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Preparation of Partial Mesophase Pitch-based Carbon Fiber from FCC-DO KCI 등재

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  • URLhttps://db.koreascholar.com/Article/Detail/259537
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Carbon Letters (Carbon letters)
한국탄소학회 (Korean Carbon Society)
초록

Partial mesophase (PM) pitch precursor was prepared from fluidized catalytic cracking-decant oils (FCC-DO) by chemical reaction in the presence of Br2. The PM pitch heated-treatment at 420℃ for 9 h exhibited the softening point of 297℃ with 23% yield, and 55% anisotropic content. The PM pitch precursor was melt-spun through circular nozzle by pressurized N2, stabilized at 310℃, carbonized at 700℃, 1000℃, and 1200℃. The enough stabilization introduced 16.4% of the oxygen approximately. The stacking height (Lc002) and interlayer spacing (d002) of the as-spun fibers were 4.58 nm and 3.45a and the value became minimum and maximum at 700℃ respectively in the carbonization procedure. The tensile strength increased with an increase in the heat treatment temperature exhibiting highest value of 750 MPa at 1200℃ carbonization.

저자
  • Sang-Hee Park(Faculty of Applied Chemistry, Chonnam National University)
  • Kap-Seung Yang(Faculty of Applied Chemistry, Chonnam National University)
  • Soon-Young Soh(Hanwha Chemical Co.)