of the complex corrosion tester, and measures to supply stable salt water and maintain temperature in the salt water tank. Based on these contents, detailed specifications and design contents of the chloride stress corrosion cracking simulation test apparatus were presented in this study.

국내의 사용후핵연료가 증가함에 따라 사용후핵연료 저장조는 곧 포화가 될 것으로 예상된다. 따라서 사용후핵연료 건식저장 운영 및 관리 방안에 대해 연구하는 것은 매우 중요하다. 미국에서는 오랜 기간 건식저장을 운영해왔으며 이를 바탕으로 사용후핵연료 건식저장 운영 및 관리 방안에 대해 많은 연구가 수행되고 있다. 그러나 우리나라에서는 경수로 사용후핵연료 건식저장 경험이 없으며 관련 관리방안 및 구체적인 기준이 매우 부족한 현실이다. 건식저장기간 동안 주요한 이슈중의 하나는 건식저장용기 열화현상이며 대표적으로 응력부식균열에 의한 부식현상이 있다. 미국에서는 U.S. DOE, U.S. NRC, 그리고 EPRI 주관 아래 건식저장 캐니스터에서의 염화물 응력부식균열에 관한 많은 연구들을 수행하고 있다. 또한 건식저장 캐니스터의 염화물 응력부식균열 현상을 설명하기 위해 SNL에서는 확률론적 응력부식균열 모델을 제시하였다. 본 논문에 서는 SNL에서 제시한 확률론적 응력부식균열 모델을 검토하였으며 모델에 제시된 주요인자들을 세세하게 분석하였다. 본 논문은 우리나라에서 스테인리스 스틸로 제작된 캐니스터를 경수로 사용후핵연료 건식저장으로 이용할 경우, 건식저장 운영 및 관리 방안을 구축하는 대에 좋은 참고문헌이 될 것이라 사료된다.

For the aerospace structural application of high-strength 2xxx series aluminum alloys, stress corrosion cracking(SCC) behavior in aggressive environments needs to be well understood. In this study, the SCC sensitivities of 2024- T62, 2124-T851 and 2050-T84 alloys in a 3.5% NaCl solution are measured using a constant load testing method without polarization and a slow strain rate test(SSRT) method at a strain rate of 10-6 /sec under a cathodic applied potential. When the specimens are exposed to a 3.5% NaCl solution under a constant load for 10 days, the decrease in tensile ductility is negligible for 2124-T851 and 2050-T84 specimens, proving that T8 heat treatment is beneficial in improving the SCC resistance of 2xxx series aluminum alloys. The specimens are also susceptible to SCC in a hydrogen-generating environment at a slow strain rate of 10−6/sec in a 3.5% NaCl solution under a cathodic applied potential. Regardless of the test method, low impurity 2124-T851 and high Cu/Mg ratio 2050-T84 alloys are found to have relatively lower SCC sensitivity than 2024-T62. The SCC behavior of 2xxx series aluminum alloys in the 3.5% NaCl solution is discussed based on fractographic and micrographic observations.

The likelihood of failure for the stress corrosion cracking (SCC) of caustic cracking, which affect to a risk of facilities, was analyzed through the risk based-inspection using API-581 BRD. We found that SCC of the caustic cracking was occurred above 5 % NaOH concentration, and the technical module subfactor (TMSF) was maximized for above 50 % concentration. The heat traced and monitoring were not sensitive to the TMSF with NaOH concentration and temperature. But the steam out was more of less affect minimum value of the TMSF. Also, the inspection number, the inspection effectiveness, and the year since inspection were very sensitive to the TMSF with NaOH concentration and temperature. Therefore, the plan of next inspection will be established with compositively considering those at once.

The stress corrosion cracking (SCC) susceptibility of Alloy 600 MA, Alloy 600 TT, Alloy 800, and Alloy 690 TT were investigated in a deaerated 0.01 M solution of sodium tetrathionate using reverse u-bend test samples at . The results showed that SCC occurred in all alloys, excluding Alloy 690 TT. The SCC susceptibility decreased with an increase in the chromium content of the alloys. The results of the deposits and spectra taken from an energy dispersive X-ray system confirmed the existence of a reduced sulfur causing SCC.

Cavitation can occur in pipes when liquid is moving at high velocity, especially at pittings where the smooth bore of the pipe is interrupted. The effect is usually to produce pitting on the downstream side of the turbulence. However, stress corrosion cracking behavior under cavitation erosion-corrosion was neatly unknown. In this study, therefore, some were investigated of stress corrosion cracking behavior, others were stress corrosion cracking behavior under cavitation erosion-corrosion of water injection. And datas obtained as the results of experiment were compared between the two. Mainresult obtained are as follows: 1) Stress corrosion cracking growth rate of heat affected zone under cavitation erosion-corrosion becomes most rapid, and stress intensity factor K1becomes most high. 2) Stress corrosion cracking growth mechanism by cavitation erosion-corrosion is judgement on the strength of the film rupture model and the tunnel model. 3) The range of potential as passivation of heat affected zone is less noble than that of base metal, and that value is smaller. 4) Corrosion potential under cavitation erosion-corrosion in loaded stress is less noble than that of stress corrosion, and corrosion current density is higher.

The effect of fluid flow on corrosion and erosion-corrosion of metal is a well-recognized phenomenon in pipelines and machinery equipment, and so on. Not only are fluid hydrodynamics important, but also the corrosiveness of the process or production stream affects the corrosion system. Recent research demonstrates that it is possible to erosion-corrosion(E/C) phenomena in terms of hydrodynamics, electrochemical corrosion kinetics and film growth/removal phenomena. Stress corrosion cracking behavior under cavitation erosion-corrosion of mild steel(SS41) was investigated of base metal and weldment under loaded stress. Main result obtained are as follows : 1) The cavitation erosion sensitivity of base metal affected weight loss is more susceptive than heat affected zone, 2) The corrosion sensitivity affected weight loss of welding heat cycle is less susceptive on stress corrosion under cavitation erosion-corrosion than stress corrosion.

320˚C, 40%NaOH 용액의 autoclave에서 약 300wppm의 탄소를 함유하고 있는 15Cr-9Fe-balanced Ni 합금 판상시편에 대해 응력부식 저항성을 조사하였다. 부식시편은 700˚C, 100시간 동안의 열처리로 합금내부에 석출될 수 있는 가능한 한 많은 양의 크롬계 탄화물을 석출시킨 후, 다시 재용해에 의해 크롬계 탄화물의 형태를 조절하는 800˚C-950˚C범위의 최종열처리를 시행하고 급냉시킨 다음 U-자형으로 응력을 가하여 준비되었다. 최종열처리 온도가 올라감에 따라 시편들의 입계응력부식균열(IGSCC ) 전파속도는 900˚C까지는 거의 직선적으로 증가하다가 950˚C에서는 700˚C에서 얻은 값보다도 더 낮게 감소하였다. 즉, 크롬계 탄화물이 재용해되어 그 밀도가 감소함에 따라 IGSCC저항성이 감소하다가 완전히 재용해된 950˚C 열처리 조건에서 오히겨 가장 큰 IGSCC 저항성을 나타내었다. 이와같은 최조열처리 온도에 따른 니켈계 합금 600의 부식거동은 입계에 존재하는 크롬계탄화물의 형태변화 때문이 아니라 입계에서 탄소-크롬계 탄화물-크롬간의 상평형에 의해 이루어지는 탄소의 입계편석량이 크롬계탄화물이 존재할 때에는 열처리 온도에 따라 증가하다가 그것이 완전히 재용해 되었을 때 가장 낮아지기 때문인 것으로 생각된다.

가압 경수로형 원전에 사용되는 Alloy 600 증기발생기 전열관재료의 입계응력부식균열 거동에 미치는 냉간변형의 영향을 1차 냉각수 모사조건에서 정속인장시험방법으로 조사하였다. 인장 냉간변형은 응력부식균열을 크게 가속화 시키지는 않았으며 변형량이 25%이상인 경우에는 응력부식균열이 발생하지 않았다. 이 현상은 냉간 변형량 및 형태에 따른 미소변형 및 응력의 불균질성에 영향을 받는 것으로 사려되며 응력의 크기는 직접적인 영향을 주지 않는 것으로 보인다. 국부적인 큰 응력구배가 존재하는 경우 균열의생성 및 성장이 현저히 가속화되었는데 이는 원전 1차측 응력부식균열 기구가 응력구배에 의존하는 과정과 연관되어 있다는 증거이다. Hump 시편을 이용한 정속인장시험방법은 짧은 실험기간내에 원전 1차측 응력부식균열 특성을 평가할 수 있는 방법이었다.