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음이온성 아크릴아미드와 아크릴산의 역유화 중합에 관한 연구 KCI 등재

A Study on the Inverse Emulsion Polymerization of Anionic Arcrylamide and Acrylic Acid

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  • URLhttps://db.koreascholar.com/Article/Detail/256918
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한국응용과학기술학회지 (The Korean Society of Applied Science and Technology)
한국응용과학기술학회(구 한국유화학회) (The Korean Society of Applied Science and Technology (KSAST))
초록

To developed new process for obtaining maximum molecular weight of anionic acrylamide and acrylic acid copolymer by inverse emulsion polymerization. Concentration of initiator, reducing agent, surfactant and mole ratio of acrylamide-acrylic acid were studied for the process. Semi-batch processes with method of redox, control of reaction temperature, feeding method of monomer and reaction time, was suitable for maximum molecular weight of P(AMAC) from this process obtained 3.09 × 106(Mn.) and 4.41 × 106(Mw.) in molecular weight measured by the intrinsic viscosity method. inverse emulsion polymerization mechanism of P(AMAC) does not followed the Smith-Ewart and Medvedev theory, but selected for concentration of initiator, reducing agent, surfactant, water solubility of monomer.

저자
  • 이기창 | Lee, Ki-Chang
  • 최희천 | Choi, Hee-Chun
  • 최봉종 | Choi, Bong-Jong
  • 이광일 | Lee, Kwang-Il