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Synthesis and Characterization of Three-dimensional Polymer Produced by Mutual Condensation of Ethylenediamine and C60 KCI 등재
The polymer with contents of C60 up to 57 wt.% was produced by mutual condensation of fullerene C60 and ethylenediamine. The investigations of this polymer as well as pristine fullerene to comparison were carried out by FT-IR and UV-Vis spectroscopy, ToF-SIMS, TGA, and elemental analysis. At least three kinds of components was revealed as building blocks of polymer. The fullerene cage underwent only distortion but didn't destroy during formation of polymer. The pure fullerene was found as an intermediate of the thermal decomposition of polymer. The conclusion that this polymer could serve as precursor to produce carbon nanomaterial with high concentration curved graphene sheets and can be used for gas adsorption and electrochemical application was made.
