For the unconfined vapor cloud explosion accident by the continuous release of gas-liquid flow of various saturated liquids in a vessel at ground level, overpressures were estimated and analyzed with various release conditions and materials by TNT equivalency model with vapor dispersion. We found that at same release conditions, overpressure showed n-heptane > xylene > n-hexane > toluene > n-heptane > benzene, respectively and that overpressure was increased with increasing the hole diameter and the storage pressure, but it was increased with decreasing the wind speed, the interested distance, and the vessel thickness.