벤조산유도체 I, Nitrone 유도체에 대한 Thiourea의 친핵성 첨가반응메카니즘과 그 반응속도론적 연구

김동환; 이기창; 류정욱; 최봉종

논문 상세보기

벤조산유도체 I, Nitrone 유도체에 대한 Thiourea의 친핵성 첨가반응메카니즘과 그 반응속도론적 연구 KCI 등재

Benzoic Acid Derivatives I, The Kinetics and Mechanism of the Nucleopilic Addition of Thiourea to Nitrone Derivatives

김동환, 이기창, 류정욱, 최봉종

언어KOR
URLhttps://db.koreascholar.com/Article/Detail/256967

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한국응용과학기술학회지 (The Korean Society of Applied Science and Technology)

Vol.8 No.1 (1991.06)
pp.21-26

한국응용과학기술학회(구 한국유화학회) (The Korean Society of Applied Science and Technology (KSAST))

초록

The rate constants for the addition reaction of thiourea to nitrone derivatives were determind at various pH and reaction rate equation which could be applied over a wide pH were obtained. The substituent effects and general base catalysis for the addition of thiourea to nitrone derivatives were observed. On the basis of these findings, a plausible reaction mechanism for the nucleophilic addition of thiourea to nitrone was proposed.

저자

김동환 | Kim, Dong-Hwan
이기창 | Lee, Ki-Chang
류정욱 | Ryu, Jung-Wook
최봉종 | Choi, Bong-Jong

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