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다분자층 흡착과 BET 흡착식의 통계 역학적 고찰 KCI 등재
A Statistical-Mechanical Study on Multilayer Adsorptions and the BET Adsorption Equation
한국응용과학기술학회지
(The Korean Society of Applied Science and Technology)
Vol.23 No.4 (2006.12)
pp.280-289
pp.280-289
한국응용과학기술학회(구 한국유화학회)
(The Korean Society of Applied Science and Technology (KSAST))
초록
Multilayer adsorptions and BET adsorption are analyzed statistical-mechanically. Which ensemble is selected for the analysis is unimportant, because each ensemble yields the same results. However, the amount of mathematical manipulations and the matter of convenience vary from ensemble to ensemble. Hence, multilayer adsorptions and BET adsorption are examined using a canonical and a grand canonical ensembles, and an ensemble of subsystems. Also, the characteristics of multilayer and BET adsorptions are delineated.
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