The lightweight and high strength characteristics of aluminum alloy materials make them have promising prospects in the field of construction engineering. This paper primarily focuses on aluminum alloy materials. Aluminum alloy was combined with concrete, wood and carbon fiber reinforced plastic (CFRP) cloth to create a composite column. The axial compression test was then conducted to understand the mechanical properties of different composite structures. It was found that the pure aluminum tube exhibited poor performance in the axial compression test, with an ultimate load of only 302.56 kN. However, the performance of the various composite columns showed varying degrees of improvement. With the increase of the load, the displacement and strain of each specimen rapidly increased, and after reaching the ultimate load, both load and strain gradually decreased. In comparison, the aluminum alloy-concrete composite column performed better than the aluminum alloy-wood composite column, while the aluminum alloy-wood-CFRP cloth composite column demonstrated superior performance. These results highlight excellent performance potential for aluminum alloy-wood-CFRP composite columns in practical applications.

Background: Problem-based learning (PBL) is presented as a superior teaching method compared to existing lecture-based learning. Objectives: To analyzed the effectiveness of creative problem-solving competency, class participation, and self-efficacy in physical therapy students after PBL. Design: Questionnaire design. Methods: This study involved 29 physical therapy students and analyzed changes in their creative problem-solving competency, class participation, and self-efficacy and the correlations between these measurement variables before and after PBL on the “Therapeutic Exercise & Practice” subject. Results: PBL in the musculoskeletal exercise therapy-related subject significantly improved class participation and self-efficacy (P<.05) compared to conventional lecture-based learning, but there was no significant difference in creative problem-solving competency. There was also a positive correlation between a higher level of class participation and higher self-efficacy (P<.05). Conclusions: PBL in the “Therapeutic Exercise & Practice” subject in the Department of Physical Therapy can be an effective educational strategy to increase students’ class participation and self-efficacy. Accordingly, instructors in this department should systematically construct the design of PBL curricula to improve the quality of educational content.

Aurantii Fructus Immature (AFI) and Aurantii Fructus (AF) are two important traditional Chinese herbs. As the harvesting time varies, the medicinal value of the plants is not uniform. Consequently, it has been difficult to quickly recognize them within the realm of traditional Chinese medicine. Separation and detection technologies are employed in combination to create fingerprints for identification. We proposed the utilization of graphene-assisted electrochemical fingerprint technology to acquire fingerprints of two varieties of medicinal materials. Simultaneously, we also obtained their fingerprints through HPLC. Two fingerprint recognition technologies were compared for their effectiveness. The findings demonstrate that the signals obtained through electrochemical fingerprinting have a higher recognition rate.

In recent years, supercapacitors have attracted extensive attention due to their advantages such as fast charge and discharge rate, high power density and long cycle life. Because of its unique porous structure and excellent electrochemical properties, heteroatom-doped porous carbon (HPC) is deemed as a promising electrode material for supercapacitors. However, it is a great challenge to synthesize electrode materials with large surface area, ultra-high porosity and good electrochemical performance. In this work, two-dimensional conjugated microporous polymers (CMPs) containing ketones were synthesized by a simple one-step coupling reaction and used as carbon precursors. A series of samples (CMP-Ts) were prepared with the procedures of coupling reaction and carbonization. The optimized carbon material has high specific surface area (up to 2229.85 m2 g− 1), porous structure, high specific capacitance (375 F g− 1 at 0.5 A g− 1), and good cycling stability (capacitance retention of 98.8% after 1000 cycles at 5 A g− 1). Further, the supercapacitor has an energy density of 28.8 Wh kg− 1 at a power density of 5000 W kg− 1. This work lays a foundation for the preparation of carbon materials using microporous polymer as a precursor system, provides a new way of thinking, and demonstrates a great potential of high-performance supercapacitors.

This study presents the synthesis, characterization, and utilization of marine macroalgae-derived bio-carbon catalysts (BC and KOH-AC) for the efficient conversion of waste cooking oil (WCO) into biodiesel. The biochar (BC) was produced through slow pyrolysis of macroalgal biomass, which was subsequently activated with potassium hydroxide (KOH) to produce a KOH-modified activated carbon (KOH-AC) catalyst. Advanced characterization techniques, including SEM, EDX, XRD, FTIR, and TGA, were used to examine the physicochemical characteristics of the catalysts. The synthesized catalysts were utilized to produce biodiesel from WCO, and the results revealed that the highest biodiesel yields, 98.96%, and 47.54%, were obtained using KOH-AC and BC catalysts, respectively, under optimal reaction conditions of 66 °C temperature, 12.3 M/O molar ratio, 130 min time, and 3.08 wt.% catalyst loading via RSM optimization. The kinetic and thermodynamic parameters, such as k, Ea, ΔH, ΔS, and ΔG, were determined to be 0.0346 min− 1, 43.31 kJ mol− 1, 38.98 kJ mol− 1, − 158.38 J K− 1 mol− 1, and 92.58 kJ mol− 1, respectively. The KOH-AC catalyst was recycled up to five times, with a significant biodiesel yield of 80.37%. The fuel properties of the biodiesel met ASTM (D6751) specifications, ensuring that it has excellent fuel characteristics and can be used as an alternative fuel.

Decabromodiphenyl ether (BDE209) is a persistent aromatic compound widely associated with environmental pollutants. Given its persistence and possible bioaccumulation, exploring a feasible technique to eradicate BDE209 efficiently is critical for today’s environmentally sustainable societies. Herein, an advanced nanocomposite is elaborately constructed, in which a large number of titanium dioxide ( TiO2) nanoparticles are anchored uniformly on two-dimensional graphene oxide (GO) nanosheets ( TiO2/GO) via a modified Hummer’s method and subsequent solvothermal treatment to achieve efficient photocatalytic degradation BDE209. The obtained TiO2/ GO photocatalyst has excellent photocatalytic due to the intense coupling between conductive GO nanosheets and TiO2 nanoparticles. Under the optimal photocatalytic degradation test conditions, the degradation efficiency of BDE209 is more than 90%. In addition, this study also provides an efficient route for designing highly active catalytic materials.

AI recommendation service is adopted in consumption consulting such as high-tech and fashion consumption (Thapliyal & Ahuj, 2021). Now, for high-tech and fashion products, the advance selling strategy is widely adopted. Thus, this study targets to detective the consumers’ preference toward AI agents comparing human agents under advance selling and spot selling. The independent variable of this study is consumption type: Pre-sale Products vs. Spot Products. Pre-sale Products are quite popular currently, especially technological products. Construal-level theory (CLT) offers a valuable framework to explain the mechanisms that trigger evaluations, predictions, and behaviors by linking the degree of mental abstraction (the construal level) to psychological distance (Trope & Liberman, 2000; 2003; 2010). Four dimensions including temporal, special, social, and probability distance are argued to present the psychological distance (Trope et al., 2007). Liberman et al. (2022) discuss the time distance and argue the distant-future events are represented in a more abstract, structured, high-level manner than near-future events. Kim & Duhachek (2020) draw on a dimension of persuasion by AI agents to posit that AI agents are perceived as low-construal agents because of the fact that people hold a lay theory that AI agents do not have superordinate goals and cannot learn from their experiences or possess consciousness like humans do. Consequently, they find that individuals perceive greater appropriateness and are more persuaded when an AI agent’s persuasive messages highlight low-construal as opposed to high-construal features. Moreover, consumers prefer abstract information related to a certain product rather than concrete information when a purchase is to take place in the distant future or when construal levels are high (Hernandez et al., 2015). Thus, this research hypothesizes: When consumers buy pre-sale products (vs. spot products), human agents will be the more favorable service provider than AI agents since the consumer is under a high level of construal. This research proposes to adopt a 2 (Advance Selling vs. Spot Selling) x 2 (Short Psychological Distance vs. Far Psychological Distance) x 2 (AI Agents vs. Human Agents) between groups experimental study to test the main effects and mechanism (H1). Furthermore, this study would identify the key moderating effects to discuss the boundary effects of the mechanism for establishing marketing strategies with AI services for managers.

The research aims to estimate the role of SMAs implementation in impacting event image, commemorative product perceived value, and TBIs in the context of sports tourism events. Additionally, this study analyzes the effects of perceived value and event image on TBIs. This article focuses on the following research questions: (1) What is the SMAs' influence on TBIs? (2) What is the impact of SMAs on event image and commemorative product perceived value? (3) What is the role of event image and product perceived value in the relationships between SMAs and TBIs in the sports tourism context? The data collection was done during the Beijing Winter Olympic Games to address the research goals. The study examines the data from 315 valid questionnaires from tourists in the Chinese market by SEM (structural equation modeling).

This study investigated the key factors that explain the continuous usage intention of mobile payment users in the post COVID-19 pandemic era. Based on the health belief model (HBM) and communication privacy management (CPM) theory, this study examined how the five constructs of HBM influence mobile payments continuous usage intention through perceived privacy risk and perceived security. It also investigated the moderating role of perceived privacy awareness on the relationship between perceived privacy risk and continuous usage intention as well as the moderating role of information sensitivity on the relationship between perceived security and continuous usage intention.

With the popularity of live streaming commerce, the characteristics of streamers and products subtly influence consumer behavior through visual live streaming form. Based on dual-process theory, this paper develops a comprehensive theoretical model to examine how consumer perceived streamer characteristics and product characteristics influence streamer attractiveness and product attractiveness, and explore how consumer behavior inertia is affected by streamer attractiveness and product attractiveness. An online survey consisting of 300 participants was recruited to empirically examine the proposed research model. The results indicated that consumer perceived streamer characteristics and product characteristics are important factors affecting the streamer attractiveness and product attractiveness, which in turn positively affect consumer’s shopping experience memory, which further influence consumer behavior inertia. In addition, the moderating effects of mindfulness are also examined.

An all-perovskite oxide heterostructure composed of SrSnO3/Nb-doped SrTiO3 was fabricated using the pulsed laser deposition method. In-plane and out-of-plane structural characterization of the fabricated films were analyzed by x-ray diffraction with θ-2θ scans and φ scans. X-ray photoelectron spectroscopy measurement was performed to check the film’s composition. The electrical transport characteristic of the heterostructure was determined by applying a pulsed dc bias across the interface. Unusual transport properties of the interface between the SrSnO3 and Nb-doped SrTiO3 were investigated at temperatures from 100 to 300 K. A diodelike rectifying behavior was observed in the temperature-dependent current-voltage (IV) measurements. The forward current showed the typical IV characteristics of p-n junctions or Schottky diodes, and were perfectly fitted using the thermionic emission model. Two regions with different transport mechanism were detected, and the boundary curve was expressed by ln I = -1.28V - 13. Under reverse bias, however, the temperature- dependent IV curves revealed an unusual increase in the reverse-bias current with decreasing temperature, indicating tunneling effects at the interface. The Poole-Frenkel emission was used to explain this electrical transport mechanism under the reverse voltages.

This paper probes the elements of theoretical necessity, starting with the word ruo (若) in Duan Yucai’s Shuo Wen Jie Zi Zhu (段玉裁《說文解字註》). From the prospective of theoretical methods of “Ruo (若) ,” the theoretical necessity of “Ruo (若) ,” the exegesis functions of “Ruo (若) ” and different intonations with different modal particles, the author conducted multi-level and multi-dimensional analysis on “Ruo (若) ” in Duan Yucai’s Shuo Wen Jie Zi Zhu (段玉裁《說文解 字註》) so as to explore the concepts of theoretical necessity from Duan Yucai.

Core–shell ZIFs wrapped CuO hybrid materials (CuO@ZIF-67(Co)) were designed, synthesized, characterized, and employed as peroxymonosulfate (PMS) activators to degrade methylene blue (MB). It demonstrated outstanding catalytic activity on account of the unique structure and the synergistic effect between CuO cores and ZIF-67(Co) shells, resulting in complete degradation of MB (10 mg/L) in 1 min. Reactive oxygen species (ROSs) research showed that both SO4 − and OH were responsible for the removal of MB. The synergistic activation mechanisms in the CuO@ZIF-67(Co)/PMS system were investigated, which mainly involved the effective electron transfer of CuO and ZIF-67(Co) for accelerating the cycle of CuII/ CuI and CoIII/ CoII. This study broadens the application of MOF-derived materials for wastewater treatment.

Graphite felt is a felt-like porous material made of high-temperature carbonized polymers. It is widely used in electrode materials because of its good temperature resistance, corrosion resistance, large surface area and excellent electrical conductivity. In this paper, the surface functional group modification is of graphite felt electrodes (mainly nitrogen doping modification, nitrogen–sulfur or nitrogen–boron co-doping modification) and surface catalytic modification (metal/ion surface modification and metal oxide surface modification as Main). There are two main methods and research progresses to improve the performance of graphite felt electrodes, and the comprehensive performance of surface functional group-modified graphite felt electrodes and surface catalytically modified graphite felt electrodes are compared respectively. The results show that both surface functional group modification and surface catalytic modification can improve the comprehensive performance of graphite felt electrodes. In this paper, the future development direction of graphite felt activation modification is also prospected.

Background: Height is an important factor in determining a person’s appearance, so people often wear height increase elevator shoes insoles (HIESI) or high heels to make themselves look taller. However, high heels often act as a risk factor for musculoskeletal diseases. Objectives: To investigated how muscle tone and muscle stiffness in the lumbar region of young adult men varied according to the height of the HIESI, and analyzed the correlation. Design: Non-randomised trial. Methods: Muscle tone and muscle stiffness in the upper and lower lumbar regions of 20 healthy young adult men in an upright standing position were measured as the subjects wore no insoles and 2 cm, 3 cm, and 4 cm insoles. Results: Muscle tone and muscle stiffness in the lumbar region did not show a significant change according to the increased height of the HIESI. However, a positive correlation was observed when the subjects wore 4 cm HIESI, as there was a significant increase (P<.05) in muscle tone and stiffness in the left side of the upper lumbar region and in the right side of the lower lumbar region. Conclusion: Wearing HIESI for short periods of time in the static standing position did not cause a change in muscle tone and muscle stiffness in the lumbar region. However, wearing 4 cm HIESI demonstrated a correlation of increased muscle tone and stiffness in the upper and lower lumbar regions in an asymmetric manner.

백묘는 중국 전통 회화에서 단색 묵선으로 꽃을 묘사하는 기 법으로 선이 간결하고 간결하며 이미지가 생동감 있는 것이 특 징이다.화훼 스케치의 선화는 독자적인 미학을 나타낸다.그것은 제재에서 화조화의 범주에 속하며 이 범주의 기초이기도 하다. 시기에 따라 화훼 스케치의 선화는 서로 다른 형식적 특징과 정신적 의미를 나타낸다.예술가들은 화훼 스케치 선도의 내용 과 형식의 통일된 아름다움을 끊임없이 탐구한다.현재 세계 문 화 구조의 배경에서 중국과 서양 문화의 교류와 융합은 새로운 단계에 들어섰다.문화일군들은 세계문화에 대해 자신의 견해를 갖고있고 민족문화에 대해 책임감을 갖고있다. 그들은 반드시 우수한 전통문화에 대해 신심을 가지게 될것이며 또 그것을 부 흥시킬 책임도 있게 될것이다. 어떻게 전통적인 화훼 스케치 선도의 도식을 현대 표현과 심 미적 정취에 융합시켜 오늘날 사람들의 정신적 수요를 만족시 킬 수 있는지 우리가 연구하고 탐색할 필요가 있다.

This article provides an analyses the implications of China’s constitutionally proclaimed notion of “Community of Shared Future for Mankind” (CSFM), which reveals the stance of the PRC party in promoting so-called “Chinese wisdom” and a “Chinese solution” to address common issues in global governance and in pursuing China’s global leadership in President Xi Jinping’s “New Era.” The author explores the possibility for China and the West of reaching a normative consensus in terms of standards set by the CSFM vision and human security in light of the current global pandemic. The author advocates pursuing a pragmatic, problem-solving approach to international engagement with China without advancing a particular political agenda based on broad ideological presumptions, namely by encouraging and facilitating China’s further participation in international institutions and treaties. This approach may establish an increasing convergence and resonance of local and nonlocal norms to reach a normative consensus and, ultimately, to influence treaty performance incrementally and gradually.

Background: Virtual reality (VR) programs based on motion capture camera are the most convenient and cost-effective approaches for remote rehabilitation. Assessment of physical function is critical for providing optimal VR rehabilitation training; however, direct muscle strength measurement using camera-based kinematic data is impracticable. Therefore, it is necessary to develop a method to indirectly estimate the muscle strength of users from the value obtained using a motion capture camera. Objects: The purpose of this study was to determine whether the pedaling speed converted using the VR engine from the captured foot position data in the VR environment can be used as an indirect way to evaluate knee muscle strength, and to investigate the validity and reliability of a camera-based VR program. Methods: Thirty healthy adults were included in this study. Each subject performed a 15-second maximum pedaling test in the VR and built-in speedometer modes. In the VR speedometer mode, a motion capture camera was used to detect the position of the ankle joints and automatically calculate the pedaling speed. An isokinetic dynamometer was used to assess the isometric and isokinetic peak torques of knee flexion and extension. Results: The pedaling speeds in VR and built-in speedometer modes revealed a significantly high positive correlation (r = 0.922). In addition, the intra-rater reliability of the pedaling speed in the VR speedometer mode was good (ICC [intraclass correlation coefficient] = 0.685). The results of the Pearson correlation analysis revealed a significant moderate positive correlation between the pedaling speed of the VR speedometer and the peak torque of knee isokinetic flexion (r = 0.639) and extension (r = 0.598). Conclusion: This study suggests the potential benefits of measuring the maximum pedaling speed using 3D depth camera in a VR environment as an indirect assessment of muscle strength. However, technological improvements must be followed to obtain more accurate estimation of muscle strength from the VR cycling test.