In order to minimize a building energy consumption with ventilation, a development of smart ventilation system is very important. In this study, a dry adsorbent that is main element of smart ventilation system was developed for removing indoor CO2, and evaluate the adsorption performance. Specific surface area, pore characteristic and crystal structure of the modified sorbent was measured to analyze physical properties. From this analysis, it was found that the developed absorbent has a low specific surface area, due to mesopores of substrate was filled with metal contained raw material. Additionally, through analysis of the adsorption properties, the developed adsorbent was shown a adsorption form of mesopore (type Ⅳ), which means adsorption amount was rapidly increased at the part of high-pressure. Order to applying for the field, chamber test was performed. Continuous column tests (2,500 ppm) and batch chamber tests (4 m3, 5,000 ppm) showed CO2 removal efficiency of 95% and 88% within 1 hour, respectively.