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메탄에 의한 Ag/Al2O3 촉매의 선택적 탈질 환원촉매반응에서 탈질전환율에 미치는 황화물 형성의 영향과 Mg첨가 효과 KCI 등재

The Effects of Sulfate Formation and Mg Addition on the Selective Catalytic Reduction of NOx with CH4 on Ag/Al2O3 Catalysts

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한국분말야금학회지 (Journal of Korean Powder Metallurgy Institute)
한국분말재료학회(구 한국분말야금학회) (Korean Powder Metallurgy Institute)
초록

The influence of sulfate on the selective catalytic reduction of on the Ag/ catalyst was studied when was used as a reducing agent. Various preparation methods influenced differently on the activity. Among the methods, cogelation precipitation gave best activity. When sulfates were formed on the surfaces of samples prepared by impregnated and deposition precipitation, activity was enhanced as long as suitable forming condition is satisfied. The major sulfate formed in Ag/ catalyst was the aluminum sulfate and it seems that this sulfate acted as a promoter. When Mg was added to the Ag/ catalyst it promoted activity at high temperature. Intentionally added sulfate also enhanced activity, when their amount was confined less than 3 wt%.

저자
  • 최희락 | Choi Hee-Lack
  • 유창용 | Yu Chang-Yong
  • 하헌필 | Ha Heon-Phil