After analyzing the correlation between air pollution and visibility, TSP and NO2 is responsible for poor visibility in Pusan. After analyzing the correlation between meteorological factors and visibility, general pattern of humidity has clear negative correlation. The variation of wind speed has a positive correlation. In order to investigate the cause of poor visibility in Pusan area, the Andersen sampler and PM-2.5 are used to collect and analyze aerosol. This study was carried out to monitor the visibility using Forward scattering meter and to find out the characteristics and the cause of good visibility case and poor visibility case by measuring and analyzing a variety of parameters, such as particle size distributions, chemical compositions, and meteorological conditions in Pusan. According to the analysis of intensive sampling, NO3-, NH4+ ion concentration increased together with the mass concentration around 0.5∼2.5㎛ approximately during the case of poor visibility. NH4NO3, NH4Cl, and NaCl were thought to be the major components of fine particles.