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Capacitance behaviors of Polyaniline/Graphene Nanosheet Composites Prepared by Aniline Chemical Polymerization KCI 등재

  • 언어ENG
  • URLhttps://db.koreascholar.com/Article/Detail/259906
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Carbon Letters (Carbon letters)
한국탄소학회 (Korean Carbon Society)
초록

In this study, polyaniline (PANI)/graphene nanosheet (GNS) composites were synthesized through chemical oxidation polymerization by changing the weight ratio of aniline mono-mers. To examine the morphological structure of the composites, scanning electron micros-copy and transmission electron microscopy (TEM) were conducted. TEM results revealed that fibril-likePANI with a diameter of 50 nm was homogeneously coated on the surface of the GNS. The electrochemical properties of the composites were studied by cyclic voltam-metry in 1 M H2SO4 electrolyte. Among the prepared samples, the PANI/GNS (having 40 wt% aniline content) showed the highest specificcapacitance, 528 Fg-1, at 10 mVs-1. The im-proved performance was attributed to the GNS, which provides a large number of active sites and good electrical conductivity. The resulting composites are promising electrode materials for high capacitative supercapacitors.

저자
  • Jieun Kim(Department of Chemical and Biochemical Engineering, Pusan National University)
  • Soo-Jin Park(Department of Chemistry, Inha University)
  • Seok Kim(Department of Chemical and Biochemical Engineering, Pusan National University) Corresponding Author