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Influence of ionic liquid additives on the conducting and interfacial properties of organic solvent-based electrolytes against an activated carbon electrode KCI 등재

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  • URLhttps://db.koreascholar.com/Article/Detail/278152
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Carbon Letters (Carbon letters)
한국탄소학회 (Korean Carbon Society)
초록

This study reports on the influenceof N-butyl-N-methylpyrrolidinium tetrafluoroborat (PYR14BF4) ionic liquid additive on the conducting and interfacial properties of organic solvent based electrolytes against a carbon electrode. We used the mixture of ethylene carbonate/dimethoxyethane (1:1) as an organic solvent electrolyte and tetraethylammo-nium tetrafluoroborate(TEABF4) as a common salt. Using the PYR14BF ionic liquid as additive produced higher ionic conductivity in the electrolyte and lower interface resis-tance between carbon and electrolyte, resulting in improved capacitance. The chemical and electrochemical stability of the electrolyte was measured by ionic conductivity me-ter and linear sweep voltammetry. The electrochemical analysis between electrolyte and carbon electrode was examined by cyclic voltammetry and electrochemical impedance spectroscopy.

저자
  • Kim, Kyungmin(Department of Chemical and Biochemical Engineering, Pusan National University)
  • Jung, Yongju( Department of Applied Chemical Engineering, Korea University of Technology and Education) | Jung, Yongju
  • Kim, Seok( Department of Chemical and Biochemical Engineering, Pusan National University) | Kim, Seok