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신 촉매를 이용한 DME 전환율에 관한 연구 KCI 등재

A Study on DME Conversion rate using New Catalyst

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한국기계기술학회지 (Journal of the Korean Society of Mechanical Technology)
한국기계기술학회 (Korean Society of Mechanical Technology)
초록

It has been stand high in estimation to converse from Carbon dioxide to Dimethyl Ether in new alternative fuel energy division in 21C, especially Using of DME in point of view of transportation fuel has been discussed of a new clean energy which is very lower of exhaust gas than gasoline and diesel energy. In this paper it is used ZSM-5 and I developed new catalyst by addition of cerium to control acidity. The new catalyst was proved high conversion rate, when it was conversed from methanol to DME, there wasn't any additional material except DME and water, and I overlooked reaction temperature, reaction time, amount of catalyst, amount of added cerium, effect of water content in methanol, reaction temperature by making change of reaction time. I have conclude that conversion rate to DME was increased as increased of catalyst amounts. The best catalyst condition of without additional product was treated poisoning from ZSM-5 to 5% cerium and new catalyst was not effected in purity of fuel methanol.

목차
Abstract
 1. 서론
 2. 이론적 배경
  2.1 DME의 일반적 물성
  2.2 DME 제조공정
  2.3 DME 활용 특성
 3. 실험
  3.1 촉매 제조
  3.2 실험 장치
  3.3 실험 방법
 4. 결과 및 고찰
  4.1 cerium처리에 의한 반응 전환율 변화
  4.2 촉매량에 따른 전환율 변화
  4.3 원료 메탄올의 순도에 따른 전환율 변화
  4.4 반응시간에 따른 전환율 변화
 5. 결론
 참고문헌
저자
  • 정인상(한국폴리텍V대학 광주캠퍼스 그린에너지설비학과) | I. S. Jeong