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CSA를 사용한 플라이애시 함유 시멘트 수화물의 초기 특성에 관한 연구 KCI 등재

The Study on the Early Characteristic of Fly Ash Cement using Calcium Sulfo Aluminate

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한국폐기물자원순환학회지 (Journal of Korea Society of Waste Management)
한국폐기물자원순환학회 (Korea Society Of Waste Management)
초록

Concrete strength is not only an important factor in design and quality control, but it also represents the overall qualityof concrete. The use of admixture has been increasingly prevalent in the recent cases of concrete production as a meansto improve the functionality of concrete. Of particular note, fly ash is added in either the cement or the ready-mixedconcrete production stage with the general mixing ratio being about 15%; however, using fly ash slows down the initialhydration of the binding material, which can in turn cause a delay in acquisition of strength. In this study, calcium sulfoaluminate (C4A3S; CSA) was added to improve the initial strength of cement after the use of fly ash, and its effect instrength improvement was analyzed. The substitution ratios of fly ash were 0, 10, 20 and 30%, and the amount of CSAadded to improve the initial strength was 8% of the fly ash weight. The results of the experiment showed that adding CSA resulted in high calorific values at peaks 1 and 2 of hydration heat, and an X-ray diffraction analysis showed thatthe amount of unhydrated materials was higher with increasing substitution ratio of fly ash. An increase in CSA wasalso shown to lead to a higher amount of ettringite being generated in the early ages. In conclusion, addition of 30% flyash and 8% CSA led to an ettringite production that was 3 times higher than the mixing ratio of fly ash, which effectivelyimproved the initial strength. The same phenomenon was observed in the electron microscope analysis. Based on theseresults, it was determined that adding CSA in an amount that equaled to 8% of fly ash weight can promote the productionof ettringite, thereby improving the initial strength, which gets reduced by the use of fly ash.

저자
  • 박지선(한국건설기술연구원 공공건축연구본부) | Ji-Sun Park Corresponding author
  • 송태협(한국건설기술연구원 공공건축연구본부) | Tae-Hyeob Song
  • 전찬수(한국건설기술연구원 공공건축연구본부) | Chan-Su Chon
  • 송훈(한국세라믹기술원 에너지환경소재본부) | Hun Song