Concrete strength is not only an important factor in design and quality control, but it also represents the overall qualityof concrete. The use of admixture has been increasingly prevalent in the recent cases of concrete production as a meansto improve the functionality of concrete. Of particular note, fly ash is added in either the cement or the ready-mixedconcrete production stage with the general mixing ratio being about 15%; however, using fly ash slows down the initialhydration of the binding material, which can in turn cause a delay in acquisition of strength. In this study, calcium sulfoaluminate (C4A3S; CSA) was added to improve the initial strength of cement after the use of fly ash, and its effect instrength improvement was analyzed. The substitution ratios of fly ash were 0, 10, 20 and 30%, and the amount of CSAadded to improve the initial strength was 8% of the fly ash weight. The results of the experiment showed that adding CSA resulted in high calorific values at peaks 1 and 2 of hydration heat, and an X-ray diffraction analysis showed thatthe amount of unhydrated materials was higher with increasing substitution ratio of fly ash. An increase in CSA wasalso shown to lead to a higher amount of ettringite being generated in the early ages. In conclusion, addition of 30% flyash and 8% CSA led to an ettringite production that was 3 times higher than the mixing ratio of fly ash, which effectivelyimproved the initial strength. The same phenomenon was observed in the electron microscope analysis. Based on theseresults, it was determined that adding CSA in an amount that equaled to 8% of fly ash weight can promote the productionof ettringite, thereby improving the initial strength, which gets reduced by the use of fly ash.