Boilers and diesel engines have many problems because their exhaust particles, i.e., soot have lots of bad influence on environment. And it's spray and flame have fundamentally axial symmetric shape. To investigate the relationship between fuel concentration distribution of spray and soot concentration distribution as well as temperature distribution of flame, we made a axial symmetric two phase spray-flame and analyzed the structure of is. The measuring method is the principle of the light extinction method for the spray-flame and onion peeling model is applied to analyze the radial distribution of fuel and soot concentration. The temperature of flame is measured by ø 0.4mm Pt-Pt.RH 3% thermocouple. The oils for the experiments are diesel oil and 10% water emulsified diesel oil. It was found that the soot concentration becomes higher as it comes near to the center of flame, and the fuel concentration does, too. And the soot concentration level of diesel oil is generally higher than that of the 10% water emulsified fuel. The maximum flame temperature of diesel oil is 1,170℃, however, 10% water emulsified diesel oil is 1,270℃.